Esterification of oleic acid in a semi-batch bubble reactor for biodiesel production
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/33914 |
Resumo: | A semi-batch bubble reactor has been developed to produce fatty acid ethyl ester (biodiesel) by acid-catalyzed esterification of oleic acid with superheated ethanol vapor. In this paper, the effects of reaction temperature (110, 130 and 150°C), ethanol volumetric flow rate (1.35, 2.50 and 3.65 mL/min) and vapor bubble size on the reactor performance were evaluated. The results demonstrated that temperature and volumetric flow rate have significant effects on the chemical reaction, gas phase solubility and mass transfer limitations. In addition, the free fatty acid conversion velocity was increased by approximately 56% when a microporous stainless-steel tube was employed to generate and distribute the vapor bubbles inside the reactor, which allowed the process to reach 95% conversion in approximately 40 minutes for the operating temperature of 150°C and volumetric flow rate of 2.5 mL/min |
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Souza, Domingos Fabiano de SantanaSilva, Maxwell GomesOliveira, G. S.Carvalho, J. C. R.Nobre, L. R. P.Deus, M. S.Jesus, A. A.Oliveira, Jackson Araújo de2021-09-16T14:34:33Z2021-09-16T14:34:33Z2019-03SILVA, M. G.; OLIVEIRA, G. S.; CARVALHO, J. C. R.; NOBRE, L. R. P.; DEUS, M. S.; JESUS, A. A.; OLIVEIRA, J. A.; SOUZA, D. F. S.. ESTERIFICATION OF OLEIC ACID IN A SEMI-BATCH BUBBLE REACTOR FOR BIODIESEL PRODUCTION. Brazilian Journal Of Chemical Engineering, [S.L.], v. 36, n. 1, p. 299-308, mar. 2019. Disponível em <www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322019000100299> . Acesso em 25 mar. 2021. http://dx.doi.org/10.1590/0104-6632.20190361s20180185.1678-4383https://repositorio.ufrn.br/handle/123456789/3391410.1590/0104-6632.20190361s20180185Brazilian Society of Chemical EngineeringAttribution 3.0 Brazilhttp://creativecommons.org/licenses/by/3.0/br/info:eu-repo/semantics/openAccessBiodieselEsterificationBubble reactorOleic acidEthanolEsterification of oleic acid in a semi-batch bubble reactor for biodiesel productioninfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleA semi-batch bubble reactor has been developed to produce fatty acid ethyl ester (biodiesel) by acid-catalyzed esterification of oleic acid with superheated ethanol vapor. In this paper, the effects of reaction temperature (110, 130 and 150°C), ethanol volumetric flow rate (1.35, 2.50 and 3.65 mL/min) and vapor bubble size on the reactor performance were evaluated. The results demonstrated that temperature and volumetric flow rate have significant effects on the chemical reaction, gas phase solubility and mass transfer limitations. In addition, the free fatty acid conversion velocity was increased by approximately 56% when a microporous stainless-steel tube was employed to generate and distribute the vapor bubbles inside the reactor, which allowed the process to reach 95% conversion in approximately 40 minutes for the operating temperature of 150°C and volumetric flow rate of 2.5 mL/minengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALEsterificationOfOleicAcid_Souza_2019.pdfEsterificationOfOleicAcid_Souza_2019.pdfapplication/pdf1767293https://repositorio.ufrn.br/bitstream/123456789/33914/1/EsterificationOfOleicAcid_Souza_2019.pdfb053f962c2e975fa135cfee7369804d7MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/33914/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/33914/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53123456789/339142021-09-16 11:34:34.211oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-09-16T14:34:34Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Esterification of oleic acid in a semi-batch bubble reactor for biodiesel production |
title |
Esterification of oleic acid in a semi-batch bubble reactor for biodiesel production |
spellingShingle |
Esterification of oleic acid in a semi-batch bubble reactor for biodiesel production Souza, Domingos Fabiano de Santana Biodiesel Esterification Bubble reactor Oleic acid Ethanol |
title_short |
Esterification of oleic acid in a semi-batch bubble reactor for biodiesel production |
title_full |
