DETERMINATION OF SILICA CONTENT IN WOOD BY FLAME ATOMIC ABSORPTION SPECTROSCOPY VERSUS ULTRAVIOLET-VISIBLE SPECTROSCOPY
Autor(a) principal: | |
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Data de Publicação: | 2008 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Ciência Florestal (Online) |
Texto Completo: | https://periodicos.ufsm.br/cienciaflorestal/article/view/462 |
Resumo: | The objective of this work was to compare the performance of two analytical techniques, flame atomic absorption spectroscopy (FAAS) and ultraviolet-visible spectroscopy (UV-VIS), in the determination of the silica content in lignocellulosic materials. The methods were tested in wood specimens of three trees of Apuleia leiocarpa (Vog.) Macbride. The results showed that both techniques present good performance, but the FAAS presents better precision, speed and operational simplicity. However, the application of the UV-VIS spectroscopy is justified by the fact of the acquisition and maintenance costs of an UV-VIS spectrophotometer are lower when compared to those of a spectrometer of atomic absorption. The use of the FAAS technique should just be chosen when the silica content is expected to be very low, once the UV-VIS spectroscopy, in those cases, does not present good precision. |
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DETERMINATION OF SILICA CONTENT IN WOOD BY FLAME ATOMIC ABSORPTION SPECTROSCOPY VERSUS ULTRAVIOLET-VISIBLE SPECTROSCOPYDeterminação do teor de sílica em madeira por espectroscopia de absorção atômica de chama versus espectroscopia no ultravioleta-visível.tropical woodssiliconsilicates and inorganic materialsmadeiras tropicaismateriais inorgânicossilicatos e silício.The objective of this work was to compare the performance of two analytical techniques, flame atomic absorption spectroscopy (FAAS) and ultraviolet-visible spectroscopy (UV-VIS), in the determination of the silica content in lignocellulosic materials. The methods were tested in wood specimens of three trees of Apuleia leiocarpa (Vog.) Macbride. The results showed that both techniques present good performance, but the FAAS presents better precision, speed and operational simplicity. However, the application of the UV-VIS spectroscopy is justified by the fact of the acquisition and maintenance costs of an UV-VIS spectrophotometer are lower when compared to those of a spectrometer of atomic absorption. The use of the FAAS technique should just be chosen when the silica content is expected to be very low, once the UV-VIS spectroscopy, in those cases, does not present good precision. O presente trabalho teve como objetivo comparar o desempenho de duas técnicas analíticas, espectroscopia de absorção atômica de chama (FAAS) e espectroscopia no ultravioleta-visível (UV-VIS), na determinação do teor de sílica em materiais lignocelulósicos. Os métodos foram testados em amostras de madeira de três árvores de Apuleia leiocarpa (Vog.) Macbride. Os resultados mostraram que ambas as técnicas apresentam bons resultados, no entanto, a FAAS apresenta melhor precisão, rapidez e simplicidade operacional. Entretanto, a aplicação da espectroscopia UV-VIS é justificada pelo fato de os custos de aquisição e manutenção de um espectrofotômetro UV-VIS serem muito inferiores àqueles de um espectrômetro de absorção atômica. O uso da técnica FAAS deve ser preferido apenas quando os teores de sílica a serem determinados forem muito baixos, tendo em vista que a espectroscopia UV-VIS, nesses casos, não apresenta boa precisão.Universidade Federal de Santa Maria2008-06-30info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufsm.br/cienciaflorestal/article/view/46210.5902/19805098462Ciência Florestal; Vol. 18 No. 2 (2008); 259-264Ciência Florestal; v. 18 n. 2 (2008); 259-2641980-50980103-9954reponame:Ciência Florestal (Online)instname:Universidade Federal de Santa Maria (UFSM)instacron:UFSMporhttps://periodicos.ufsm.br/cienciaflorestal/article/view/462/359Rodrigues, Laécio CarneiroSantana, Marcos Antonio Eduardoinfo:eu-repo/semantics/openAccess2017-05-11T13:35:06Zoai:ojs.pkp.sfu.ca:article/462Revistahttp://www.ufsm.br/cienciaflorestal/ONGhttps://old.scielo.br/oai/scielo-oai.php||cienciaflorestal@ufsm.br|| cienciaflorestal@gmail.com|| cf@smail.ufsm.br1980-50980103-9954opendoar:2017-05-11T13:35:06Ciência Florestal (Online) - Universidade Federal de Santa Maria (UFSM)false |
