CO2 em zeólita LTA obtida de argila pinheiro do Estado de Sergipe

Detalhes bibliográficos
Autor(a) principal: Ramos, Victor Hugo dos Santos
Data de Publicação: 2019
Tipo de documento: Dissertação
Idioma: por
Título da fonte: Repositório Institucional da UFS
Texto Completo: https://ri.ufs.br/jspui/handle/riufs/17806
Resumo: This study aimed to synthetize the LTA zeolite using Pinheiro clay state of Sergipe (LTA-PIN), currently limited clay for the production of ceramic artifacts, for CO2 adsorption in static system. The Pinheiro clay was treated with HCl for the removal of organic matter and metals. The LTAPIN zeolite was synthesized by two-step route using calcination followed by hydrothermal treatment. The characterization was performed using the techniques of XRD, XRF, SEM, TG/DTA and FT-IR. The main crystalline phases identified in Pinheiro clay were muscovite, ilite, calcite, montmorillonite and quartz. The crystalline restructuring of the clay was evidenced by XRD and the synthesis of LTA zeolite was verified by comparison with the crystallographic cards being obtained with 95.70% of purity. The CO2 adsorption experiments on LTA zeolite were performed using the static volumetric method performed at 25°C, for 1 h, by varying the initial CO2 pressure between 0.05-0.36 MPa using 2 g of adsorbent. The kinetic study showed that the adsorption of CO2 in the pores of the LTA-PIN zeolite occurs in the first 30 min and is best represented by the pseudo second order kinetic model with Qe of 101.26 mg g-1 and k2 of 0.0014 g mg-1 min-1 . The LTA-PIN zeolite presented adsorption capacity of 131.44 mg g-1 with chemical equilibrium described by the Langmuir isotherm indicating chemical adsorption and presenting high regenerative capacity.
id UFS-2_1517066a2039bc3bbef6357c40c18e12
oai_identifier_str oai:ufs.br:riufs/17806
network_acronym_str UFS-2
network_name_str Repositório Institucional da UFS
repository_id_str
spelling Ramos, Victor Hugo dos SantosJesus, Edilson deQuintela, Paulo Henrique Leite2023-07-06T21:51:15Z2023-07-06T21:51:15Z2019-07-24RAMOS, Victor Hugo dos Santos. CO2 em zeólita LTA obtida de argila pinheiro do Estado de Sergipe. 2019. 73 f. Dissertação (Mestrado em Engenharia Química) – Universidade Federal de Sergipe, São Cristóvão, 2019.https://ri.ufs.br/jspui/handle/riufs/17806This study aimed to synthetize the LTA zeolite using Pinheiro clay state of Sergipe (LTA-PIN), currently limited clay for the production of ceramic artifacts, for CO2 adsorption in static system. The Pinheiro clay was treated with HCl for the removal of organic matter and metals. The LTAPIN zeolite was synthesized by two-step route using calcination followed by hydrothermal treatment. The characterization was performed using the techniques of XRD, XRF, SEM, TG/DTA and FT-IR. The main crystalline phases identified in Pinheiro clay were muscovite, ilite, calcite, montmorillonite and quartz. The crystalline restructuring of the clay was evidenced by XRD and the synthesis of LTA zeolite was verified by comparison with the crystallographic cards being obtained with 95.70% of purity. The CO2 adsorption experiments on LTA zeolite were performed using the static volumetric method performed at 25°C, for 1 h, by varying the initial CO2 pressure between 0.05-0.36 MPa using 2 g of adsorbent. The kinetic study showed that the adsorption of CO2 in the pores of the LTA-PIN zeolite occurs in the first 30 min and is best represented by the pseudo second order