Thermal decomposition kinetics of PrMO3 (M 5 Ni or Co) ceramic materials via thermogravimetry
Autor(a) principal: | |
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Data de Publicação: | 2010 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/32026 |
Resumo: | Thermogravimetric data using the non-isother-mal kinetic models of Flynn and Wall and ‘‘Model free Kinetics’’ were used to determine the activation energy to study the decomposition kinetics of the ligand groups with system’s metallic ions that takes part in the synthesis of PrMO3 (M = Ni or Co). This activation energy was determined for the stage of highest decomposition of the organic matter to establish parameters in synthesis condition optimization and application of the proposed material |
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Aquino, Flávia de MedeirosMelo, Dulce Maria de AraújoSantiago, R. C.Melo, Marcus Antônio de FreitasMartinelli, Antonio EduardoFreitas, Júlio César de OliveiraAraújo, L. C. B.2021-03-30T18:11:51Z2021-03-30T18:11:51Z2010-12-08AQUINO, F.M., MELO, D.M.A., SANTIAGO, R.C. et al. Thermal decomposition kinetics of PrMO3 (M = Ni or Co) ceramic materials via thermogravimetry. J Therm Anal Calorim 104, 701–705 (2011). Disponível em: https://link.springer.com/article/10.1007/s10973-010-1191-0 Acesso em: 16 nov. 2020. https://doi.org/10.1007/s10973-010-1191-01572-89431388-6150https://repositorio.ufrn.br/handle/123456789/3202610.1007/s10973-010-1191-0SpringerAttribution 3.0 Brazilhttp://creativecommons.org/licenses/by/3.0/br/info:eu-repo/semantics/openAccessCeramic materialsThermogravimetryActivation energyThermal decomposition kinetics of PrMO3 (M 5 Ni or Co) ceramic materials via thermogravimetryinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleThermogravimetric data using the non-isother-mal kinetic models of Flynn and Wall and ‘‘Model free Kinetics’’ were used to determine the activation energy to study the decomposition kinetics of the ligand groups with system’s metallic ions that takes part in the synthesis of PrMO3 (M = Ni or Co). This activation energy was determined for the stage of highest decomposition of the organic matter to establish parameters in synthesis condition optimization and application of the proposed materialengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALThermalDecompositionKinetics_MARTINELLI_2010.pdfThermalDecompositionKinetics_MARTINELLI_2010.pdfapplication/pdf446654https://repositorio.ufrn.br/bitstream/123456789/32026/1/ThermalDecompositionKinetics_MARTINELLI_2010.pdfaa70625f6f85ca48754abda6864c823dMD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/32026/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/32026/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53TEXTThermalDecompositionKinetics_MARTINELLI_2010.pdf.txtThermalDecompositionKinetics_MARTINELLI_2010.pdf.txtExtracted texttext/plain16261https://repositorio.ufrn.br/bitstream/123456789/32026/4/ThermalDecompositionKinetics_MARTINELLI_2010.pdf.txt488da6f8c1398bff1259070b29a1b80cMD54THUMBNAILThermalDecompositionKinetics_MARTINELLI_2010.pdf.jpgThermalDecompositionKinetics_MARTINELLI_2010.pdf.jpgGenerated