Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content

Detalhes bibliográficos
Autor(a) principal: Asencios, Yvan Jesus Olortiga [UNIFESP]
Data de Publicação: 2016
Outros Autores: Marcos, Francielle Candian Firmino, Assaf, Jose Mansur, Assaf, Elisabete Moreira
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNIFESP
Texto Completo: https://dx.doi.org/10.1590/0104-6632.20160333s20150056
https://repositorio.unifesp.br/handle/11600/57573
Resumo: In this work the behavior of NiO-PrO2-ZrO2 catalysts containing various nickel loadings was evaluated in the partial oxidation of methane and oxidative-reforming reactions of methane. The catalysts were characterized by X-Ray Diffraction Analysis (in situ-XRD), Temperature Programmed Reduction (H-2-TPR), Scanning Electron Microscopy (SEM/EDX) and Adsorption-Desorption of nitrogen (BET area). The reactions were carried out at 750 degrees C and 1 atm for 5 hours. The catalysts were studied with different nickel content: 0, 5, 10 and 15% (related to total weight of catalyst, wt%). In both reactions, the catalyst containing the mixture of the three oxides (NiO/PrO2/ZrO2) with 15% nickel (15NiPrZr catalyst) showed the best activity for the conversion of the reactants into Syngas and showed high selectivity for H-2 and CO. The results suggest that the promoter PrO2 and the Ni degrees centers are in a good proportion in the catalyst with 15% Ni. Our results showed that low nickel concentrations in the catalyst led to high metallic dispersion; however, very low nickel concentrations did not favor the methane transformation into Syngas. The catalyst containing only NiO/ZrO2 in the mixture was not sufficient for the catalysis. The presence of the promoter PrO2 was very important for the catalysis of the POM.
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spelling Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel contentReforming methanePartial-oxidationSyngasNickel-contentPraseodymiumIn this work the behavior of NiO-PrO2-ZrO2 catalysts containing various nickel loadings was evaluated in the partial oxidation of methane and oxidative-reforming reactions of methane. The catalysts were characterized by X-Ray Diffraction Analysis (in situ-XRD), Temperature Programmed Reduction (H-2-TPR), Scanning Electron Microscopy (SEM/EDX) and Adsorption-Desorption of nitrogen (BET area). The reactions were carried out at 750 degrees C and 1 atm for 5 hours. The catalysts were studied with different nickel content: 0, 5, 10 and 15% (related to total weight of catalyst, wt%). In both reactions, the catalyst containing the mixture of the three oxides (NiO/PrO2/ZrO2) with 15% nickel (15NiPrZr catalyst) showed the best activity for the conversion of the reactants into Syngas and showed high selectivity for H-2 and CO. The results suggest that the promoter PrO2 and the Ni degrees centers are in a good proportion in the catalyst with 15% Ni. Our results showed that low nickel concentrations in the catalyst led to high metallic dispersion; however, very low nickel concentrations did not favor the methane transformation into Syngas. The catalyst containing only NiO/ZrO2 in the mixture was not sufficient for the catalysis. The presence of the promoter PrO2 was very important for the catalysis of the POM.Univ Fed Sao Paulo, Inst Mar, BR-11070100 Santos, SP, BrazilUniv Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, BrazilUniv Fed Sao Carlos, Dept Engn Quim, BR-13565905 Sao Carlos, SP, BrazilUniv Fed Sao Paulo, Inst Mar, BR-11070100 Santos, SP, BrazilWeb of ScienceBrazilian Soc Chemical EngUniversidade Federal de São Paulo (UNIFESP)Asencios, Yvan Jesus Olortiga [UNIFESP]Marcos, Francielle Candian FirminoAssaf, Jose MansurAssaf, Elisabete Moreira2020-08-14T13:44:17Z2020-08-14T13:44:17Z2016info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion627-636application/pdfhttps://dx.doi.org/10.1590/0104-6632.20160333s20150056Brazilian Journal Of Chemical Engineering. Sao Paulo, v. 33, n. 3, p. 627-636, 2016.10.1590/0104-6632.20160333s20150056S0104-66322016000300627.pdf0104-6632S0104-66322016000300627https://repositorio.unifesp.br/handle/11600/57573WOS:000389234200020engBrazilian Journal Of Chemical Engineering20th Brazilian Congress of Chemical Engineering (COBEQ)Sao Pauloinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UNIFESPinstname:Universidade Federal de São Paulo (UNIFESP)instacron:UNIFESP2024-08-08T22:21:46Zoai:repositorio.unifesp.br/:11600/57573Repositório InstitucionalPUBhttp://www.repositorio.unifesp.br/oai/requestbiblioteca.csp@unifesp.bropendoar:34652024-08-08T22:21:46Repositório Institucional da UNIFESP - Universidade Federal de São Paulo (UNIFESP)false
