Estudo fitoquímico da madeira de Guarea macrophylla (Meliaceae)

Detalhes bibliográficos
Autor(a) principal: Lago, Joao Henrique Ghilardi [UNIFESP]
Data de Publicação: 2009
Outros Autores: Roque, Nídia Franca
Tipo de documento: Artigo
Idioma: por
Título da fonte: Repositório Institucional da UNIFESP
Texto Completo: http://dx.doi.org/10.1590/S0100-40422009000900022
http://repositorio.unifesp.br/handle/11600/4786
Resumo: In the present work, the crude ethanol extract from wood of G. macrophylla was submitted to liquid/liquid partition between hexane, CH2Cl2, EtOAc and n-BuOH. Each phase was individually chromatographed over silica gel, Sephadex LH-20 or Amberlite XAD-2 to give eight terpene derivatives, such as five sesquiterpenoids (caryophyllene oxide, guai-6-en-10β-ol, spathulenol, aromadendrane-4β,10α-diol and aloaromadendrane-4α,10β-diol) as well as three triterpenoids (cicloart-24-ene-3β,23(R*)-diol, cicloart-24-ene-3β,23(S*)-diol, and cicloart-23E-ene-3β,25-diol). Additionally, were isolated three fatty acids (linolenic, linoleic and stearic), two steroids (sitosterol and stigmasterol) and sacarose. The structures of all these compounds were characterized by spectrometric analysis, mainly mass spectrometry and NMR and comparison of these data described in the literature.
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spelling Estudo fitoquímico da madeira de Guarea macrophylla (Meliaceae)Phytochemical study of the wood from Guarea macrophylla (Meliaceae)MeliaceaeGuarea macrophyllacycloartane triterpenoidsIn the present work, the crude ethanol extract from wood of G. macrophylla was submitted to liquid/liquid partition between hexane, CH2Cl2, EtOAc and n-BuOH. Each phase was individually chromatographed over silica gel, Sephadex LH-20 or Amberlite XAD-2 to give eight terpene derivatives, such as five sesquiterpenoids (caryophyllene oxide, guai-6-en-10β-ol, spathulenol, aromadendrane-4β,10α-diol and aloaromadendrane-4α,10β-diol) as well as three triterpenoids (cicloart-24-ene-3β,23(R*)-diol, cicloart-24-ene-3β,23(S*)-diol, and cicloart-23E-ene-3β,25-diol). Additionally, were isolated three fatty acids (linolenic, linoleic and stearic), two steroids (sitosterol and stigmasterol) and sacarose. The structures of all these compounds were characterized by spectrometric analysis, mainly mass spectrometry and NMR and comparison of these data described in the literature.Universidade Federal de São Paulo (UNIFESP) Departamento de Ciências Exatas e da TerraUniversidade Federal da Bahia Instituto de QuímicaUNIFESP, Depto. de Ciências Exatas e da TerraSciELOFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Sociedade Brasileira de QuímicaUniversidade Federal de São Paulo (UNIFESP)Universidade Federal da Bahia Instituto de QuímicaLago, Joao Henrique Ghilardi [UNIFESP]Roque, Nídia Franca2015-06-14T13:38:58Z2015-06-14T13:38:58Z2009-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion2351-2354application/pdfhttp://dx.doi.org/10.1590/S0100-40422009000900022LAGO, João Henrique Ghilardi; ROQUE, Nídia Franca. Estudo fitoquímico da madeira de Guarea macrophylla (Meliaceae). Quím. Nova, São Paulo , v. 32, n. 9, p. 2351-2354, 200910.1590/S0100-40422009000900022S0100-40422009000900022.pdf0100-4042S0100-40422009000900022http://repositorio.unifesp.br/handle/11600/4786WOS:000273059500022porQuímica Novainfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UNIFESPinstname:Universidade Federal de São Paulo (UNIFESP)instacron:UNIFESP2024-07-29T16:27:41Zoai:repositorio.unifesp.br/:11600/4786Repositório InstitucionalPUBhttp://www.repositorio.unifesp.br/oai/requestbiblioteca.csp@unifesp.bropendoar:34652024-07-29T16:27:41Repositório Institucional da UNIFESP - Universidade Federal de São Paulo (UNIFESP)false
dc.title.none.fl_str_mv Estudo fitoquímico da madeira de Guarea macrophylla (Meliaceae)
