Estudo de catalisadores mesoporosos visando uso na rea??o de desidrata??o do glicerol

Detalhes bibliográficos
Autor(a) principal: Santos, Izadora da Silva
Data de Publicação: 2021
Tipo de documento: Dissertação
Idioma: por
Título da fonte: Biblioteca Digital de Teses e Dissertações da UFRRJ
Texto Completo: https://tede.ufrrj.br/jspui/handle/jspui/6510
Resumo: The reaction of transesterification of oils and fats for biodiesel production generates glycerol as its main by-product, a low-cost and viable raw material for conversion into products with high added value. The glycerol dehydration reaction is an alternative to the partial oxidation of propylene (derived from fossil material) for the production of acrolein and acrylic acid, which makes the commercial development of the biodiesel value chain sustainable. Among the materials used, ZSM-5 zeolite in its acid form and SBA-15 mesoporous silica with natural sites are active catalysts for the glycerol dehydration reaction and selective for the production of acrolein. Thus, the objective of the present work was to synthesize the ZSM-5 zeolite with hierarchical pore structure through the alkaline treatment of desilication in the presence of a surfactant and the mesoporous silica Al-SBA-15 through the direct using different Si/Al to ratios use in the glycerol dehydration reaction. How they were characterized by different techniques to elucidate the influence on the reaction. A crystal structure of the ZSM-5 was confirmed by DRX and FTIR. By XRD and adsorption of N2, it was evidenced the obtainment of silica with highly regular mesopores, characteristic of SBA-15. For ZSM-5 zeolite, highlighted specific area and presence of micro and mesopores. The Al-SBA-15 Al-SBA-15 direct a direct relationship between the Si/Al ratio with a specific area and the volume of mesopores, indicating that the presence of aluminum affects the structure of the material. Through the chemical composition data, it was possible to establish a real Si/Al ratio and the theoretical acidity. ZSM-5 particles are spherical and crystals in plate shape and Al-SBA-15 in a cylindrical shape. The analysis of the physicochemical properties of the synthesized samples indicates that these materials are promising for a possible application in the glycerol dehydration reaction.
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spelling Fernandes, Lindoval Domiciano837.359.257-15http://lattes.cnpq.br/7921814684730923Fernandes, Lindoval DomicianoArroyo, Pedro AugustoMachado Junior, H?lio Fernandes385.854.508-27https://orcid.org/0000-0002-5556-5020http://lattes.cnpq.br/5778858249864254Santos, Izadora da Silva2023-04-12T17:07:44Z2021-07-28SANTOS, Izadora da Silva. Estudo de catalisadores mesoporosos visando uso na rea??o de desidrata??o do glicerol. 2021. 100 f. Disserta??o (Mestrado em Engenharia Qu?mica) - Instituto de Tecnologia, Universidade Federal Rural do Rio de Janeiro, Serop?dica, RJ, 2021.https://tede.ufrrj.br/jspui/handle/jspui/6510The reaction of transesterification of oils and fats for biodiesel production generates glycerol as its main by-product, a low-cost and viable raw material for conversion into products with high added value. The glycerol dehydration reaction is an alternative to the partial oxidation of propylene (derived from fossil material) for the production of acrolein and acrylic acid, which makes the commercial development of the biodiesel value chain sustainable. Among the materials used, ZSM-5 zeolite in its acid form and SBA-15 mesoporous silica with natural sites are active catalysts for the glycerol dehydration reaction and selective for the production of acrolein. Thus, the objective of the present work was to synthesize the ZSM-5 zeolite with hierarchical pore structure through the alkaline treatment of desilication in the presence of a surfactant and the mesoporous silica Al-SBA-15 through the direct using different Si/Al to ratios use in the glycerol dehydration reaction. How they were characterized by different techniques to elucidate the influence on the reaction. A crystal structure of the ZSM-5 was confirmed by DRX and FTIR. By XRD and adsorption of N2, it was evidenced the obtainment of silica with highly regular mesopores, characteristic of SBA-15. For ZSM-5 zeolite, highlighted specific area and presence of micro and mesopores. The Al-SBA-15 Al-SBA-15 direct a direct relationship between the Si/Al ratio with a specific area and the volume of mesopores, indicating that the presence of aluminum