Propriedades tecnológicas da madeira densificada de eucalipto submetida ao tratamento em óleo vegetal

Detalhes bibliográficos
Autor(a) principal: Pertuzzatti, Anderson
Data de Publicação: 2018
Tipo de documento: Tese
Idioma: por
Título da fonte: Manancial - Repositório Digital da UFSM
Texto Completo: http://repositorio.ufsm.br/handle/1/16301
Resumo: Densification is relevant in the timber industry. Since it makes it possible to increase the use of wood less valued by the market. However, densified wood shows high dimensional instability. In order to minimize this problem, a post-treatment using the oil heat treatment (OHT®) was performed. In view of the above, the present research aims to evaluate the technological properties of densified wood of the eucalipto submitted to treatment in vegetable oil. The methodology consisted in the use of wood of E. grandis, E. dunnii, E. cloeziana and E. tereticornis that were submitted to the process of densification and post-treatment in vegetable oil. Twenty-four treatments were performed, consisting of different species, densification temperatures and post-treatment. For the characterization of the produced wood based material, physical, mechanical, chemical and superficial tests were carried out. For the statistical analysis, the 4 x 6 qualitative factorial arrangement was used, with four species and six treatments, compared by the Tukey test. The main results showed that densification increases distinctly in the basic density (ρb) among the evaluated species, which shows that the increase of ρb by densification is conditioned to its initial value. In the case of wood dimensional stability it was observed that the densification caused a reduction in this property in relation to the control. However, in the treatments in which the post-treatment in oil was applied, there was a decrease of more than 30% in the dimensional instability, caused by the relaxation of the stresses stored during the compression, through the partial hydrolysis of the hemicelluloses. As for the hygroscopicity of the wood, it was observed that the densification using the temperature of 140 °C showed an increase in the water absorption after 24 hours of immersion, caused by the reopening of the flattened vessels. However, when the wood was submitted to the post-treatment, there was a reduction of the hygroscopicity caused by the thermal degradation and the presence of oil in the cell lumens. In wettability it was identified that the only densified wood presented a hydrophilic character. However, when submitted to post-treatment it has become hydrophobic. Mechanical strength showed the most satisfactory results in densified wood at 140 °C without post-treatment, obtaining increases in all properties and species evaluated. However, with the post-treatment application there was an average decrease of 20% in the mechanical strength of the treated wood. In the analysis of Infrared Spectrometry it was verified that there was a greater chemical alteration after the application of the post-treatment, obtaining degradation of hemicelluloses and amorphous cellulose, which provided proportional increase of crystalline cellulose and lignin. For the colorimetric parameters, it was identified that the post-treatment presented the greatest changes in the color of the wood, causing the wood of the four species to gain a tropical tone (dark brown), which is feasible for the application of aesthetic purposes.
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spelling Propriedades tecnológicas da madeira densificada de eucalipto submetida ao tratamento em óleo vegetalTechnological properties of densified wood of the eucalipto submitted to the treatment in vegetable oilResistência mecânicaSpringbackPlastificaçãoPós-tratamentoSuperfície da madeiraMechanical resistancePlastificationPost-treatmentWood surfaceCNPQ::CIENCIAS AGRARIAS::RECURSOS FLORESTAIS E ENGENHARIA FLORESTALDensification is relevant in the timber industry. Since it makes it possible to increase the use of wood less valued by the market. However, densified wood shows high dimensional instability. In order to minimize this problem, a post-treatment using the oil heat treatment (OHT®) was performed. In view of the above, the present research aims to evaluate the technological properties of densified wood of the eucalipto submitted to treatment in vegetable oil. The methodology consisted in the use of wood of E. grandis, E. dunnii, E. cloeziana and E. tereticornis that were submitted to the process