Estudo da versatilidade do bis(2-piridinil)ditelano em química de coordenação

• Autor(a) principal: Silva, Felipe Dornelles da
• Data de Publicação: 2020
• Tipo de documento: Tese
• Idioma: por
• Título da fonte: Manancial - Repositório Digital da UFSM
• dARK ID: ark:/26339/001300000nrx7
• Texto Completo: http://repositorio.ufsm.br/handle/1/23093
• topic: Compostos de coordenação; Clusters; Zwitteríon; Band gap; Fotocatálise; Produção de hidrogênio; Coordination compounds; Photocatalysis; Hydrogen production; CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA

This present work describes the synthesis and characterization of 19 compounds derivatives from bis(2-pyridinyl)ditellane (oPy2Te2, oPy = 2-pyridinyl) and bis(5-trifluoromethyl-2-pyridinyl)ditellane (Tfpy2Te2, Tfpy = 5-trifluoromethyl-2-pyridinyl). Due to their different coordination sites hardness (N and Te), the simple change between metal centers hardness used in reaction with these ligands resulted in different types of compounds like zwitterionic aryltellurium(II) halides H(Tfpy)TeX2 (X = Cl (1) or Br (2)), coordination compounds [Co(oPy2Te2-κN,N’)X2] (X = Cl (3) or Br (4)), [Cu(oPy2Te2-κN1,Te2,N2’)X]2 (X = Cl (5) or Br (6)), [Cu(oPy2TeClO-κO,N,N’)ClO]2 (7), [Cu2(oPy2Te-κN,N’)(MeCN)Br2] (8), [Re(RTeCl)(PPh3)2(O)2Cl] (9) and (10), [Tc2(NO)2(oPy2Te2-κTe,N)(PPh3)2Cl4] (11), monometallic clusters [Cu(-TeoPy-κTe,N)]4 (12), [Hg4(Ph3P)2(-TeoPy)6X2] (X = Cl (13) or Br (14)), [Hg4(Ph3P)2(-TeoPy)6I2]DMF (15), [Hg8(-TeoPy)12SCl2]·5,25DMF (16), zwitterionic clusters [Hg8(-TeoPy)11,07(-TeoPyH)0,93 SBr2,93]·7,62DMF (17) and [Hg8(-TeoPy)11,17(-TeoPyH)0,83 SI2,83]·7,25DMF (18) and heterometallic clusters [HgAg4(PPh3)3(-TeoPy)3(μ3-TeoPy)3] (19). The obtained compounds had their structure evaluated by X-ray crystallography, Fourier-transform infrared spectroscopy, confocal Raman spectroscopy, heteronuclear magnetic resonance spectroscopy (1H, 13C, 19F, 31P, 99Tc, and 125Te), elemental analysis and other complementary analyzes. Optical band gap estimation by UV-Vis spectroscopy on solid state and theoretical calculations were performed. Based on the analyzed properties, compound [Co(oPy2Te2-κN,N’)Br2] (4) was tested as potential photocatalyst for gaseous hydrogen production from water splitting, showing good results in the initial tests.