Esterification of oleic acid in a semi-batch bubble reactor for biodiesel production |
title_fullStr |
Esterification of oleic acid in a semi-batch bubble reactor for biodiesel production |
title_full_unstemmed |
Esterification of oleic acid in a semi-batch bubble reactor for biodiesel production |
title_sort |
Esterification of oleic acid in a semi-batch bubble reactor for biodiesel production |
author |
Souza, Domingos Fabiano de Santana |
author_facet |
Souza, Domingos Fabiano de Santana Silva, Maxwell Gomes Oliveira, G. S. Carvalho, J. C. R. Nobre, L. R. P. Deus, M. S. Jesus, A. A. Oliveira, Jackson Araújo de |
author_role |
author |
author2 |
Silva, Maxwell Gomes Oliveira, G. S. Carvalho, J. C. R. Nobre, L. R. P. Deus, M. S. Jesus, A. A. Oliveira, Jackson Araújo de |
author2_role |
author author author author author author author |
dc.contributor.author.fl_str_mv |
Souza, Domingos Fabiano de Santana Silva, Maxwell Gomes Oliveira, G. S. Carvalho, J. C. R. Nobre, L. R. P. Deus, M. S. Jesus, A. A. Oliveira, Jackson Araújo de |
dc.subject.por.fl_str_mv |
Biodiesel Esterification Bubble reactor Oleic acid Ethanol |
topic |
Biodiesel Esterification Bubble reactor Oleic acid Ethanol |
description |
A semi-batch bubble reactor has been developed to produce fatty acid ethyl ester (biodiesel) by acid-catalyzed esterification of oleic acid with superheated ethanol vapor. In this paper, the effects of reaction temperature (110, 130 and 150°C), ethanol volumetric flow rate (1.35, 2.50 and 3.65 mL/min) and vapor bubble size on the reactor performance were evaluated. The results demonstrated that temperature and volumetric flow rate have significant effects on the chemical reaction, gas phase solubility and mass transfer limitations. In addition, the free fatty acid conversion velocity was increased by approximately 56% when a microporous stainless-steel tube was employed to generate and distribute the vapor bubbles inside the reactor, which allowed the process to reach 95% conversion in approximately 40 minutes for the operating temperature of 150°C and volumetric flow rate of 2.5 mL/min |
publishDate |
2019 |
dc.date.issued.fl_str_mv |
2019-03 |
dc.date.accessioned.fl_str_mv |
2021-09-16T14:34:33Z |
dc.date.available.fl_str_mv |
2021-09-16T14:34:33Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
SILVA, M. G.; OLIVEIRA, G. S.; CARVALHO, J. C. R.; NOBRE, L. R. P.; DEUS, M. S.; JESUS, A. A.; OLIVEIRA, J. A.; SOUZA, D. F. S.. ESTERIFICATION OF OLEIC ACID IN A SEMI-BATCH BUBBLE REACTOR FOR BIODIESEL PRODUCTION. Brazilian Journal Of Chemical Engineering, [S.L.], v. 36, n. 1, p. 299-308, mar. 2019. Disponível em <www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322019000100299> . Acesso em 25 mar. 2021. http://dx.doi.org/10.1590/0104-6632.20190361s20180185. |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/33914 |
dc.identifier.issn.none.fl_str_mv |
1678-4383 |
dc.identifier.doi.none.fl_str_mv |
10.1590/0104-6632.20190361s20180185 |
identifier_str_mv |
SILVA, M. G.; OLIVEIRA, G. S.; CARVALHO, J. C. R.; NOBRE, L. R. P.; DEUS, M. S.; JESUS, A. A.; OLIVEIRA, J. A.; SOUZA, D. F. S.. ESTERIFICATION OF OLEIC ACID IN A SEMI-BATCH BUBBLE REACTOR FOR BIODIESEL PRODUCTION. Brazilian Journal Of Chemical Engineering, [S.L.], v. 36, n. 1, p. 299-308, mar. 2019. Disponível em <www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322019000100299> . Acesso em 25 mar. 2021. http://dx.doi.org/10.1590/0104-6632.20190361s20180185. 1678-4383 10.1590/0104-6632.20190361s20180185 |
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https://repositorio.ufrn.br/handle/123456789/33914 |
dc.language.iso.fl_str_mv |
eng |
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eng |
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Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ info:eu-repo/semantics/openAccess |
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Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ |
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openAccess |
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Brazilian Society of Chemical Engineering |
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Brazilian Society of Chemical Engineering |
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