of densification and post-treatment in vegetable oil. Twenty-four treatments were performed, consisting of different species, densification temperatures and post-treatment. For the characterization of the produced wood based material, physical, mechanical, chemical and superficial tests were carried out. For the statistical analysis, the 4 x 6 qualitative factorial arrangement was used, with four species and six treatments, compared by the Tukey test. The main results showed that densification increases distinctly in the basic density (ρb) among the evaluated species, which shows that the increase of ρb by densification is conditioned to its initial value. In the case of wood dimensional stability it was observed that the densification caused a reduction in this property in relation to the control. However, in the treatments in which the post-treatment in oil was applied, there was a decrease of more than 30% in the dimensional instability, caused by the relaxation of the stresses stored during the compression, through the partial hydrolysis of the hemicelluloses. As for the hygroscopicity of the wood, it was observed that the densification using the temperature of 140 °C showed an increase in the water absorption after 24 hours of immersion, caused by the reopening of the flattened vessels. However, when the wood was submitted to the post-treatment, there was a reduction of the hygroscopicity caused by the thermal degradation and the presence of oil in the cell lumens. In wettability it was identified that the only densified wood presented a hydrophilic character. However, when submitted to post-treatment it has become hydrophobic. Mechanical strength showed the most satisfactory results in densified wood at 140 °C without post-treatment, obtaining increases in all properties and species evaluated. However, with the post-treatment application there was an average decrease of 20% in the mechanical strength of the treated wood. In the analysis of Infrared Spectrometry it was verified that there was a greater chemical alteration after the application of the post-treatment, obtaining degradation of hemicelluloses and amorphous cellulose, which provided proportional increase of crystalline cellulose and lignin. For the colorimetric parameters, it was identified that the post-treatment presented the greatest changes in the color of the wood, causing the wood of the four species to gain a tropical tone (dark brown), which is feasible for the application of aesthetic purposes.Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPESA densificação apresenta relevante importância na indústria madeireira. Uma vez que possibilita ampliar a utilização de madeiras menos valorizadas pelo mercado. Entretanto, a madeira densificada apresenta elevada instabilidade dimensional. Visando minimizar esse problema foi realizado um pós-tratamento, utilizando a termorretificação em óleo pelo processo OHT® (Oil heat treatment). Diante do exposto, a presente pesquisa tem por objetivo avaliar as propriedades tecnológicas da madeira densificada de eucalipto submetida ao tratamento em óleo vegetal. A metodologia consistiu na utilização da madeira de E. grandis, E. dunnii, E. cloeziana e E. tereticornis que foram submetidas ao processo de densificação e pós-tratamento em óleo vegetal. Foram realizados 24 tratamentos, compondo-se de diferentes espécies, temperaturas de densificação e pós-tratamento. Para a caracterização do material gerado, foram realizados ensaios físicos, mecânicos, químicos e superficiais na madeira. Para a análise estatística foi utilizado o arranjo fatorial qualitativo 4 x 6, com quatro espécies e seis tratamentos, comparados pelo teste de Tukey. Os principais resultados demostraram que a densificação apresentou acréscimos distintos na densidade aparente (ρap) entre as espécies avaliadas, o que demonstra que o aumento da ρap por meio da densificação está condicionado ao seu valor inicial. No caso da estabilidade dimensional da madeira foi observado que a densificação provocou redução nessa propriedade em relação ao controle. Entretanto, nos tratamentos em que foi aplicado o pós-tratamento em óleo houve decréscimo de mais de 30% na instabilidade dimensional, ocasionado pelo relaxamento das tensões armazenadas durante a compressão, por meio da hidrólise parcial das hemiceluloses. Já para a higroscopicidade da madeira foi observado que a densificação utilizando a temperatura de 140 °C apresentou aumento na absorção de água após 24 horas de imersão, provocado pela