Thumbnailimage/jpeg1775https://repositorio.ufrn.br/bitstream/123456789/32026/5/ThermalDecompositionKinetics_MARTINELLI_2010.pdf.jpg431dffd7e826ca343936d48d15dd14b4MD55123456789/320262021-12-06 17:13:44.699oai:https://repositorio.ufrn.br:123456789/32026Tk9OLUVYQ0xVU0lWRSBESVNUUklCVVRJT04gTElDRU5TRQoKCkJ5IHNpZ25pbmcgYW5kIGRlbGl2ZXJpbmcgdGhpcyBsaWNlbnNlLCBNci4gKGF1dGhvciBvciBjb3B5cmlnaHQgaG9sZGVyKToKCgphKSBHcmFudHMgdGhlIFVuaXZlcnNpZGFkZSBGZWRlcmFsIFJpbyBHcmFuZGUgZG8gTm9ydGUgdGhlIG5vbi1leGNsdXNpdmUgcmlnaHQgb2YKcmVwcm9kdWNlLCBjb252ZXJ0IChhcyBkZWZpbmVkIGJlbG93KSwgY29tbXVuaWNhdGUgYW5kIC8gb3IKZGlzdHJpYnV0ZSB0aGUgZGVsaXZlcmVkIGRvY3VtZW50IChpbmNsdWRpbmcgYWJzdHJhY3QgLyBhYnN0cmFjdCkgaW4KZGlnaXRhbCBvciBwcmludGVkIGZvcm1hdCBhbmQgaW4gYW55IG1lZGl1bS4KCmIpIERlY2xhcmVzIHRoYXQgdGhlIGRvY3VtZW50IHN1Ym1pdHRlZCBpcyBpdHMgb3JpZ2luYWwgd29yaywgYW5kIHRoYXQKeW91IGhhdmUgdGhlIHJpZ2h0IHRvIGdyYW50IHRoZSByaWdodHMgY29udGFpbmVkIGluIHRoaXMgbGljZW5zZS4gRGVjbGFyZXMKdGhhdCB0aGUgZGVsaXZlcnkgb2YgdGhlIGRvY3VtZW50IGRvZXMgbm90IGluZnJpbmdlLCBhcyBmYXIgYXMgaXQgaXMKdGhlIHJpZ2h0cyBvZiBhbnkgb3RoZXIgcGVyc29uIG9yIGVudGl0eS4KCmMpIElmIHRoZSBkb2N1bWVudCBkZWxpdmVyZWQgY29udGFpbnMgbWF0ZXJpYWwgd2hpY2ggZG9lcyBub3QKcmlnaHRzLCBkZWNsYXJlcyB0aGF0IGl0IGhhcyBvYnRhaW5lZCBhdXRob3JpemF0aW9uIGZyb20gdGhlIGhvbGRlciBvZiB0aGUKY29weXJpZ2h0IHRvIGdyYW50IHRoZSBVbml2ZXJzaWRhZGUgRmVkZXJhbCBkbyBSaW8gR3JhbmRlIGRvIE5vcnRlIHRoZSByaWdodHMgcmVxdWlyZWQgYnkgdGhpcyBsaWNlbnNlLCBhbmQgdGhhdCB0aGlzIG1hdGVyaWFsIHdob3NlIHJpZ2h0cyBhcmUgb2YKdGhpcmQgcGFydGllcyBpcyBjbGVhcmx5IGlkZW50aWZpZWQgYW5kIHJlY29nbml6ZWQgaW4gdGhlIHRleHQgb3IKY29udGVudCBvZiB0aGUgZG9jdW1lbnQgZGVsaXZlcmVkLgoKSWYgdGhlIGRvY3VtZW50IHN1Ym1pdHRlZCBpcyBiYXNlZCBvbiBmdW5kZWQgb3Igc3VwcG9ydGVkIHdvcmsKYnkgYW5vdGhlciBpbnN0aXR1dGlvbiBvdGhlciB0aGFuIHRoZSBVbml2ZXJzaWRhZGUgRmVkZXJhbCBkbyBSaW8gR3JhbmRlIGRvIE5vcnRlLCBkZWNsYXJlcyB0aGF0IGl0IGhhcyBmdWxmaWxsZWQgYW55IG9ibGlnYXRpb25zIHJlcXVpcmVkIGJ5IHRoZSByZXNwZWN0aXZlIGFncmVlbWVudCBvciBhZ3JlZW1lbnQuCgpUaGUgVW5pdmVyc2lkYWRlIEZlZGVyYWwgZG8gUmlvIEdyYW5kZSBkbyBOb3J0ZSB3aWxsIGNsZWFybHkgaWRlbnRpZnkgaXRzIG5hbWUgKHMpIGFzIHRoZSBhdXRob3IgKHMpIG9yIGhvbGRlciAocykgb2YgdGhlIGRvY3VtZW50J3MgcmlnaHRzCmRlbGl2ZXJlZCwgYW5kIHdpbGwgbm90IG1ha2UgYW55IGNoYW5nZXMsIG90aGVyIHRoYW4gdGhvc2UgcGVybWl0dGVkIGJ5CnRoaXMgbGljZW5zZQo=Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-12-06T20:13:44Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Thermal decomposition kinetics of PrMO3 (M 5 Ni or Co) ceramic materials via thermogravimetry |
title |
Thermal decomposition kinetics of PrMO3 (M 5 Ni or Co) ceramic materials via thermogravimetry |
spellingShingle |
Thermal decomposition kinetics of PrMO3 (M 5 Ni or Co) ceramic materials via thermogravimetry Aquino, Flávia de Medeiros Ceramic materials Thermogravimetry Activation energy |
title_short |
Thermal decomposition kinetics of PrMO3 (M 5 Ni or Co) ceramic materials via thermogravimetry |
title_full |
Thermal decomposition kinetics of PrMO3 (M 5 Ni or Co) ceramic materials via thermogravimetry |
title_fullStr |
Thermal decomposition kinetics of PrMO3 (M 5 Ni or Co) ceramic materials via thermogravimetry |
title_full_unstemmed |
Thermal decomposition kinetics of PrMO3 (M 5 Ni or Co) ceramic materials via thermogravimetry |