kinetic model with Qe of 101.26 mg g-1 and k2 of 0.0014 g mg-1 min-1 . The LTA-PIN zeolite presented adsorption capacity of 131.44 mg g-1 with chemical equilibrium described by the Langmuir isotherm indicating chemical adsorption and presenting high regenerative capacity.Este trabalho teve como objetivo obter a zeólita LTA a partir da argila Pinheiro do estado de Sergipe (LTA-PIN), argila atualmente limitada para a produção de artefatos cerâmicos, para a adsorção de CO2 em sistema estático. A argila Pinheiro foi tratada com HCl para a remoção de matéria orgânica e de metais. A zeólita LTA foi sintetizada por rota com duas etapas, utilizando calcinação seguida de tratamento hidrotérmico. A caracterização foi feita mediante as técnicas de DRX, FRX, MEV, TG/DTA e FTIR. As principais fases cristalinas identificadas na argila Pinheiro foram muscovita, ilita, calcita, montmorilonita e quartzo. A reestruturação cristalina da argila foi evidenciada por DRX sendo comprovada a síntese de zeólita LTA por comparação com as fichas cristalográficas sendo obtida com 95,79% de pureza. Os ensaios de adsorção de CO2 em zeólita LTA foram realizados utilizando o método volumétrico estático realizados à temperatura de 25˚C, tempo de 1 hora, variando a pressão inicial de CO2 entre a faixa de 0,05-0,36 MPa utilizando 2 g de adsorvente. O estudo cinético mostrou que a adsorção de CO2 nos poros da zeólita LTA-PIN ocorre nos primeiros 30 minutos sendo melhor representada pelo modelo cinético de pseudosegunda ordem apresentando Qe de 101,26 mg g-1 e k2 de 0,0014 g mg-1 min-1 . A zeólita LTA-PIN apresentou capacidade adsortiva de 131,44 mg g-1 com equilibrio químico descrito pela isoterma de Langmuir indicando adsorção química e apresentando alta capacidade regenerativa.Fundação de Apoio a Pesquisa e à Inovação Tecnológica do Estado de Sergipe - FAPITEC/SESão CristóvãoporEngenharia químicaZeolitosArgilaDióxido de carbonoSergipe (SE)Zeólita LTAArgila PinheiroCO2LTA zeolitePinheiro clayENGENHARIAS::ENGENHARIA QUIMICACO2 em zeólita LTA obtida de argila pinheiro do Estado de Sergipeinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisPós-Graduação em Engenharia QuímicaUniversidade Federal de Sergipe (UFS)reponame:Repositório Institucional da UFSinstname:Universidade Federal de Sergipe (UFS)instacron:UFSinfo:eu-repo/semantics/openAccessLICENSElicense.txtlicense.txttext/plain; charset=utf-81475https://ri.ufs.br/jspui/bitstream/riufs/17806/1/license.txt098cbbf65c2c15e1fb2e49c5d306a44cMD51ORIGINALVICTOR_HUGO_SANTOS_RAMOS.pdfVICTOR_HUGO_SANTOS_RAMOS.pdfapplication/pdf2474637https://ri.ufs.br/jspui/bitstream/riufs/17806/2/VICTOR_HUGO_SANTOS_RAMOS.pdf8d7ca775cef1b84b5354ff35ae010724MD52TEXTVICTOR_HUGO_SANTOS_RAMOS.pdf.txtVICTOR_HUGO_SANTOS_RAMOS.pdf.txtExtracted texttext/plain98773https://ri.ufs.br/jspui/bitstream/riufs/17806/3/VICTOR_HUGO_SANTOS_RAMOS.pdf.txt397365410805a58114bdecd795a63f31MD53THUMBNAILVICTOR_HUGO_SANTOS_RAMOS.pdf.jpgVICTOR_HUGO_SANTOS_RAMOS.pdf.jpgGenerated Thumbnailimage/jpeg1259https://ri.ufs.br/jspui/bitstream/riufs/17806/4/VICTOR_HUGO_SANTOS_RAMOS.pdf.jpg2664af8e88dc5b210ad2e8ef1e82ebe9MD54riufs/178062023-07-06 