affects the structure of the material. Through the chemical composition data, it was possible to establish a real Si/Al ratio and the theoretical acidity. ZSM-5 particles are spherical and crystals in plate shape and Al-SBA-15 in a cylindrical shape. The analysis of the physicochemical properties of the synthesized samples indicates that these materials are promising for a possible application in the glycerol dehydration reaction.A rea??o de transesterifica??o de ?leos e gorduras para produ??o de biodiesel gera como principal subproduto o glicerol, uma mat?ria-prima de baixo custo e vi?vel para convers?o em produtos com alto valor agregado. A rea??o de desidrata??o de glicerol ? uma alternativa ? oxida??o parcial do propileno (derivado de material f?ssil) para a produ??o de acrole?na e ?cido acr?lico, que torna sustent?vel o desenvolvimento comercial da cadeia de valor do biodiesel. Dentre os materiais utilizados, a ze?lita ZSM-5 em sua forma ?cida e a s?lica mesoporosa SBA-15 com s?tios ?cidos s?o catalisadores ativos para a rea??o de desidrata??o do glicerol e seletivos para a produ??o da acrole?na. Dessa forma, o objetivo do presente trabalho foi sintetizar a ze?lita ZSM-5 com estrutura hier?rquica de poros por meio de tratamento alcalino de dessilica??o na presen?a de um surfactante e a s?lica mesoporosa AlSBA-15 pela da s?ntese direta utilizando diferentes raz?es Si/Al para utiliza??o na rea??o de desidrata??o do glicerol. As amostras foram caracterizadas por diferentes t?cnicas para elucidar a influ?ncia na rea??o. A estrutura cristalina das amostras de ZSM-5 foi confirmada por DRX e FTIR. Por DRX e adsor??o de N2 foi evidenciada a obten??o de s?lica com mesoporos altamente regulares, caracter?sticas da SBA-15. Para a ze?lita ZSM-5, mostrou alta ?rea espec?fica e a presen?a de micro e mesoporos. As amostras de AlSBA-15 apresentaram uma rela??o direta entre a raz?o Si/Al com a ?rea espec?fica e o volume de mesoporos, indicando que a presen?a de alum?nio afeta a estrutura do material. A partir dos dados de composi??o qu?mica, foi poss?vel estabelecer a raz?o Si/Al real das amostras e a acidez te?rica. As part?culas de ZSM-5 apresentaram formato esf?rico e cristais em forma de placa e a AlSBA-15 em formato cil?ndrico. A an?lise das propriedades f?sico-qu?micas das amostras sintetizadas indica que esses materiais s?o promissores para uma poss?vel aplica??o na rea??o de desidrata??o do glicerol.Submitted by Jorge Silva (jorgelmsilva@ufrrj.br) on 2023-04-12T17:07:44Z No. of bitstreams: 1 2021 - Izadora da Silva Santos.pdf: 3504671 bytes, checksum: d904b21a431aa53261bdbaab16fd5f37 (MD5)Made available in DSpace on 2023-04-12T17:07:44Z (GMT). No. of bitstreams: 1 2021 - Izadora da Silva Santos.pdf: 3504671 bytes, checksum: d904b21a431aa53261bdbaab16fd5f37 (MD5) Previous issue date: 2021-07-28CAPES - Coordena??o de Aperfei?oamento de Pessoal de N?vel Superiorapplication/pdfhttps://tede.ufrrj.br/retrieve/72922/2021%20-%20Izadora%20da%20Silva%20Santos.pdf.jpgporUniversidade Federal Rural do Rio de JaneiroPrograma de P?s-Gradua??o em Engenharia Qu?micaUFRRJBrasilInstituto de TecnologiaANITHA, M.; KAMARUDIN, S. K.; KOFLI, N. T. The potential of glycerol as a value-added commodity. Chemical Engineering Journal, v. 295, p. 119?130, 2016. ATKINS, P.; JONES, L. Princ?pios de Qu?mica: Questionando a vida moderna e o meio ambienteBookman, 2006. BEN, B. E. N. Relato?rio S?ntese: BEN 2020 - ano base 2019. p. 73, 2020. BHANGE, P.; BHANGE, D. S.; PRADHAN, S.; RAMASWAMY, V. Direct synthesis of well-ordered mesoporous Al-SBA-15 and its correlation with the catalytic activity. Applied Catalysis A: General, v. 400, n. 1?2, p. 176?184, 2011. 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dc.title.por.fl_str_mv Estudo de catalisadores mesoporosos visando uso na rea??o de desidrata??o do glicerol
dc.title.alternative.eng.fl_str_mv Study of mesoporous catalysts for use in the glycerol dehydration reaction
title Estudo de catalisadores mesoporosos visando uso na rea??o de desidrata??o do glicerol
spellingShingle Estudo de catalisadores mesoporosos visando uso na rea??o de desidrata??o do glicerol
Santos, Izadora da Silva
Desidrata??o do glicerol
ZSM-5
Al-SBA-15
dessilica??o
catalisadores mesoposoros
Dehydration of glycerol
desilication
mesoporous catalysts
Engenharia Qu?mica
title_short Estudo de catalisadores mesoporosos visando uso na rea??o de desidrata??o do glicerol
title_full Estudo de catalisadores mesoporosos visando uso na rea??o de desidrata??o do glicerol
