Influência de adições de grafeno e nanocompósitos Cds-diatomita nas propriedades autolimpantes de argamassa para rejuntamento
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Tipo de documento: | Dissertação |
Idioma: | por |
Título da fonte: | Repositório Institucional da UFS |
Texto Completo: | http://ri.ufs.br/jspui/handle/riufs/13133 |
Resumo: | The evaluation of the functionality of graphene and CdS/diatomite nanocomposite as mortar additives for self-cleaning properties was carried out with the preparation of mixtures of a nanocomposite of cadmium sulphide (CdS) anchored in diatomite and graphene nanoplates in 1.5% and 2.5% of graphene by weight of nanocomposite. The self-cleaning mortars were prepared by adding graphene, the CdS nanocomposites and the CdS/graphene mixtures in a commercial cementitious joint mortar, with the main goal of promoting microalgae inhibition. Starting materials and mortars were characterized by X-ray diffraction, Raman, infrared and diffuse reflectance UV-vis spectroscopies. The photocatalytic activity was evaluated from methylene blue dye degradation assays in the presence and absence of UV-A radiation, as well as tests of chlorophyll degradation of a biofilm composed of Chlorella vulgaris and Scenedesmus sp., and its growth inhibition. The results indicate that the modified mortars with CdS/graphene mixtures obtained the best photocatalytic responses, degrading approximately 18% of the dye in six hours of testing, approximately 8% more than those mortars modified with the pure CdS nanocomposite. Regarding the biofilm degradation and its inhibition, the pure graphene modified mortar was the most efficient. In chlorophyll degradation tests on biofilms, this sample is presented the whitest gray level. The microalgae growth inhibition test showed that the sample modified only with graphene had, on average, 2.5% micoalgae coverage by the end of 8 weeks of testing, while the control sample presented an average 87% of algae coverage. This result was pointed out in the chlorophyll degradation test, in which RG sample presented the whitest gray level, therefore, it was the most efficient in the biofilm degradation. |
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Prudente, Isis Nayra RolembergBarreto, Ledjane Silva2020-03-24T14:01:13Z2020-03-24T14:01:13Z2020-01-28PRUDENTE, Isis Nayra Rolemberg. Influência de adições de grafeno e nanocompósitos Cds-diatomita nas propriedades autolimpantes de argamassa para rejuntamento. 2019. 108 f. Dissertação (Mestrado em Ciência e Engenharia de Materiais) – Universidade Federal de Sergipe, São Cristóvão, SE, 2020.http://ri.ufs.br/jspui/handle/riufs/13133The evaluation of the functionality of graphene and CdS/diatomite nanocomposite as mortar additives for self-cleaning properties was carried out with the preparation of mixtures of a nanocomposite of cadmium sulphide (CdS) anchored in diatomite and graphene nanoplates in 1.5% and 2.5% of graphene by weight of nanocomposite. The self-cleaning mortars were prepared by adding graphene, the CdS nanocomposites and the CdS/graphene mixtures in a commercial cementitious joint mortar, with the main goal of promoting microalgae inhibition. Starting materials