Avalia??o da biomassa da Terminalia catappa Linn (amendoeira) como adsorvente: estudo cin?tico e termodin?mico

Jurado, Lizeth Vanessa Amado

Avalia??o da biomassa da Terminalia catappa Linn (amendoeira) como adsorvente: estudo cin?tico e termodin?mico

Detalhes bibliográficos
Autor(a) principal:	Jurado, Lizeth Vanessa Amado
Data de Publicação:	2020
Tipo de documento:	Dissertação
Idioma:	por
Título da fonte:	Biblioteca Digital de Teses e Dissertações da UFRRJ
Texto Completo:	https://tede.ufrrj.br/jspui/handle/jspui/6254
Resumo:	The textile industries are responsible for the disposal of large volumes of effluents, damaging aquatic life and human health. The disposal of wastewater without treatment can modify the natural color of water resources, causing some problems, such as the formation of foams on the surface and an increase in the concentration of toxic substances as dyes. There are different technologies that have been studied to solve this problem, but the adsorption has been an attractive and promising for dye removal due to its advantages such as the possibility to reuse biomaterials, low operating cost, among others. Moreover, the application of alternative adsorbents of residues from biomasses has been increasingly studied. Terminalia catappa Linn (TCL), for example, generates an organic waste such as their fruits, which fall to the ground, and cause manhole clogging in the cities of Rio de Janeiro. Therefore, in this work, it was evaluated the efficiency of the endocarp of the almond fruit as adsorbent in the adsorption process of an organic dye, methyl orange. The adsorption studies were carried out by analyzing the equilibrium and kinetics. The endocarp were evaluated in its natural form, calcinated at 400 ?C, and chemical activated with phosphoric acid (H3PO4). It was observed that the material treated with acid showed the best results with 100% removal of the dye. So, the experiments were done using the activated carbon with H3PO4 varying the initial concentration (200 ? 800 mg.L- 1), temperature (25, 35 and 45 ?C), contact time (0 - 150 min), pH (1 - 11) and addition of sodium chloride (0.5, 0.7, 1.0 and 1.2 g.100 mL-1). The highest adsorptive capacity, 197.87 mg.g-1, was reached at pH 3, at 25 ?C, 800 mg.L-1 and a contact time of 150 min, removing 99.67% of the dye. The pseudo-second order model was, in general, the best that described the adsorption process, wich indicates that adsorption is limited by chemisorption process. The Freundlich isotherm best describes the adsorption of dye, which implies that the adsorption is heterogeneous with multi-layers. The thermodynamic study indicated that the process is endothermic, spontaneous, and the results indicated an affinity between the adsorbent and the adsorbate. Therefore, the activated carbon of the almond endocarp had a good performance, making it a promising adsorbent for the removal of methyl orange.

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spelling	Mendes, Marisa Fernandes023.918.187-50http://lattes.cnpq.br/3233683706295801Mendes, Marisa FernandesPereira, Karen SignoriMancini, Maur?cio Cordeiro061.451.687-06https://orcid.org/0000-0002-7004-7934http://lattes.cnpq.br/8378851448851020Jurado, Lizeth Vanessa Amado2023-01-24T15:41:51Z2020-02-12JURADO, Lizeth Vanessa Amado. Avalia??o da biomassa da Terminalia catappa Linn (amendoeira) como adsorvente: estudo cin?tico e termodin?mico. 2020. 