18:51:20.768oai:ufs.br:riufs/17806TElDRU7Dh0EgREUgRElTVFJJQlVJw4fDg08gTsODTy1FWENMVVNJVkEKCkNvbSBhIGFwcmVzZW50YcOnw6NvIGRlc3RhIGxpY2Vuw6dhLCB2b2PDqiAobyBhdXRvcihlcykgb3UgbyB0aXR1bGFyIGRvcyBkaXJlaXRvcyBkZSBhdXRvcikgY29uY2VkZSDDoCBVbml2ZXJzaWRhZGUgRmVkZXJhbCBkZSBTZXJnaXBlIG8gZGlyZWl0byBuw6NvLWV4Y2x1c2l2byBkZSByZXByb2R1emlyIHNldSB0cmFiYWxobyBubyBmb3JtYXRvIGVsZXRyw7RuaWNvLCBpbmNsdWluZG8gb3MgZm9ybWF0b3Mgw6F1ZGlvIG91IHbDrWRlby4KClZvY8OqIGNvbmNvcmRhIHF1ZSBhIFVuaXZlcnNpZGFkZSBGZWRlcmFsIGRlIFNlcmdpcGUgcG9kZSwgc2VtIGFsdGVyYXIgbyBjb250ZcO6ZG8sIHRyYW5zcG9yIHNldSB0cmFiYWxobyBwYXJhIHF1YWxxdWVyIG1laW8gb3UgZm9ybWF0byBwYXJhIGZpbnMgZGUgcHJlc2VydmHDp8Ojby4KClZvY8OqIHRhbWLDqW0gY29uY29yZGEgcXVlIGEgVW5pdmVyc2lkYWRlIEZlZGVyYWwgZGUgU2VyZ2lwZSBwb2RlIG1hbnRlciBtYWlzIGRlIHVtYSBjw7NwaWEgZGUgc2V1IHRyYWJhbGhvIHBhcmEgZmlucyBkZSBzZWd1cmFuw6dhLCBiYWNrLXVwIGUgcHJlc2VydmHDp8Ojby4KClZvY8OqIGRlY2xhcmEgcXVlIHNldSB0cmFiYWxobyDDqSBvcmlnaW5hbCBlIHF1ZSB2b2PDqiB0ZW0gbyBwb2RlciBkZSBjb25jZWRlciBvcyBkaXJlaXRvcyBjb250aWRvcyBuZXN0YSBsaWNlbsOnYS4gVm9jw6ogdGFtYsOpbSBkZWNsYXJhIHF1ZSBvIGRlcMOzc2l0bywgcXVlIHNlamEgZGUgc2V1IGNvbmhlY2ltZW50bywgbsOjbyBpbmZyaW5nZSBkaXJlaXRvcyBhdXRvcmFpcyBkZSBuaW5ndcOpbS4KCkNhc28gbyB0cmFiYWxobyBjb250ZW5oYSBtYXRlcmlhbCBxdWUgdm9jw6ogbsOjbyBwb3NzdWkgYSB0aXR1bGFyaWRhZGUgZG9zIGRpcmVpdG9zIGF1dG9yYWlzLCB2b2PDqiBkZWNsYXJhIHF1ZSBvYnRldmUgYSBwZXJtaXNzw6NvIGlycmVzdHJpdGEgZG8gZGV0ZW50b3IgZG9zIGRpcmVpdG9zIGF1dG9yYWlzIHBhcmEgY29uY2VkZXIgw6AgVW5pdmVyc2lkYWRlIEZlZGVyYWwgZGUgU2VyZ2lwZSBvcyBkaXJlaXRvcyBhcHJlc2VudGFkb3MgbmVzdGEgbGljZW7Dp2EsIGUgcXVlIGVzc2UgbWF0ZXJpYWwgZGUgcHJvcHJpZWRhZGUgZGUgdGVyY2Vpcm9zIGVzdMOhIGNsYXJhbWVudGUgaWRlbnRpZmljYWRvIGUgcmVjb25oZWNpZG8gbm8gdGV4dG8gb3Ugbm8gY29udGXDumRvLgoKQSBVbml2ZXJzaWRhZGUgRmVkZXJhbCBkZSBTZXJnaXBlIHNlIGNvbXByb21ldGUgYSBpZGVudGlmaWNhciBjbGFyYW1lbnRlIG8gc2V1IG5vbWUocykgb3UgbyhzKSBub21lKHMpIGRvKHMpIApkZXRlbnRvcihlcykgZG9zIGRpcmVpdG9zIGF1dG9yYWlzIGRvIHRyYWJhbGhvLCBlIG7Do28gZmFyw6EgcXVhbHF1ZXIgYWx0ZXJhw6fDo28sIGFsw6ltIGRhcXVlbGFzIGNvbmNlZGlkYXMgcG9yIGVzdGEgbGljZW7Dp2EuIAo=Repositório InstitucionalPUBhttps://ri.ufs.br/oai/requestrepositorio@academico.ufs.bropendoar:2023-07-06T21:51:20Repositório Institucional da UFS - Universidade Federal de Sergipe (UFS)false
dc.title.pt_BR.fl_str_mv CO2 em zeólita LTA obtida de argila pinheiro do Estado de Sergipe
title CO2 em zeólita LTA obtida de argila pinheiro do Estado de Sergipe
spellingShingle CO2 em zeólita LTA obtida de argila pinheiro do Estado de Sergipe
Ramos, Victor Hugo dos Santos
Engenharia química
Zeolitos
Argila
Dióxido de carbono
Sergipe (SE)
Zeólita LTA
Argila Pinheiro
CO2
LTA zeolite
Pinheiro clay
ENGENHARIAS::ENGENHARIA QUIMICA
title_short CO2 em zeólita LTA obtida de argila pinheiro do Estado de Sergipe
title_full CO2 em zeólita LTA obtida de argila pinheiro do Estado de Sergipe
title_fullStr CO2 em zeólita LTA obtida de argila pinheiro do Estado de Sergipe
title_full_unstemmed CO2 em zeólita LTA obtida de argila pinheiro do Estado de Sergipe
title_sort CO2 em zeólita LTA obtida de argila pinheiro do Estado de Sergipe
author Ramos, Victor Hugo dos Santos
author_facet Ramos, Victor Hugo dos Santos
author_role author
dc.contributor.author.fl_str_mv Ramos, Victor Hugo dos Santos
dc.contributor.advisor1.fl_str_mv Jesus, Edilson de
dc.contributor.advisor-co1.fl_str_mv Quintela, Paulo Henrique Leite
contributor_str_mv Jesus, Edilson de
Quintela, Paulo Henrique Leite
dc.subject.por.fl_str_mv Engenharia química
Zeolitos
Argila
Dióxido de carbono
Sergipe (SE)
Zeólita LTA
Argila Pinheiro
CO2
topic Engenharia química
Zeolitos
Argila
Dióxido de carbono
Sergipe (SE)
Zeólita LTA
Argila Pinheiro
CO2
LTA zeolite
Pinheiro clay
ENGENHARIAS::ENGENHARIA QUIMICA
dc.subject.eng.fl_str_mv LTA zeolite
Pinheiro clay
dc.subject.cnpq.fl_str_mv ENGENHARIAS::ENGENHARIA QUIMICA