and mortars were characterized by X-ray diffraction, Raman, infrared and diffuse reflectance UV-vis spectroscopies. The photocatalytic activity was evaluated from methylene blue dye degradation assays in the presence and absence of UV-A radiation, as well as tests of chlorophyll degradation of a biofilm composed of Chlorella vulgaris and Scenedesmus sp., and its growth inhibition. The results indicate that the modified mortars with CdS/graphene mixtures obtained the best photocatalytic responses, degrading approximately 18% of the dye in six hours of testing, approximately 8% more than those mortars modified with the pure CdS nanocomposite. Regarding the biofilm degradation and its inhibition, the pure graphene modified mortar was the most efficient. In chlorophyll degradation tests on biofilms, this sample is presented the whitest gray level. The microalgae growth inhibition test showed that the sample modified only with graphene had, on average, 2.5% micoalgae coverage by the end of 8 weeks of testing, while the control sample presented an average 87% of algae coverage. This result was pointed out in the chlorophyll degradation test, in which RG sample presented the whitest gray level, therefore, it was the most efficient in the biofilm degradation.A avaliação da funcionalidade do grafeno e do nanocompósito de CdS-diatomita para autolimpeza de argamassas de rejuntamento foi realizada com a preparação de misturas de um nanocompósito de sulfeto de cádmio (CdS) ancorado em diatomita e nanoplacas de grafeno, em concentrações 1,5% e 2,5% de grafeno em peso do nanocompósito. As argamassas autolimpantes foram obtidas pela adição das misturas e seus precursores em uma argamassa comercial de rejuntamento visando principalmente a inibição do crescimento de microalgas. Os materiais de partida e argamassas foram caracterizados por difração de raio X, espectroscopias Raman, infravermelho e UV-vis por reflectância difusa. A atividade fotocatalítica foi avaliada a partir de ensaios de degradação do corante azul de metileno na presença e na ausência de radiação UV-A, bem como a capacidade desses materiais em degradar a clorofila de um biofilme formado pelas algas Chlorella vulgaris e Scenedesmus sp. e inibir o crescimento desses organismos. Os resultados apontam que as argamassas modificadas com as misturas do nanocompósito de CdS e grafeno obtiveram as melhores respostas fotocatalíticas, degradando aproximadamente 18% do corante em seis horas de ensaio, com uma média de 8% a mais que os rejuntes modificados apenas com o nanocompósito de sulfeto de cádmio. O teste de inibição do crescimento das microalgas mostrou que as amostras contendo apenas grafeno apresentaram, em média, 2,5% de cobertura pelo biofilme ao fim de 8 semanas de ensaio, enquanto as demais composições apresentou média superior a 87%. Esse resultado foi evidenciado nos testes de degradação de clorofila dos biofilmes, onde essas amostras apresentaram filmes com nível de cinza mais próximos do branco, portanto, sendo mais eficiente na degradação do biofilme de algas.Conselho Nacional de Pesquisa e Desenvolvimento Científico e Tecnológico - CNPqCoordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPESFinanciadora de Estudos