122 f. Disserta??o (Mestrado em Engenharia Qu?mica) - Instituto de Tecnologia, Universidade Federal Rural do Rio de Janeiro, Serop?dica, RJ, 2020.https://tede.ufrrj.br/jspui/handle/jspui/6254The textile industries are responsible for the disposal of large volumes of effluents, damaging aquatic life and human health. The disposal of wastewater without treatment can modify the natural color of water resources, causing some problems, such as the formation of foams on the surface and an increase in the concentration of toxic substances as dyes. There are different technologies that have been studied to solve this problem, but the adsorption has been an attractive and promising for dye removal due to its advantages such as the possibility to reuse biomaterials, low operating cost, among others. Moreover, the application of alternative adsorbents of residues from biomasses has been increasingly studied. Terminalia catappa Linn (TCL), for example, generates an organic waste such as their fruits, which fall to the ground, and cause manhole clogging in the cities of Rio de Janeiro. Therefore, in this work, it was evaluated the efficiency of the endocarp of the almond fruit as adsorbent in the adsorption process of an organic dye, methyl orange. The adsorption studies were carried out by analyzing the equilibrium and kinetics. The endocarp were evaluated in its natural form, calcinated at 400 ?C, and chemical activated with phosphoric acid (H3PO4). It was observed that the material treated with acid showed the best results with 100% removal of the dye. So, the experiments were done using the activated carbon with H3PO4 varying the initial concentration (200 ? 800 mg.L- 1), temperature (25, 35 and 45 ?C), contact time (0 - 150 min), pH (1 - 11) and addition of sodium chloride (0.5, 0.7, 1.0 and 1.2 g.100 mL-1). The highest adsorptive capacity, 197.87 mg.g-1, was reached at pH 3, at 25 ?C, 800 mg.L-1 and a contact time of 150 min, removing 99.67% of the dye. The pseudo-second order model was, in general, the best that described the adsorption process, wich indicates that adsorption is limited by chemisorption process. The Freundlich isotherm best describes the adsorption of dye, which implies that the adsorption is heterogeneous with multi-layers. The thermodynamic study indicated that the process is endothermic, spontaneous, and the results indicated an affinity between the adsorbent and the adsorbate. Therefore, the activated carbon of the almond endocarp had a good performance, making it a promising adsorbent for the removal of methyl orange.As ind?strias t?xteis s?o respons?veis pelo descarte de grandes volumes de efluentes, prejudicando a vida aqu?tica e a sa?de humana. O descarte de efluentes l?quidos sem tratamento pode modificar a colora??o natural dos recursos h?dricos, causando alguns problemas como a forma??o de espumas na superf?cie e o aumento da concentra??o de subst?ncias t?xicas, como os corantes. A adsor??o tem se apresentado como uma t?cnica atrativa para a remo??o de corantes, devido ?s suas vantagens como reutiliza??o de biomateriais, baixo custo operacional, entre outros. A aplica??o de adsorventes alternativos oriundos de res?duos tem sido cada vez mais estudada. A Terminalia catappa Linn, por exemplo, gera alguns res?duos org?nicos como seus frutos, que caem no ch?o e tendem a causar o entupimento dos bueiros. Portanto, este trabalho avaliou a efici?ncia do endocarpo do fruto da amendoeira, no processo de adsor??o de um corante org?nico, o alaranjado de metila. Os estudos de adsor??o foram realizados analisando-se o equil?brio e a cin?tica do processo. Foi avaliado o endocarpo na sua forma in natura, calcinado a 400 ?C e ativado com ?cido fosf?rico (H3PO4). Foi observado que o material tratado com ?cido apresentou os melhores resultados atingindo 100% de remo??o do corante. Frente ao melhor desempenho, foi avaliada a varia??o da concentra??o inicial (200 ? 800 mg.L-1), da temperatura (25, 35 e 45 ?C), do tempo de contato (0 ? 150 min), do pH (1 ? 