title_fullStr Estudo de catalisadores mesoporosos visando uso na rea??o de desidrata??o do glicerol
title_full_unstemmed Estudo de catalisadores mesoporosos visando uso na rea??o de desidrata??o do glicerol
title_sort Estudo de catalisadores mesoporosos visando uso na rea??o de desidrata??o do glicerol
author Santos, Izadora da Silva
author_facet Santos, Izadora da Silva
author_role author
dc.contributor.advisor1.fl_str_mv Fernandes, Lindoval Domiciano
dc.contributor.advisor1ID.fl_str_mv 837.359.257-15
dc.contributor.advisor1Lattes.fl_str_mv http://lattes.cnpq.br/7921814684730923
dc.contributor.referee1.fl_str_mv Fernandes, Lindoval Domiciano
dc.contributor.referee2.fl_str_mv Arroyo, Pedro Augusto
dc.contributor.referee3.fl_str_mv Machado Junior, H?lio Fernandes
dc.contributor.authorID.fl_str_mv 385.854.508-27
https://orcid.org/0000-0002-5556-5020
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/5778858249864254
dc.contributor.author.fl_str_mv Santos, Izadora da Silva
contributor_str_mv Fernandes, Lindoval Domiciano
Fernandes, Lindoval Domiciano
Arroyo, Pedro Augusto
Machado Junior, H?lio Fernandes
dc.subject.por.fl_str_mv Desidrata??o do glicerol
ZSM-5
Al-SBA-15
dessilica??o
catalisadores mesoposoros
topic Desidrata??o do glicerol
ZSM-5
Al-SBA-15
dessilica??o
catalisadores mesoposoros
Dehydration of glycerol
desilication
mesoporous catalysts
Engenharia Qu?mica
dc.subject.eng.fl_str_mv Dehydration of glycerol
desilication
mesoporous catalysts
dc.subject.cnpq.fl_str_mv Engenharia Qu?mica
description The reaction of transesterification of oils and fats for biodiesel production generates glycerol as its main by-product, a low-cost and viable raw material for conversion into products with high added value. The glycerol dehydration reaction is an alternative to the partial oxidation of propylene (derived from fossil material) for the production of acrolein and acrylic acid, which makes the commercial development of the biodiesel value chain sustainable. Among the materials used, ZSM-5 zeolite in its acid form and SBA-15 mesoporous silica with natural sites are active catalysts for the glycerol dehydration reaction and selective for the production of acrolein. Thus, the objective of the present work was to synthesize the ZSM-5 zeolite with hierarchical pore structure through the alkaline treatment of desilication in the presence of a surfactant and the mesoporous silica Al-SBA-15 through the direct using different Si/Al to ratios use in the glycerol dehydration reaction. How they were characterized by different techniques to elucidate the influence on the reaction. A crystal structure of the ZSM-5 was confirmed by DRX and FTIR. By XRD and adsorption of N2, it was evidenced the obtainment of silica with highly regular mesopores, characteristic of SBA-15. For ZSM-5 zeolite, highlighted specific area and presence of micro and mesopores. The Al-SBA-15 Al-SBA-15 direct a direct relationship between the Si/Al ratio with a specific area and the volume of mesopores, indicating that the presence of aluminum affects the structure of the material. Through the chemical composition data, it was possible to establish a real Si/Al ratio and the theoretical acidity. ZSM-5 particles are spherical and crystals in plate shape and Al-SBA-15 in a cylindrical shape. The analysis of the physicochemical properties of the synthesized samples indicates that these materials are promising for a possible application in the glycerol dehydration reaction.
publishDate 2021
dc.date.issued.fl_str_mv 2021-07-28
dc.date.accessioned.fl_str_mv 2023-04-12T17:07:44Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/masterThesis
format masterThesis
status_str publishedVersion
dc.identifier.citation.fl_str_mv SANTOS, Izadora da Silva. Estudo de catalisadores mesoporosos visando uso na rea??o de desidrata??o do glicerol. 2021. 100 f. Disserta??o (Mestrado em Engenharia Qu?mica) - Instituto de Tecnologia, Universidade Federal Rural do Rio de Janeiro, Serop?dica, RJ, 2021.
dc.identifier.uri.fl_str_mv https://tede.ufrrj.br/jspui/handle/jspui/6510
identifier_str_mv SANTOS, Izadora da Silva. Estudo de catalisadores mesoporosos visando uso na rea??o de desidrata??o do glicerol. 2021. 100 f. Disserta??o (Mestrado em Engenharia Qu?mica) - Instituto de Tecnologia, Universidade Federal Rural do Rio de Janeiro, Serop?dica, RJ, 2021.
url https://tede.ufrrj.br/jspui/handle/jspui/6510
dc.language.iso.fl_str_mv por
language por
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