dc.title.none.fl_str_mv |
DETERMINATION OF SILICA CONTENT IN WOOD BY FLAME ATOMIC ABSORPTION SPECTROSCOPY VERSUS ULTRAVIOLET-VISIBLE SPECTROSCOPY Determinação do teor de sílica em madeira por espectroscopia de absorção atômica de chama versus espectroscopia no ultravioleta-visível. |
title |
DETERMINATION OF SILICA CONTENT IN WOOD BY FLAME ATOMIC ABSORPTION SPECTROSCOPY VERSUS ULTRAVIOLET-VISIBLE SPECTROSCOPY |
spellingShingle |
DETERMINATION OF SILICA CONTENT IN WOOD BY FLAME ATOMIC ABSORPTION SPECTROSCOPY VERSUS ULTRAVIOLET-VISIBLE SPECTROSCOPY Rodrigues, Laécio Carneiro tropical woods silicon silicates and inorganic materials madeiras tropicais materiais inorgânicos silicatos e silício. |
title_short |
DETERMINATION OF SILICA CONTENT IN WOOD BY FLAME ATOMIC ABSORPTION SPECTROSCOPY VERSUS ULTRAVIOLET-VISIBLE SPECTROSCOPY |
title_full |
DETERMINATION OF SILICA CONTENT IN WOOD BY FLAME ATOMIC ABSORPTION SPECTROSCOPY VERSUS ULTRAVIOLET-VISIBLE SPECTROSCOPY |
title_fullStr |
DETERMINATION OF SILICA CONTENT IN WOOD BY FLAME ATOMIC ABSORPTION SPECTROSCOPY VERSUS ULTRAVIOLET-VISIBLE SPECTROSCOPY |
title_full_unstemmed |
DETERMINATION OF SILICA CONTENT IN WOOD BY FLAME ATOMIC ABSORPTION SPECTROSCOPY VERSUS ULTRAVIOLET-VISIBLE SPECTROSCOPY |
title_sort |
DETERMINATION OF SILICA CONTENT IN WOOD BY FLAME ATOMIC ABSORPTION SPECTROSCOPY VERSUS ULTRAVIOLET-VISIBLE SPECTROSCOPY |
author |
Rodrigues, Laécio Carneiro |
author_facet |
Rodrigues, Laécio Carneiro Santana, Marcos Antonio Eduardo |
author_role |
author |
author2 |
Santana, Marcos Antonio Eduardo |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Rodrigues, Laécio Carneiro Santana, Marcos Antonio Eduardo |
dc.subject.por.fl_str_mv |
tropical woods silicon silicates and inorganic materials madeiras tropicais materiais inorgânicos silicatos e silício. |
topic |
tropical woods silicon silicates and inorganic materials madeiras tropicais materiais inorgânicos silicatos e silício. |
description |
The objective of this work was to compare the performance of two analytical techniques, flame atomic absorption spectroscopy (FAAS) and ultraviolet-visible spectroscopy (UV-VIS), in the determination of the silica content in lignocellulosic materials. The methods were tested in wood specimens of three trees of Apuleia leiocarpa (Vog.) Macbride. The results showed that both techniques present good performance, but the FAAS presents better precision, speed and operational simplicity. However, the application of the UV-VIS spectroscopy is justified by the fact of the acquisition and maintenance costs of an UV-VIS spectrophotometer are lower when compared to those of a spectrometer of atomic absorption. The use of the FAAS technique should just be chosen when the silica content is expected to be very low, once the UV-VIS spectroscopy, in those cases, does not present good precision. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-06-30 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://periodicos.ufsm.br/cienciaflorestal/article/view/462 10.5902/19805098462 |
url |
https://periodicos.ufsm.br/cienciaflorestal/article/view/462 |
identifier_str_mv |
10.5902/19805098462 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
https://periodicos.ufsm.br/cienciaflorestal/article/view/462/359 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Federal de Santa Maria |
publisher.none.fl_str_mv |
Universidade Federal de Santa Maria |
dc.source.none.fl_str_mv |
Ciência Florestal; Vol. 18 No. 2 (2008); 259-264 Ciência Florestal; v. 18 n. 2 (2008); 259-264 1980-5098 0103-9954 reponame:Ciência Florestal (Online) instname:Universidade Federal de Santa Maria (UFSM) instacron:UFSM |
instname_str |
Universidade Federal de Santa Maria (UFSM) |
instacron_str |
UFSM |
institution |
UFSM |
reponame_str |
Ciência Florestal (Online) |
collection |
Ciência Florestal (Online) |
repository.name.fl_str_mv |
Ciência Florestal (Online) - Universidade Federal de Santa Maria (UFSM) |
repository.mail.fl_str_mv |
||cienciaflorestal@ufsm.br|| cienciaflorestal@gmail.com|| cf@smail.ufsm.br |
_version_ |
1799944125443735552 |