11) e da adi??o de cloreto de s?dio (0,5, 0,7, 1,0 e 1,2 g.100 mL-1) na efici?ncia do processo de adsor??o. A maior capacidade adsortiva, 197,87 mg.g-1, foi atingida no pH 3, a 25 ?C, 800 mg.L-1 e tempo de contato de 150 min, conseguindo remover 99,67% do corante. O modelo cin?tico de pseudo-segunda ordem foi, em geral, o que melhor descreveu o processo de adsor??o, indicando adsor??o qu?mica. A isoterma de Freundlich ajustou melhor os dados experimentais, indicando adsor??o em multicamadas e superf?cie heterog?nea. O estudo termodin?mico indicou que o processo ? endot?rmico, espont?neo e apresentou afinidade entre o adsorvente e o adsorbato. Como conclus?o, o carv?o ativado do endocarpo da amendoeira mostrou-se ser um bom adsorvente para a remo??o do alaranjado de metila.Submitted by Jorge Silva (jorgelmsilva@ufrrj.br) on 2023-01-24T15:41:50Z No. of bitstreams: 1 2020 - Lizeth Vanessa Amado Jurado.pdf: 2179015 bytes, checksum: ba4e7dc875b54a0a8c2cbed9ec0c0802 (MD5)Made available in DSpace on 2023-01-24T15:41:51Z (GMT). No. of bitstreams: 1 2020 - Lizeth Vanessa Amado Jurado.pdf: 2179015 bytes, checksum: ba4e7dc875b54a0a8c2cbed9ec0c0802 (MD5) Previous issue date: 2020-02-12CAPES - Coordena??o de Aperfei?oamento de Pessoal de N?vel Superiorapplication/pdfhttps://tede.ufrrj.br/retrieve/71888/2020%20-%20Lizeth%20Vanessa%20Amado%20Jurado.pdf.jpgporUniversidade Federal Rural do Rio de JaneiroPrograma de P?s-Gradua??o em Engenharia Qu?micaUFRRJBrasilInstituto de TecnologiaAHAMD, M. Z.; EHTISHAM-UL-HAQUE, S.; NISAR, N.; QURESHI, K.; GHAFFAR, A.; ABBAS, M; NISAR, J.; IQBAL, M. Detoxification of photo-catalytically treated 2- chlorophenol: optimization through response surface methodology, Water Sci. Technol. v. 76, n. 2, p. 323-336, 2017. AHARONI, C.; TOMPKINS, F. C. Kinetics of adsorption and desorption and the Elovich equation, Advances in Catalysis. v. 21, p. 1-49, 1970. AHMAD, A.; MOHD-SETAPAR, S. H.; CHUONG, C. S.; KHATOON, A.; WANI, W. A.; KUMAR, R.; RAFATULLAH, M. 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Effect of phosphoric acid on the surface properties and Pb (II) adsorption mechanisms of hydrochars prepared from fresh banana peels. 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dc.title.por.fl_str_mv	Avalia??o da biomassa da Terminalia catappa Linn (amendoeira) como adsorvente: estudo cin?tico e termodin?mico
dc.title.alternative.eng.fl_str_mv	Study of adsorption of dyes by endocarp of Terminalia catappa Linn biomass: kinetics and thermodynamic studies
title	Avalia??o da biomassa da Terminalia catappa Linn (amendoeira) como adsorvente: estudo cin?tico e termodin?mico
spellingShingle	Avalia??o da biomassa da Terminalia catappa Linn (amendoeira) como adsorvente: estudo cin?tico e termodin?mico Jurado, Lizeth Vanessa Amado amendoeira isoterma de equil?brio corante FTIR almond tree equilibrium isotherm dye Engenharia Qu?mica
title_short	Avalia??o da biomassa da Terminalia catappa Linn (amendoeira) como adsorvente: estudo cin?tico e termodin?mico
title_full	Avalia??o da biomassa da Terminalia catappa Linn (amendoeira) como adsorvente: estudo cin?tico e termodin?mico
title_fullStr	Avalia??o da biomassa da Terminalia catappa Linn (amendoeira) como adsorvente: estudo cin?tico e termodin?mico
title_full_unstemmed	Avalia??o da biomassa da Terminalia catappa Linn (amendoeira) como adsorvente: estudo cin?tico e termodin?mico
title_sort	Avalia??o da biomassa da Terminalia catappa Linn (amendoeira) como adsorvente: estudo cin?tico e termodin?mico
author	Jurado, Lizeth Vanessa Amado
author_facet	Jurado, Lizeth Vanessa Amado
author_role	author
dc.contributor.advisor1.fl_str_mv	Mendes, Marisa Fernandes
dc.contributor.advisor1ID.fl_str_mv	023.918.187-50
dc.contributor.advisor1Lattes.fl_str_mv	http://lattes.cnpq.br/3233683706295801
dc.contributor.referee1.fl_str_mv	Mendes, Marisa Fernandes
dc.contributor.referee2.fl_str_mv	Pereira, Karen Signori
dc.contributor.referee3.fl_str_mv	Mancini, Maur?cio Cordeiro
dc.contributor.authorID.fl_str_mv	061.451.687-06 https://orcid.org/0000-0002-7004-7934
dc.contributor.authorLattes.fl_str_mv	http://lattes.cnpq.br/8378851448851020
dc.contributor.author.fl_str_mv	Jurado, Lizeth Vanessa Amado
contributor_str_mv	Mendes, Marisa Fernandes Mendes, Marisa Fernandes Pereira, Karen Signori Mancini, Maur?cio Cordeiro