reabertura dos vasos achatados. No entanto, quando a madeira foi submetida ao pós-tratamento houve redução da higroscopicidade ocasionada pela degradação térmica e presença de óleo nos lumens celulares. Na molhabilidade foi identificado que a madeira somente densificada apresentou caráter hidrofílico. Entretanto, quando submetida ao pós-tratamento tornou-se hidrofóbica. A resistência mecânica apresentou os resultados mais satisfatórios na madeira densificada a 140 °C sem aplicação de pós-tratamento, obtendo acréscimos em todas as propriedades e espécies avaliadas. No entanto, com a aplicação de pós-tratamento houve decréscimo médio de 20% na resistência mecânica da madeira tratada. Na análise de Espectrometria no Infravermelho foi verificado que houve maior alteração química após a aplicação do pós-tratamento, obtendo degradação de hemiceluloses e celulose amorfa, o que proporcionou acréscimo proporcional de celulose cristalina e lignina. Para os parâmetros colorimétricos, foi identificado que o pós-tratamento apresentou as maiores alterações na cor da madeira, fazendo com que a madeira das quatro as espécies ganhassem um tom tropical (marrom escuro), viável para aplicação de fins estéticos.Universidade Federal de Santa MariaBrasilRecursos Florestais e Engenharia FlorestalUFSMPrograma de Pós-Graduação em Engenharia FlorestalCentro de Ciências RuraisGatto, Darci Albertohttp://lattes.cnpq.br/0592339091520248Haselein, Clovis Robertohttp://lattes.cnpq.br/5522749609471065Santini, Elio Joséhttp://lattes.cnpq.br/1939844237237675Beltrame, Rafaelhttp://lattes.cnpq.br/1995147035662011Rosso, Silvianahttp://lattes.cnpq.br/1109211725706666Pertuzzatti, Anderson2019-04-24T12:46:53Z2019-04-24T12:46:53Z2018-12-14info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisapplication/pdfhttp://repositorio.ufsm.br/handle/1/16301porAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessreponame:Manancial - Repositório Digital da UFSMinstname:Universidade Federal de Santa Maria (UFSM)instacron:UFSM2019-04-25T06:02:13Zoai:repositorio.ufsm.br:1/16301Biblioteca Digital de Teses e Dissertaçõeshttps://repositorio.ufsm.br/ONGhttps://repositorio.ufsm.br/oai/requestatendimento.sib@ufsm.br||tedebc@gmail.comopendoar:2019-04-25T06:02:13Manancial - Repositório Digital da UFSM - Universidade Federal de Santa Maria (UFSM)false
dc.title.none.fl_str_mv Propriedades tecnológicas da madeira densificada de eucalipto submetida ao tratamento em óleo vegetal
Technological properties of densified wood of the eucalipto submitted to the treatment in vegetable oil
title Propriedades tecnológicas da madeira densificada de eucalipto submetida ao tratamento em óleo vegetal
spellingShingle Propriedades tecnológicas da madeira densificada de eucalipto submetida ao tratamento em óleo vegetal
Pertuzzatti, Anderson
Resistência mecânica
Springback
Plastificação
Pós-tratamento
Superfície da madeira
Mechanical resistance
Plastification
Post-treatment
Wood surface
CNPQ::CIENCIAS AGRARIAS::RECURSOS FLORESTAIS E ENGENHARIA FLORESTAL
title_short Propriedades tecnológicas da madeira densificada de eucalipto submetida ao tratamento em óleo vegetal
title_full Propriedades tecnológicas da madeira densificada de eucalipto submetida ao tratamento em óleo vegetal
title_fullStr Propriedades tecnológicas da madeira densificada de eucalipto submetida ao tratamento em óleo vegetal
title_full_unstemmed Propriedades tecnológicas da madeira densificada de eucalipto submetida ao tratamento em óleo vegetal
title_sort Propriedades tecnológicas da madeira densificada de eucalipto submetida ao tratamento em óleo vegetal
author Pertuzzatti, Anderson
author_facet Pertuzzatti, Anderson
author_role author
dc.contributor.none.fl_str_mv Gatto, Darci Alberto
http://lattes.cnpq.br/0592339091520248
Haselein, Clovis Roberto
http://lattes.cnpq.br/5522749609471065
Santini, Elio José
http://lattes.cnpq.br/1939844237237675
Beltrame, Rafael
http://lattes.cnpq.br/1995147035662011
Rosso, Silviana
http://lattes.cnpq.br/1109211725706666
dc.contributor.author.fl_str_mv Pertuzzatti, Anderson
dc.subject.por.fl_str_mv Resistência mecânica
Springback
Plastificação
Pós-tratamento
Superfície da madeira
Mechanical resistance
Plastification
Post-treatment
Wood surface
CNPQ::CIENCIAS AGRARIAS::RECURSOS FLORESTAIS E ENGENHARIA FLORESTAL
topic Resistência mecânica
Springback
Plastificação
Pós-tratamento
Superfície da madeira
Mechanical resistance
Plastification
Post-treatment
Wood surface
CNPQ::CIENCIAS AGRARIAS::RECURSOS FLORESTAIS E ENGENHARIA FLORESTAL
