A One-dimensional coordination polymer constructed from isatine-3-oximate and sodium
Autor(a) principal: | |
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Data de Publicação: | 2011 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFS |
Texto Completo: | http://scripts.iucr.org/cgi-bin/paper?S1600536811018290 https://ri.ufs.br/handle/riufs/630 |
Resumo: | The reaction of hydroxylamine hydrochloride with isatin in ethanol, catalysed with HCl and neutralized with Na2CO3, yielded the one-dimensional coordination polymer, catena-poly[[[aquasodium]-di-μ-aqua-[aquasodium]-bis(μ-2-oxoindoline-2,3-dione 3-oximato)] tetrakis(oxoindoline-2,3-dione 3-oxime)], {[Na(C8H5N2O2)(H2O)2]·2C8H6N2O2}n. The NaI atom has a six-coordinate distorted-octahedral environment. Isatine-3-oximate O atoms and water molecules bridge adjacent Na atoms, forming a one-dimensional polymeric structure parallel to [100]. Each isatine-3-oxime dimerizes through N—HO interactions and in addition each oxime is linked to a coordination polymer. Thus, coordination polymers are linked by O—HO and O—HN interactions from isatine-3-oxime dimers, building a two-dimensional network parallel to [110]. |
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Martins, Bianca BarretoBresolin, LeandroCarratu, Vanessa SantanaBehm, Mariana BonebergerOliveira, Adriano Bof de2013-07-02T00:04:18Z2013-07-02T00:04:18Z2011-05MARTINS, B. B. et al. A One-dimensional coordination polymer constructed from isatine-3-oximate and sodium. Acta Crystallographica Section E, Copenhague, v. 67, n. 6, p. m790-m791, jun. 2011. Disponível em: <http://europepmc.org/articles/PMC3120341>. Acesso em: 1 jul. 2013.1600-5368http://scripts.iucr.org/cgi-bin/paper?S1600536811018290https://ri.ufs.br/handle/riufs/630© International Union of CrystallographyThe reaction of hydroxylamine hydrochloride with isatin in ethanol, catalysed with HCl and neutralized with Na2CO3, yielded the one-dimensional coordination polymer, catena-poly[[[aquasodium]-di-μ-aqua-[aquasodium]-bis(μ-2-oxoindoline-2,3-dione 3-oximato)] tetrakis(oxoindoline-2,3-dione 3-oxime)], {[Na(C8H5N2O2)(H2O)2]·2C8H6N2O2}n. The NaI atom has a six-coordinate distorted-octahedral environment. Isatine-3-oximate O atoms and water molecules bridge adjacent Na atoms, forming a one-dimensional polymeric structure parallel to [100]. Each isatine-3-oxime dimerizes through N—HO interactions and in addition each oxime is linked to a coordination polymer. Thus, coordination polymers are linked by O—HO and O—HN interactions from isatine-3-oxime dimers, building a two-dimensional network parallel to [110].HidroxilaminaIsatinaEtanolCarbonato de sódioPolímeros de coordenação unidimensionalA One-dimensional coordination polymer constructed from isatine-3-oximate and sodiuminfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleengreponame:Repositório Institucional da UFSinstname:Universidade Federal de Sergipe (UFS)instacron:UFSinfo:eu-repo/semantics/openAccessTHUMBNAILOneDimensionalPolymer.pdf.jpgOneDimensionalPolymer.pdf.jpgGenerated Thumbnailimage/jpeg1650https://ri.ufs.br/jspui/bitstream/riufs/630/4/OneDimensionalPolymer.pdf.jpgc514a5fe14d6b7ec4b9953dd981d1b7bMD54ORIGINALOneDimensionalPolymer.pdfOneDimensionalPolymer.pdfapplication/pdf785829https://ri.ufs.br/jspui/bitstream/riufs/630/1/OneDimensionalPolymer.pdf47f6e2577ed1f577fc2381eba62ef58cMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://ri.ufs.br/jspui/bitstream/riufs/630/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52TEXTOneDimensionalPolymer.pdf.txtOneDimensionalPolymer.pdf.txtExtracted texttext/plain25014https://ri.ufs.br/jspui/bitstream/riufs/630/3/OneDimensionalPolymer.pdf.txtd21be99e2162bf38f25694d389379593MD53riufs/6302013-07-02 02:00:07.142oai:ufs.br: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Repositório InstitucionalPUBhttps://ri.ufs.br/oai/requestrepositorio@academico.ufs.bropendoar:2013-07-02T05:00:07Repositório Institucional da UFS - Universidade Federal de Sergipe (UFS)false |