e Projetos - FinepFundação de Apoio a Pesquisa e à Inovação Tecnológica do Estado de Sergipe - FAPITEC/SESão Cristóvão, SEporEngenharia de materiaisArgamassaRejuntamentoCatáliseAlgasNanocompósitos (Materiais)FotocatáliseChlorella vulgarisScenedesmus spGrafenoNanocompósito CdS-diatomitaMortarsJointPhotocatalysisAlgaeGrapheneCdS-diatomite nanocompositeENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICAInfluência de adições de grafeno e nanocompósitos Cds-diatomita nas propriedades autolimpantes de argamassa para rejuntamentoInfluence of CdS-diatomite nanocomposite and graphene additions on self-cleaning mortarsisisinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisPós-Graduação em Ciência e Engenharia de MateriaisUnivesidade Federal de Sergipereponame:Repositório Institucional da UFSinstname:Universidade Federal de Sergipe (UFS)instacron:UFSinfo:eu-repo/semantics/openAccessTEXTISIS_NAYRA_ROLEMBERG_PRUDENTE.pdf.txtISIS_NAYRA_ROLEMBERG_PRUDENTE.pdf.txtExtracted texttext/plain202515https://ri.ufs.br/jspui/bitstream/riufs/13133/3/ISIS_NAYRA_ROLEMBERG_PRUDENTE.pdf.txtc7b99d3182ba953f7ac55923c13292c2MD53THUMBNAILISIS_NAYRA_ROLEMBERG_PRUDENTE.pdf.jpgISIS_NAYRA_ROLEMBERG_PRUDENTE.pdf.jpgGenerated Thumbnailimage/jpeg1321https://ri.ufs.br/jspui/bitstream/riufs/13133/4/ISIS_NAYRA_ROLEMBERG_PRUDENTE.pdf.jpg8c36eedf1c4c911901a801eb14df6679MD54ORIGINALISIS_NAYRA_ROLEMBERG_PRUDENTE.pdfISIS_NAYRA_ROLEMBERG_PRUDENTE.pdfapplication/pdf4697229https://ri.ufs.br/jspui/bitstream/riufs/13133/2/ISIS_NAYRA_ROLEMBERG_PRUDENTE.pdf29ab5e071a2c3fe6cb113c1f76ffe148MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81475https://ri.ufs.br/jspui/bitstream/riufs/13133/1/license.txt098cbbf65c2c15e1fb2e49c5d306a44cMD51riufs/131332021-11-16 08:55:02.761oai:ufs.br:riufs/13133TElDRU7Dh0EgREUgRElTVFJJQlVJw4fDg08gTsODTy1FWENMVVNJVkEKCkNvbSBhIGFwcmVzZW50YcOnw6NvIGRlc3RhIGxpY2Vuw6dhLCB2b2PDqiAobyBhdXRvcihlcykgb3UgbyB0aXR1bGFyIGRvcyBkaXJlaXRvcyBkZSBhdXRvcikgY29uY2VkZSDDoCBVbml2ZXJzaWRhZGUgRmVkZXJhbCBkZSBTZXJnaXBlIG8gZGlyZWl0byBuw6NvLWV4Y2x1c2l2byBkZSByZXByb2R1emlyIHNldSB0cmFiYWxobyBubyBmb3JtYXRvIGVsZXRyw7RuaWNvLCBpbmNsdWluZG8gb3MgZm9ybWF0b3Mgw6F1ZGlvIG91IHbDrWRlby4KClZvY8OqIGNvbmNvcmRhIHF1ZSBhIFVuaXZlcnNpZGFkZSBGZWRlcmFsIGRlIFNlcmdpcGUgcG9kZSwgc2VtIGFsdGVyYXIgbyBjb250ZcO6ZG8sIHRyYW5zcG9yIHNldSB0cmFiYWxobyBwYXJhIHF1YWxxdWVyIG1laW8gb3UgZm9ybWF0byBwYXJhIGZpbnMgZGUgcHJlc2VydmHDp8Ojby4KClZvY8OqIHRhbWLDqW0gY29uY29yZGEgcXVlIGEgVW5pdmVyc2lkYWRlIEZlZGVyYWwgZGUgU2VyZ2lwZSBwb2RlIG1hbnRlciBtYWlzIGRlIHVtYSBjw7NwaWEgZGUgc2V1IHRyYWJhbGhvIHBhcmEgZmlucyBkZSBzZWd1cmFuw6dhLCBiYWNrLXVwIGUgcHJlc2VydmHDp8Ojby4KClZvY8OqIGRlY2xhcmEgcXVlIHNldSB0cmFiYWxobyDDqSBvcmlnaW5hbCBlIHF1ZSB2b2PDqiB0ZW0gbyBwb2RlciBkZSBjb25jZWRlciBvcyBkaXJlaXRvcyBjb250aWRvcyBuZXN0YSBsaWNlbsOnYS4gVm9jw6ogdGFtYsOpbSBkZWNsYXJhIHF1ZSBvIGRlcMOzc2l0bywgcXVlIHNlamEgZGUgc2V1IGNvbmhlY2ltZW50bywgbsOjbyBpbmZyaW5nZSBkaXJlaXRvcyBhdXRvcmFpcyBkZSBuaW5ndcOpbS4KCkNhc28gbyB0cmFiYWxobyBjb250ZW5oYSBtYXRlcmlhbCBxdWUgdm9jw6ogbsOjbyBwb3NzdWkgYSB0aXR1bGFyaWRhZGUgZG9zIGRpcmVpdG9zIGF1dG9yYWlzLCB2b2PDqiBkZWNsYXJhIHF1ZSBvYnRldmUgYSBwZXJtaXNzw6NvIGlycmVzdHJpdGEgZG8gZGV0ZW50b3IgZG9zIGRpcmVpdG9zIGF1dG9yYWlzIHBhcmEgY29uY2VkZXIgw6AgVW5pdmVyc2lkYWRlIEZlZGVyYWwgZGUgU2VyZ2lwZSBvcyBkaXJlaXRvcyBhcHJlc2VudGFkb3MgbmVzdGEgbGljZW7Dp2EsIGUgcXVlIGVzc2UgbWF0ZXJpYWwgZGUgcHJvcHJpZWRhZGUgZGUgdGVyY2Vpcm9zIGVzdMOhIGNsYXJhbWVudGUgaWRlbnRpZmljYWRvIGUgcmVjb25oZWNpZG8gbm8gdGV4dG8gb3Ugbm8gY29udGXDumRvLgoKQSBVbml2ZXJzaWRhZGUgRmVkZXJhbCBkZSBTZXJnaXBlIHNlIGNvbXByb21ldGUgYSBpZGVudGlmaWNhciBjbGFyYW1lbnRlIG8gc2V1IG5vbWUocykgb3UgbyhzKSBub21lKHMpIGRvKHMpIApkZXRlbnRvcihlcykgZG9zIGRpcmVpdG9zIGF1dG9yYWlzIGRvIHRyYWJhbGhvLCBlIG7Do28gZmFyw6EgcXVhbHF1ZXIgYWx0ZXJhw6fDo28sIGFsw6ltIGRhcXVlbGFzIGNvbmNlZGlkYXMgcG9yIGVzdGEgbGljZW7Dp2EuIAo=Repositório InstitucionalPUBhttps://ri.ufs.br/oai/requestrepositorio@academico.ufs.bropendoar:2021-11-16T11:55:02Repositório Institucional da UFS - Universidade Federal de Sergipe (UFS)false |
dc.title.pt_BR.fl_str_mv |
Influência de adições de grafeno e nanocompósitos Cds-diatomita nas propriedades autolimpantes de argamassa para rejuntamento |
dc.title.alternative.eng.fl_str_mv |
Influence of CdS-diatomite nanocomposite and graphene additions on self-cleaning mortarsisis |
title |
Influência de adições de grafeno e nanocompósitos Cds-diatomita nas propriedades autolimpantes de argamassa para rejuntamento |
spellingShingle |
Influência de adições de grafeno e nanocompósitos Cds-diatomita nas propriedades autolimpantes de argamassa para rejuntamento Prudente, Isis Nayra Rolemberg Engenharia de materiais Argamassa Rejuntamento Catálise Algas Nanocompósitos (Materiais) Fotocatálise Chlorella vulgaris Scenedesmus sp Grafeno Nanocompósito CdS-diatomita Mortars Joint Photocatalysis Algae Graphene CdS-diatomite nanocomposite ENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICA |
title_short |
Influência de adições de grafeno e nanocompósitos Cds-diatomita nas propriedades autolimpantes de argamassa para rejuntamento |
title_full |
Influência de adições de grafeno e nanocompósitos Cds-diatomita nas propriedades autolimpantes de argamassa para rejuntamento |
title_fullStr |
Influência de adições de grafeno e nanocompósitos Cds-diatomita nas propriedades autolimpantes de argamassa para rejuntamento |
title_full_unstemmed |
Influência de adições de grafeno e nanocompósitos Cds-diatomita nas propriedades autolimpantes de argamassa para rejuntamento |
title_sort |
Influência de adições de grafeno e nanocompósitos Cds-diatomita nas propriedades autolimpantes de argamassa para rejuntamento |
author |
Prudente, Isis Nayra Rolemberg |
author_facet |
Prudente, Isis Nayra Rolemberg |
author_role |
author |
dc.contributor.author.fl_str_mv |
Prudente, Isis Nayra Rolemberg |
dc.contributor.advisor1.fl_str_mv |
Barreto, Ledjane Silva |
contributor_str_mv |
Barreto, Ledjane Silva |
dc.subject.por.fl_str_mv |
Engenharia de materiais Argamassa Rejuntamento Catálise Algas Nanocompósitos (Materiais) Fotocatálise Chlorella vulgaris Scenedesmus sp Grafeno Nanocompósito CdS-diatomita |
topic |
Engenharia de materiais Argamassa Rejuntamento Catálise Algas Nanocompósitos (Materiais) Fotocatálise Chlorella vulgaris Scenedesmus sp Grafeno Nanocompósito CdS-diatomita Mortars Joint Photocatalysis Algae Graphene CdS-diatomite nanocomposite ENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICA |
dc.subject.eng.fl_str_mv |
Mortars Joint Photocatalysis Algae Graphene CdS-diatomite nanocomposite |