dc.title.none.fl_str_mv Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content
title Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content
spellingShingle Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content
Asencios, Yvan Jesus Olortiga [UNIFESP]
Reforming methane
Partial-oxidation
Syngas
Nickel-content
Praseodymium
title_short Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content
title_full Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content
title_fullStr Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content
title_full_unstemmed Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content
title_sort Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content
author Asencios, Yvan Jesus Olortiga [UNIFESP]
author_facet Asencios, Yvan Jesus Olortiga [UNIFESP]
Marcos, Francielle Candian Firmino
Assaf, Jose Mansur
Assaf, Elisabete Moreira
author_role author
author2 Marcos, Francielle Candian Firmino
Assaf, Jose Mansur
Assaf, Elisabete Moreira
author2_role author
author
author
dc.contributor.none.fl_str_mv Universidade Federal de São Paulo (UNIFESP)
dc.contributor.author.fl_str_mv Asencios, Yvan Jesus Olortiga [UNIFESP]
Marcos, Francielle Candian Firmino
Assaf, Jose Mansur
Assaf, Elisabete Moreira
dc.subject.por.fl_str_mv Reforming methane
Partial-oxidation
Syngas
Nickel-content
Praseodymium
topic Reforming methane
Partial-oxidation
Syngas
Nickel-content
Praseodymium
description In this work the behavior of NiO-PrO2-ZrO2 catalysts containing various nickel loadings was evaluated in the partial oxidation of methane and oxidative-reforming reactions of methane. The catalysts were characterized by X-Ray Diffraction Analysis (in situ-XRD), Temperature Programmed Reduction (H-2-TPR), Scanning Electron Microscopy (SEM/EDX) and Adsorption-Desorption of nitrogen (BET area). The reactions were carried out at 750 degrees C and 1 atm for 5 hours. The catalysts were studied with different nickel content: 0, 5, 10 and 15% (related to total weight of catalyst, wt%). In both reactions, the catalyst containing the mixture of the three oxides (NiO/PrO2/ZrO2) with 15% nickel (15NiPrZr catalyst) showed the best activity for the conversion of the reactants into Syngas and showed high selectivity for H-2 and CO. The results suggest that the promoter PrO2 and the Ni degrees centers are in a good proportion in the catalyst with 15% Ni. Our results showed that low nickel concentrations in the catalyst led to high metallic dispersion; however, very low nickel concentrations did not favor the methane transformation into Syngas. The catalyst containing only NiO/ZrO2 in the mixture was not sufficient for the catalysis. The presence of the promoter PrO2 was very important for the catalysis of the POM.
publishDate 2016
dc.date.none.fl_str_mv 2016
2020-08-14T13:44:17Z
2020-08-14T13:44:17Z
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://dx.doi.org/10.1590/0104-6632.20160333s20150056
Brazilian Journal Of Chemical Engineering. Sao Paulo, v. 33, n. 3, p. 627-636, 2016.
10.1590/0104-6632.20160333s20150056
S0104-66322016000300627.pdf
0104-6632
S0104-66322016000300627
https://repositorio.unifesp.br/handle/11600/57573
WOS:000389234200020
url https://dx.doi.org/10.1590/0104-6632.20160333s20150056
https://repositorio.unifesp.br/handle/11600/57573
identifier_str_mv Brazilian Journal Of Chemical Engineering. Sao Paulo, v. 33, n. 3, p. 627-636, 2016.
10.1590/0104-6632.20160333s20150056
S0104-66322016000300627.pdf
0104-6632
S0104-66322016000300627
WOS:000389234200020
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Brazilian Journal Of Chemical Engineering
20th Brazilian Congress of Chemical Engineering (COBEQ)
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 627-636
application/pdf
dc.coverage.none.fl_str_mv Sao Paulo
dc.publisher.none.fl_str_mv Brazilian Soc Chemical Eng
publisher.none.fl_str_mv Brazilian Soc Chemical Eng
dc.source.none.fl_str_mv reponame:Repositório Institucional da UNIFESP
instname:Universidade Federal de São Paulo (UNIFESP)
instacron:UNIFESP
instname_str Universidade Federal de São Paulo (UNIFESP)
instacron_str UNIFESP
institution UNIFESP
reponame_str Repositório Institucional da UNIFESP
collection Repositório Institucional da UNIFESP
repository.name.fl_str_mv Repositório Institucional da UNIFESP - Universidade Federal de São Paulo (UNIFESP)
repository.mail.fl_str_mv biblioteca.csp@unifesp.br
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