title_sort |
Thermal decomposition kinetics of PrMO3 (M 5 Ni or Co) ceramic materials via thermogravimetry |
author |
Aquino, Flávia de Medeiros |
author_facet |
Aquino, Flávia de Medeiros Melo, Dulce Maria de Araújo Santiago, R. C. Melo, Marcus Antônio de Freitas Martinelli, Antonio Eduardo Freitas, Júlio César de Oliveira Araújo, L. C. B. |
author_role |
author |
author2 |
Melo, Dulce Maria de Araújo Santiago, R. C. Melo, Marcus Antônio de Freitas Martinelli, Antonio Eduardo Freitas, Júlio César de Oliveira Araújo, L. C. B. |
author2_role |
author author author author author author |
dc.contributor.author.fl_str_mv |
Aquino, Flávia de Medeiros Melo, Dulce Maria de Araújo Santiago, R. C. Melo, Marcus Antônio de Freitas Martinelli, Antonio Eduardo Freitas, Júlio César de Oliveira Araújo, L. C. B. |
dc.subject.por.fl_str_mv |
Ceramic materials Thermogravimetry Activation energy |
topic |
Ceramic materials Thermogravimetry Activation energy |
description |
Thermogravimetric data using the non-isother-mal kinetic models of Flynn and Wall and ‘‘Model free Kinetics’’ were used to determine the activation energy to study the decomposition kinetics of the ligand groups with system’s metallic ions that takes part in the synthesis of PrMO3 (M = Ni or Co). This activation energy was determined for the stage of highest decomposition of the organic matter to establish parameters in synthesis condition optimization and application of the proposed material |
publishDate |
2010 |
dc.date.issued.fl_str_mv |
2010-12-08 |
dc.date.accessioned.fl_str_mv |
2021-03-30T18:11:51Z |
dc.date.available.fl_str_mv |
2021-03-30T18:11:51Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
AQUINO, F.M., MELO, D.M.A., SANTIAGO, R.C. et al. Thermal decomposition kinetics of PrMO3 (M = Ni or Co) ceramic materials via thermogravimetry. J Therm Anal Calorim 104, 701–705 (2011). Disponível em: https://link.springer.com/article/10.1007/s10973-010-1191-0 Acesso em: 16 nov. 2020. https://doi.org/10.1007/s10973-010-1191-0 |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/32026 |
dc.identifier.issn.none.fl_str_mv |
1572-8943 1388-6150 |
dc.identifier.doi.none.fl_str_mv |
10.1007/s10973-010-1191-0 |
identifier_str_mv |
AQUINO, F.M., MELO, D.M.A., SANTIAGO, R.C. et al. Thermal decomposition kinetics of PrMO3 (M = Ni or Co) ceramic materials via thermogravimetry. J Therm Anal Calorim 104, 701–705 (2011). Disponível em: https://link.springer.com/article/10.1007/s10973-010-1191-0 Acesso em: 16 nov. 2020. https://doi.org/10.1007/s10973-010-1191-0 1572-8943 1388-6150 10.1007/s10973-010-1191-0 |
url |
https://repositorio.ufrn.br/handle/123456789/32026 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
Springer |
publisher.none.fl_str_mv |
Springer |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFRN instname:Universidade Federal do Rio Grande do Norte (UFRN) instacron:UFRN |
instname_str |
Universidade Federal do Rio Grande do Norte (UFRN) |
instacron_str |
UFRN |
institution |
UFRN |
reponame_str |
Repositório Institucional da UFRN |
collection |
Repositório Institucional da UFRN |
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