description This study aimed to synthetize the LTA zeolite using Pinheiro clay state of Sergipe (LTA-PIN), currently limited clay for the production of ceramic artifacts, for CO2 adsorption in static system. The Pinheiro clay was treated with HCl for the removal of organic matter and metals. The LTAPIN zeolite was synthesized by two-step route using calcination followed by hydrothermal treatment. The characterization was performed using the techniques of XRD, XRF, SEM, TG/DTA and FT-IR. The main crystalline phases identified in Pinheiro clay were muscovite, ilite, calcite, montmorillonite and quartz. The crystalline restructuring of the clay was evidenced by XRD and the synthesis of LTA zeolite was verified by comparison with the crystallographic cards being obtained with 95.70% of purity. The CO2 adsorption experiments on LTA zeolite were performed using the static volumetric method performed at 25°C, for 1 h, by varying the initial CO2 pressure between 0.05-0.36 MPa using 2 g of adsorbent. The kinetic study showed that the adsorption of CO2 in the pores of the LTA-PIN zeolite occurs in the first 30 min and is best represented by the pseudo second order kinetic model with Qe of 101.26 mg g-1 and k2 of 0.0014 g mg-1 min-1 . The LTA-PIN zeolite presented adsorption capacity of 131.44 mg g-1 with chemical equilibrium described by the Langmuir isotherm indicating chemical adsorption and presenting high regenerative capacity.
publishDate 2019
dc.date.issued.fl_str_mv 2019-07-24
dc.date.accessioned.fl_str_mv 2023-07-06T21:51:15Z
dc.date.available.fl_str_mv 2023-07-06T21:51:15Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/masterThesis
format masterThesis
status_str publishedVersion
dc.identifier.citation.fl_str_mv RAMOS, Victor Hugo dos Santos. CO2 em zeólita LTA obtida de argila pinheiro do Estado de Sergipe. 2019. 73 f. Dissertação (Mestrado em Engenharia Química) – Universidade Federal de Sergipe, São Cristóvão, 2019.
dc.identifier.uri.fl_str_mv https://ri.ufs.br/jspui/handle/riufs/17806
identifier_str_mv RAMOS, Victor Hugo dos Santos. CO2 em zeólita LTA obtida de argila pinheiro do Estado de Sergipe. 2019. 73 f. Dissertação (Mestrado em Engenharia Química) – Universidade Federal de Sergipe, São Cristóvão, 2019.
url https://ri.ufs.br/jspui/handle/riufs/17806
dc.language.iso.fl_str_mv por
language por
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.program.fl_str_mv Pós-Graduação em Engenharia Química
dc.publisher.initials.fl_str_mv Universidade Federal de Sergipe (UFS)
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFS
instname:Universidade Federal de Sergipe (UFS)
instacron:UFS
instname_str Universidade Federal de Sergipe (UFS)
instacron_str UFS
institution UFS
reponame_str Repositório Institucional da UFS
collection Repositório Institucional da UFS
bitstream.url.fl_str_mv https://ri.ufs.br/jspui/bitstream/riufs/17806/1/license.txt
https://ri.ufs.br/jspui/bitstream/riufs/17806/2/VICTOR_HUGO_SANTOS_RAMOS.pdf
https://ri.ufs.br/jspui/bitstream/riufs/17806/3/VICTOR_HUGO_SANTOS_RAMOS.pdf.txt
https://ri.ufs.br/jspui/bitstream/riufs/17806/4/VICTOR_HUGO_SANTOS_RAMOS.pdf.jpg
bitstream.checksum.fl_str_mv 098cbbf65c2c15e1fb2e49c5d306a44c
8d7ca775cef1b84b5354ff35ae010724
397365410805a58114bdecd795a63f31
2664af8e88dc5b210ad2e8ef1e82ebe9
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
MD5
MD5
repository.name.fl_str_mv Repositório Institucional da UFS - Universidade Federal de Sergipe (UFS)
repository.mail.fl_str_mv repositorio@academico.ufs.br
_version_ 1802110674981093376