Emerging contaminant degradation of paracetamol using advanced oxidation processes
Autor(a) principal: | |
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Data de Publicação: | 2015 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Revista Eletrônica em Gestão Educação e Tecnologia Ambiental (REGET) |
Texto Completo: | https://periodicos.ufsm.br/reget/article/view/18577 |
Resumo: | The Emergingcontaminants (EC), considered pollutants persistent and refractory it has been the subject studied worldwide.These compounds are present in different environmental matrices in low concentrations and cause damage to the health of animals and humans, whichmakes alternative treatments may require polishing able to promote its degradation. advanced oxidation processes (AOP) has been applied to this end, so that the present study sought to evaluate the efficiencyof two types of AOP(action UV / H2O2 and photo-Fenton) in EC paracetamol degradation.In order to quantify and detect with reliability, the compound before and after submission to treatments analysis was performed via LC / MS-IT-TOF with a previously validated method. The results showed that the AOPaction UV / H2O2was more efficient achieving promote degradation of paracetamol 100%, which is confirmed by statistical analysis experiments which showed that the addition of free iron (UV / H2O2) were the most effective in drug degradation in aqueous solution. Thus, it is possible to verify that the use of bench reactors with UV-C radiation is effective in paracetamol degradation at a low operating cost. |
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Emerging contaminant degradation of paracetamol using advanced oxidation processesDegradação do contaminante emergente paracetamol empregando processos oxidativos avançadosWaterParacetamolAOPUV RadiationÁguaParacetamolPOAValidação de metodologiaThe Emergingcontaminants (EC), considered pollutants persistent and refractory it has been the subject studied worldwide.These compounds are present in different environmental matrices in low concentrations and cause damage to the health of animals and humans, whichmakes alternative treatments may require polishing able to promote its degradation. advanced oxidation processes (AOP) has been applied to this end, so that the present study sought to evaluate the efficiencyof two types of AOP(action UV / H2O2 and photo-Fenton) in EC paracetamol degradation.In order to quantify and detect with reliability, the compound before and after submission to treatments analysis was performed via LC / MS-IT-TOF with a previously validated method. The results showed that the AOPaction UV / H2O2was more efficient achieving promote degradation of paracetamol 100%, which is confirmed by statistical analysis experiments which showed that the addition of free iron (UV / H2O2) were the most effective in drug degradation in aqueous solution. Thus, it is possible to verify that the use of bench reactors with UV-C radiation is effective in paracetamol degradation at a low operating cost.Uma classe de poluentes tem sido investigada por pesquisadores de todo o mundo, estes são os contaminantes emergentes, que são considerados persistente e refratário. Estes compostos estão presentes em diferentes matrizes ambientais em baixas concentrações que requerem tratamentos alternativos de polimento capazes de promover a degradação destes poluentes, uma vez que os tratamentos convencionais não são capazes de removê-los. Este estudo avaliou a degradação do paracetamol utilizando processos oxidativos avançados (ação UV/H2O2 e foto-Fenton). Os resultados mostraram que o processo ação UV / H2O2 foi mais eficiente conseguindo promover a degradação de 99% do paracetamol, o que é corroborado pela estatística que mostraram que as experiências isentas da adição de ferro (UV / H2O2) foram os mais eficientes na degradação do paracetamol em solução aquosa solução. A metodologia para a identificação através de cromatografia foi validado de acordo exigência das agências existentes (INMETRO e ANVISA), assegurando a confiabilidade dos resultados.Universidade Federal de Santa Maria2015-07-27info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufsm.br/reget/article/view/1857710.5902/2236117018577Revista Eletrônica em Gestão, Educação e Tecnologia Ambiental; REGET, V. 19, N. 3, SEPT.-DEC., 2015; 725-734Revista Eletrônica em Gestão, Educação e Tecnologia Ambiental; REGET, V. 19, N. 3, SET.-DEZ., 2015; 725-7342236-11702236-1170reponame:Revista Eletrônica em Gestão Educação e Tecnologia Ambiental (REGET)instname:Universidade Federal de Santa Maria (UFSM)instacron:UFSMporhttps://periodicos.ufsm.br/reget/article/view/18577/pdfhttp://creativecommons.org/licenses/by-nc-sa/4.0info:eu-repo/semantics/openAccessNapoleão, Daniella CarlaZaidan, Léa Elias Mendes CarneiroSalgado, Júlia Barbosa de AlmeidaSales, Renata Vitória de LimaSilva, Valdinete Lins da2022-05-06T18:37:54Zoai:ojs.pkp.sfu.ca:article/18577Revistahttps://periodicos.ufsm.br/regetPUBhttps://periodicos.ufsm.br/reget/oaimarcelobdarosa@gmail.com||reget.ufsm@gmail.com2236-11702236-1170opendoar:2022-05-06T18:37:54Revista Eletrônica em Gestão Educação e Tecnologia Ambiental (REGET) - Universidade Federal de Santa Maria (UFSM)false |