dc.subject.cnpq.fl_str_mv |
ENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICA |
description |
The evaluation of the functionality of graphene and CdS/diatomite nanocomposite as mortar additives for self-cleaning properties was carried out with the preparation of mixtures of a nanocomposite of cadmium sulphide (CdS) anchored in diatomite and graphene nanoplates in 1.5% and 2.5% of graphene by weight of nanocomposite. The self-cleaning mortars were prepared by adding graphene, the CdS nanocomposites and the CdS/graphene mixtures in a commercial cementitious joint mortar, with the main goal of promoting microalgae inhibition. Starting materials and mortars were characterized by X-ray diffraction, Raman, infrared and diffuse reflectance UV-vis spectroscopies. The photocatalytic activity was evaluated from methylene blue dye degradation assays in the presence and absence of UV-A radiation, as well as tests of chlorophyll degradation of a biofilm composed of Chlorella vulgaris and Scenedesmus sp., and its growth inhibition. The results indicate that the modified mortars with CdS/graphene mixtures obtained the best photocatalytic responses, degrading approximately 18% of the dye in six hours of testing, approximately 8% more than those mortars modified with the pure CdS nanocomposite. Regarding the biofilm degradation and its inhibition, the pure graphene modified mortar was the most efficient. In chlorophyll degradation tests on biofilms, this sample is presented the whitest gray level. The microalgae growth inhibition test showed that the sample modified only with graphene had, on average, 2.5% micoalgae coverage by the end of 8 weeks of testing, while the control sample presented an average 87% of algae coverage. This result was pointed out in the chlorophyll degradation test, in which RG sample presented the whitest gray level, therefore, it was the most efficient in the biofilm degradation. |
publishDate |
2020 |
dc.date.accessioned.fl_str_mv |
2020-03-24T14:01:13Z |
dc.date.available.fl_str_mv |
2020-03-24T14:01:13Z |
dc.date.issued.fl_str_mv |
2020-01-28 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/masterThesis |
format |
masterThesis |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
PRUDENTE, Isis Nayra Rolemberg. Influência de adições de grafeno e nanocompósitos Cds-diatomita nas propriedades autolimpantes de argamassa para rejuntamento. 2019. 108 f. Dissertação (Mestrado em Ciência e Engenharia de Materiais) – Universidade Federal de Sergipe, São Cristóvão, SE, 2020. |
dc.identifier.uri.fl_str_mv |
http://ri.ufs.br/jspui/handle/riufs/13133 |
identifier_str_mv |
PRUDENTE, Isis Nayra Rolemberg. Influência de adições de grafeno e nanocompósitos Cds-diatomita nas propriedades autolimpantes de argamassa para rejuntamento. 2019. 108 f. Dissertação (Mestrado em Ciência e Engenharia de Materiais) – Universidade Federal de Sergipe, São Cristóvão, SE, 2020. |
url |
http://ri.ufs.br/jspui/handle/riufs/13133 |
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Pós-Graduação em Ciência e Engenharia de Materiais |
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Univesidade Federal de Sergipe |
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