Phytochemical study of the wood from Guarea macrophylla (Meliaceae)
title Estudo fitoquímico da madeira de Guarea macrophylla (Meliaceae)
spellingShingle Estudo fitoquímico da madeira de Guarea macrophylla (Meliaceae)
Lago, Joao Henrique Ghilardi [UNIFESP]
Meliaceae
Guarea macrophylla
cycloartane triterpenoids
title_short Estudo fitoquímico da madeira de Guarea macrophylla (Meliaceae)
title_full Estudo fitoquímico da madeira de Guarea macrophylla (Meliaceae)
title_fullStr Estudo fitoquímico da madeira de Guarea macrophylla (Meliaceae)
title_full_unstemmed Estudo fitoquímico da madeira de Guarea macrophylla (Meliaceae)
title_sort Estudo fitoquímico da madeira de Guarea macrophylla (Meliaceae)
author Lago, Joao Henrique Ghilardi [UNIFESP]
author_facet Lago, Joao Henrique Ghilardi [UNIFESP]
Roque, Nídia Franca
author_role author
author2 Roque, Nídia Franca
author2_role author
dc.contributor.none.fl_str_mv Universidade Federal de São Paulo (UNIFESP)
Universidade Federal da Bahia Instituto de Química
dc.contributor.author.fl_str_mv Lago, Joao Henrique Ghilardi [UNIFESP]
Roque, Nídia Franca
dc.subject.por.fl_str_mv Meliaceae
Guarea macrophylla
cycloartane triterpenoids
topic Meliaceae
Guarea macrophylla
cycloartane triterpenoids
description In the present work, the crude ethanol extract from wood of G. macrophylla was submitted to liquid/liquid partition between hexane, CH2Cl2, EtOAc and n-BuOH. Each phase was individually chromatographed over silica gel, Sephadex LH-20 or Amberlite XAD-2 to give eight terpene derivatives, such as five sesquiterpenoids (caryophyllene oxide, guai-6-en-10β-ol, spathulenol, aromadendrane-4β,10α-diol and aloaromadendrane-4α,10β-diol) as well as three triterpenoids (cicloart-24-ene-3β,23(R*)-diol, cicloart-24-ene-3β,23(S*)-diol, and cicloart-23E-ene-3β,25-diol). Additionally, were isolated three fatty acids (linolenic, linoleic and stearic), two steroids (sitosterol and stigmasterol) and sacarose. The structures of all these compounds were characterized by spectrometric analysis, mainly mass spectrometry and NMR and comparison of these data described in the literature.
publishDate 2009
dc.date.none.fl_str_mv 2009-01-01
2015-06-14T13:38:58Z
2015-06-14T13:38:58Z
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1590/S0100-40422009000900022
LAGO, João Henrique Ghilardi; ROQUE, Nídia Franca. Estudo fitoquímico da madeira de Guarea macrophylla (Meliaceae). Quím. Nova, São Paulo , v. 32, n. 9, p. 2351-2354, 2009
10.1590/S0100-40422009000900022
S0100-40422009000900022.pdf
0100-4042
S0100-40422009000900022
http://repositorio.unifesp.br/handle/11600/4786
WOS:000273059500022
url http://dx.doi.org/10.1590/S0100-40422009000900022
http://repositorio.unifesp.br/handle/11600/4786
identifier_str_mv LAGO, João Henrique Ghilardi; ROQUE, Nídia Franca. Estudo fitoquímico da madeira de Guarea macrophylla (Meliaceae). Quím. Nova, São Paulo , v. 32, n. 9, p. 2351-2354, 2009
10.1590/S0100-40422009000900022
S0100-40422009000900022.pdf
0100-4042
S0100-40422009000900022
WOS:000273059500022
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv Química Nova
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 2351-2354
application/pdf
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv reponame:Repositório Institucional da UNIFESP
instname:Universidade Federal de São Paulo (UNIFESP)
instacron:UNIFESP
instname_str Universidade Federal de São Paulo (UNIFESP)
instacron_str UNIFESP
institution UNIFESP
reponame_str Repositório Institucional da UNIFESP
collection Repositório Institucional da UNIFESP
repository.name.fl_str_mv Repositório Institucional da UNIFESP - Universidade Federal de São Paulo (UNIFESP)
repository.mail.fl_str_mv biblioteca.csp@unifesp.br
_version_ 1814268395235835904

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