description Densification is relevant in the timber industry. Since it makes it possible to increase the use of wood less valued by the market. However, densified wood shows high dimensional instability. In order to minimize this problem, a post-treatment using the oil heat treatment (OHT®) was performed. In view of the above, the present research aims to evaluate the technological properties of densified wood of the eucalipto submitted to treatment in vegetable oil. The methodology consisted in the use of wood of E. grandis, E. dunnii, E. cloeziana and E. tereticornis that were submitted to the process of densification and post-treatment in vegetable oil. Twenty-four treatments were performed, consisting of different species, densification temperatures and post-treatment. For the characterization of the produced wood based material, physical, mechanical, chemical and superficial tests were carried out. For the statistical analysis, the 4 x 6 qualitative factorial arrangement was used, with four species and six treatments, compared by the Tukey test. The main results showed that densification increases distinctly in the basic density (ρb) among the evaluated species, which shows that the increase of ρb by densification is conditioned to its initial value. In the case of wood dimensional stability it was observed that the densification caused a reduction in this property in relation to the control. However, in the treatments in which the post-treatment in oil was applied, there was a decrease of more than 30% in the dimensional instability, caused by the relaxation of the stresses stored during the compression, through the partial hydrolysis of the hemicelluloses. As for the hygroscopicity of the wood, it was observed that the densification using the temperature of 140 °C showed an increase in the water absorption after 24 hours of immersion, caused by the reopening of the flattened vessels. However, when the wood was submitted to the post-treatment, there was a reduction of the hygroscopicity caused by the thermal degradation and the presence of oil in the cell lumens. In wettability it was identified that the only densified wood presented a hydrophilic character. However, when submitted to post-treatment it has become hydrophobic. Mechanical strength showed the most satisfactory results in densified wood at 140 °C without post-treatment, obtaining increases in all properties and species evaluated. However, with the post-treatment application there was an average decrease of 20% in the mechanical strength of the treated wood. In the analysis of Infrared Spectrometry it was verified that there was a greater chemical alteration after the application of the post-treatment, obtaining degradation of hemicelluloses and amorphous cellulose, which provided proportional increase of crystalline cellulose and lignin. For the colorimetric parameters, it was identified that the post-treatment presented the greatest changes in the color of the wood, causing the wood of the four species to gain a tropical tone (dark brown), which is feasible for the application of aesthetic purposes.
publishDate 2018
dc.date.none.fl_str_mv 2018-12-14
2019-04-24T12:46:53Z
2019-04-24T12:46:53Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/doctoralThesis
format doctoralThesis
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://repositorio.ufsm.br/handle/1/16301
url http://repositorio.ufsm.br/handle/1/16301
dc.language.iso.fl_str_mv por
language por
dc.rights.driver.fl_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal de Santa Maria
Brasil
Recursos Florestais e Engenharia Florestal
UFSM
Programa de Pós-Graduação em Engenharia Florestal
Centro de Ciências Rurais
publisher.none.fl_str_mv Universidade Federal de Santa Maria
Brasil
Recursos Florestais e Engenharia Florestal
UFSM
Programa de Pós-Graduação em Engenharia Florestal
Centro de Ciências Rurais
dc.source.none.fl_str_mv reponame:Manancial - Repositório Digital da UFSM
instname:Universidade Federal de Santa Maria (UFSM)
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instname_str Universidade Federal de Santa Maria (UFSM)
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institution UFSM
reponame_str Manancial - Repositório Digital da UFSM
collection Manancial - Repositório Digital da UFSM
repository.name.fl_str_mv Manancial - Repositório Digital da UFSM - Universidade Federal de Santa Maria (UFSM)
repository.mail.fl_str_mv atendimento.sib@ufsm.br||tedebc@gmail.com
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