dc.subject.por.fl_str_mv	amendoeira isoterma de equil?brio corante FTIR almond tree equilibrium isotherm dye
topic	amendoeira isoterma de equil?brio corante FTIR almond tree equilibrium isotherm dye Engenharia Qu?mica
dc.subject.cnpq.fl_str_mv	Engenharia Qu?mica
description	The textile industries are responsible for the disposal of large volumes of effluents, damaging aquatic life and human health. The disposal of wastewater without treatment can modify the natural color of water resources, causing some problems, such as the formation of foams on the surface and an increase in the concentration of toxic substances as dyes. There are different technologies that have been studied to solve this problem, but the adsorption has been an attractive and promising for dye removal due to its advantages such as the possibility to reuse biomaterials, low operating cost, among others. Moreover, the application of alternative adsorbents of residues from biomasses has been increasingly studied. Terminalia catappa Linn (TCL), for example, generates an organic waste such as their fruits, which fall to the ground, and cause manhole clogging in the cities of Rio de Janeiro. Therefore, in this work, it was evaluated the efficiency of the endocarp of the almond fruit as adsorbent in the adsorption process of an organic dye, methyl orange. The adsorption studies were carried out by analyzing the equilibrium and kinetics. The endocarp were evaluated in its natural form, calcinated at 400 ?C, and chemical activated with phosphoric acid (H3PO4). It was observed that the material treated with acid showed the best results with 100% removal of the dye. So, the experiments were done using the activated carbon with H3PO4 varying the initial concentration (200 ? 800 mg.L- 1), temperature (25, 35 and 45 ?C), contact time (0 - 150 min), pH (1 - 11) and addition of sodium chloride (0.5, 0.7, 1.0 and 1.2 g.100 mL-1). The highest adsorptive capacity, 197.87 mg.g-1, was reached at pH 3, at 25 ?C, 800 mg.L-1 and a contact time of 150 min, removing 99.67% of the dye. The pseudo-second order model was, in general, the best that described the adsorption process, wich indicates that adsorption is limited by chemisorption process. The Freundlich isotherm best describes the adsorption of dye, which implies that the adsorption is heterogeneous with multi-layers. The thermodynamic study indicated that the process is endothermic, spontaneous, and the results indicated an affinity between the adsorbent and the adsorbate. Therefore, the activated carbon of the almond endocarp had a good performance, making it a promising adsorbent for the removal of methyl orange.
publishDate	2020
dc.date.issued.fl_str_mv	2020-02-12
dc.date.accessioned.fl_str_mv	2023-01-24T15:41:51Z
dc.type.status.fl_str_mv	info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv	info:eu-repo/semantics/masterThesis
format	masterThesis
status_str	publishedVersion
dc.identifier.citation.fl_str_mv	JURADO, Lizeth Vanessa Amado. Avalia??o da biomassa da Terminalia catappa Linn (amendoeira) como adsorvente: estudo cin?tico e termodin?mico. 2020. 122 f. Disserta??o (Mestrado em Engenharia Qu?mica) - Instituto de Tecnologia, Universidade Federal Rural do Rio de Janeiro, Serop?dica, RJ, 2020.
dc.identifier.uri.fl_str_mv	https://tede.ufrrj.br/jspui/handle/jspui/6254
identifier_str_mv	JURADO, Lizeth Vanessa Amado. Avalia??o da biomassa da Terminalia catappa Linn (amendoeira) como adsorvente: estudo cin?tico e termodin?mico. 2020. 122 f. Disserta??o (Mestrado em Engenharia Qu?mica) - Instituto de Tecnologia, Universidade Federal Rural do Rio de Janeiro, Serop?dica, RJ, 2020.
url	https://tede.ufrrj.br/jspui/handle/jspui/6254
dc.language.iso.fl_str_mv	por
language	por
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Avalia??o da biomassa da Terminalia catappa Linn (amendoeira) como adsorvente: estudo cin?tico e termodin?mico

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