Hexaferrita de Sr do tipo M dopada com Mn produzida via o processo sol-gel proteico

• Autor(a) principal: Silva, Waldson Marcelo dos Santos
• Data de Publicação: 2015
• Tipo de documento: Tese
• Idioma: por
• Título da fonte: Repositório Institucional da UFS
• Texto Completo: https://ri.ufs.br/handle/riufs/5263
• topic: Física; Hexaferritas; Ferritas; Ferromagnetismo; Hexaferrita de estrôncio; Hexaferrita tipo M; Processo sol-gel proteico; CIENCIAS EXATAS E DA TERRA::FISICA

He studied at the structural, optical and magnetic nanoparticles in the form of hexaferrite powder samples with doping SrFe12-xMnxO19 range (0 < x < 3,5), synthesized by the sol-gel process, subjected to heat treatment of 1000º C for 1 h. The analysis TG - DTA indicated that the formation of the nanocrystalline phase of strontium hexaferrite occurred at a calcination temperature of 1000º C. Studies of structural change and microstructure of the samples were performed by X-ray diffraction (XRD) and Rietveld refinement method. The X-ray diffraction revealed that all samples showed the formation of the crystalline phase of strontium hexaferrite. The refinements made, it was observed that the network parameters have not changed significantly with the substitution of manganese. From the use of the Williamson-Hall method, it was possible to separate the microstrain network and their average sizes of crystallite. The Infrared Spectroscopy Fourier Transform (FTIR) showed the presence of three major absorption bands in the frequency range 435-535 cm-1 and 595 cm-1, indicating that there was formation of the hexaferrite. In addition, scanning electron microscopy (SEM) showed that the particles had rounded morphology, irregular, rods and hexagonal platelets, the diameters and average lengths of the particles were within the 68-204 nm range. Investigations of Mössbauer spectroscopy showed that the substitution of Fe3 + ions by Mn3 + ions occurred more preferably in some crystallographic network sites. The curves M x H indicated that all samples showed ferromagnetic behavior at room temperature. The magnetic properties such as coercive field, saturation magnetization, remanent magnetization ratio Mr / Ms and the Curie temperature, presented different figures due to preferential occupation of Mn3 + network ions, as it increased the level of doping.