dc.title.pt_BR.fl_str_mv |
A One-dimensional coordination polymer constructed from isatine-3-oximate and sodium |
title |
A One-dimensional coordination polymer constructed from isatine-3-oximate and sodium |
spellingShingle |
A One-dimensional coordination polymer constructed from isatine-3-oximate and sodium Martins, Bianca Barreto Hidroxilamina Isatina Etanol Carbonato de sódio Polímeros de coordenação unidimensional |
title_short |
A One-dimensional coordination polymer constructed from isatine-3-oximate and sodium |
title_full |
A One-dimensional coordination polymer constructed from isatine-3-oximate and sodium |
title_fullStr |
A One-dimensional coordination polymer constructed from isatine-3-oximate and sodium |
title_full_unstemmed |
A One-dimensional coordination polymer constructed from isatine-3-oximate and sodium |
title_sort |
A One-dimensional coordination polymer constructed from isatine-3-oximate and sodium |
author |
Martins, Bianca Barreto |
author_facet |
Martins, Bianca Barreto Bresolin, Leandro Carratu, Vanessa Santana Behm, Mariana Boneberger Oliveira, Adriano Bof de |
author_role |
author |
author2 |
Bresolin, Leandro Carratu, Vanessa Santana Behm, Mariana Boneberger Oliveira, Adriano Bof de |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Martins, Bianca Barreto Bresolin, Leandro Carratu, Vanessa Santana Behm, Mariana Boneberger Oliveira, Adriano Bof de |
dc.subject.por.fl_str_mv |
Hidroxilamina Isatina Etanol Carbonato de sódio Polímeros de coordenação unidimensional |
topic |
Hidroxilamina Isatina Etanol Carbonato de sódio Polímeros de coordenação unidimensional |
description |
The reaction of hydroxylamine hydrochloride with isatin in ethanol, catalysed with HCl and neutralized with Na2CO3, yielded the one-dimensional coordination polymer, catena-poly[[[aquasodium]-di-μ-aqua-[aquasodium]-bis(μ-2-oxoindoline-2,3-dione 3-oximato)] tetrakis(oxoindoline-2,3-dione 3-oxime)], {[Na(C8H5N2O2)(H2O)2]·2C8H6N2O2}n. The NaI atom has a six-coordinate distorted-octahedral environment. Isatine-3-oximate O atoms and water molecules bridge adjacent Na atoms, forming a one-dimensional polymeric structure parallel to [100]. Each isatine-3-oxime dimerizes through N—HO interactions and in addition each oxime is linked to a coordination polymer. Thus, coordination polymers are linked by O—HO and O—HN interactions from isatine-3-oxime dimers, building a two-dimensional network parallel to [110]. |
publishDate |
2011 |
dc.date.issued.fl_str_mv |
2011-05 |
dc.date.accessioned.fl_str_mv |
2013-07-02T00:04:18Z |
dc.date.available.fl_str_mv |
2013-07-02T00:04:18Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
MARTINS, B. B. et al. A One-dimensional coordination polymer constructed from isatine-3-oximate and sodium. Acta Crystallographica Section E, Copenhague, v. 67, n. 6, p. m790-m791, jun. 2011. Disponível em: <http://europepmc.org/articles/PMC3120341>. Acesso em: 1 jul. 2013. |
dc.identifier.uri.fl_str_mv |
http://scripts.iucr.org/cgi-bin/paper?S1600536811018290 https://ri.ufs.br/handle/riufs/630 |
dc.identifier.issn.none.fl_str_mv |
1600-5368 |
dc.identifier.license.pt_BR.fl_str_mv |
© International Union of Crystallography |
identifier_str_mv |
MARTINS, B. B. et al. A One-dimensional coordination polymer constructed from isatine-3-oximate and sodium. Acta Crystallographica Section E, Copenhague, v. 67, n. 6, p. m790-m791, jun. 2011. Disponível em: <http://europepmc.org/articles/PMC3120341>. Acesso em: 1 jul. 2013. 1600-5368 © International Union of Crystallography |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811018290 https://ri.ufs.br/handle/riufs/630 |
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eng |
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