dc.title.none.fl_str_mv |
Emerging contaminant degradation of paracetamol using advanced oxidation processes Degradação do contaminante emergente paracetamol empregando processos oxidativos avançados |
title |
Emerging contaminant degradation of paracetamol using advanced oxidation processes |
spellingShingle |
Emerging contaminant degradation of paracetamol using advanced oxidation processes Napoleão, Daniella Carla Water Paracetamol AOP UV Radiation Água Paracetamol POA Validação de metodologia |
title_short |
Emerging contaminant degradation of paracetamol using advanced oxidation processes |
title_full |
Emerging contaminant degradation of paracetamol using advanced oxidation processes |
title_fullStr |
Emerging contaminant degradation of paracetamol using advanced oxidation processes |
title_full_unstemmed |
Emerging contaminant degradation of paracetamol using advanced oxidation processes |
title_sort |
Emerging contaminant degradation of paracetamol using advanced oxidation processes |
author |
Napoleão, Daniella Carla |
author_facet |
Napoleão, Daniella Carla Zaidan, Léa Elias Mendes Carneiro Salgado, Júlia Barbosa de Almeida Sales, Renata Vitória de Lima Silva, Valdinete Lins da |
author_role |
author |
author2 |
Zaidan, Léa Elias Mendes Carneiro Salgado, Júlia Barbosa de Almeida Sales, Renata Vitória de Lima Silva, Valdinete Lins da |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Napoleão, Daniella Carla Zaidan, Léa Elias Mendes Carneiro Salgado, Júlia Barbosa de Almeida Sales, Renata Vitória de Lima Silva, Valdinete Lins da |
dc.subject.por.fl_str_mv |
Water Paracetamol AOP UV Radiation Água Paracetamol POA Validação de metodologia |
topic |
Water Paracetamol AOP UV Radiation Água Paracetamol POA Validação de metodologia |
description |
The Emergingcontaminants (EC), considered pollutants persistent and refractory it has been the subject studied worldwide.These compounds are present in different environmental matrices in low concentrations and cause damage to the health of animals and humans, whichmakes alternative treatments may require polishing able to promote its degradation. advanced oxidation processes (AOP) has been applied to this end, so that the present study sought to evaluate the efficiencyof two types of AOP(action UV / H2O2 and photo-Fenton) in EC paracetamol degradation.In order to quantify and detect with reliability, the compound before and after submission to treatments analysis was performed via LC / MS-IT-TOF with a previously validated method. The results showed that the AOPaction UV / H2O2was more efficient achieving promote degradation of paracetamol 100%, which is confirmed by statistical analysis experiments which showed that the addition of free iron (UV / H2O2) were the most effective in drug degradation in aqueous solution. Thus, it is possible to verify that the use of bench reactors with UV-C radiation is effective in paracetamol degradation at a low operating cost. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-07-27 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://periodicos.ufsm.br/reget/article/view/18577 10.5902/2236117018577 |
url |
https://periodicos.ufsm.br/reget/article/view/18577 |
identifier_str_mv |
10.5902/2236117018577 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
https://periodicos.ufsm.br/reget/article/view/18577/pdf |
dc.rights.driver.fl_str_mv |
http://creativecommons.org/licenses/by-nc-sa/4.0 info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc-sa/4.0 |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Federal de Santa Maria |
publisher.none.fl_str_mv |
Universidade Federal de Santa Maria |
dc.source.none.fl_str_mv |
Revista Eletrônica em Gestão, Educação e Tecnologia Ambiental; REGET, V. 19, N. 3, SEPT.-DEC., 2015; 725-734 Revista Eletrônica em Gestão, Educação e Tecnologia Ambiental; REGET, V. 19, N. 3, SET.-DEZ., 2015; 725-734 2236-1170 2236-1170 reponame:Revista Eletrônica em Gestão Educação e Tecnologia Ambiental (REGET) instname:Universidade Federal de Santa Maria (UFSM) instacron:UFSM |
instname_str |
Universidade Federal de Santa Maria (UFSM) |
instacron_str |
UFSM |
institution |
UFSM |
reponame_str |
Revista Eletrônica em Gestão Educação e Tecnologia Ambiental (REGET) |
collection |
Revista Eletrônica em Gestão Educação e Tecnologia Ambiental (REGET) |
repository.name.fl_str_mv |
Revista Eletrônica em Gestão Educação e Tecnologia Ambiental (REGET) - Universidade Federal de Santa Maria (UFSM) |
repository.mail.fl_str_mv |
marcelobdarosa@gmail.com||reget.ufsm@gmail.com |
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1799950576326279168 |