Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content
Autor(a) principal: | |
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Data de Publicação: | 2016 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNIFESP |
Texto Completo: | https://dx.doi.org/10.1590/0104-6632.20160333s20150056 https://repositorio.unifesp.br/handle/11600/57573 |
Resumo: | In this work the behavior of NiO-PrO2-ZrO2 catalysts containing various nickel loadings was evaluated in the partial oxidation of methane and oxidative-reforming reactions of methane. The catalysts were characterized by X-Ray Diffraction Analysis (in situ-XRD), Temperature Programmed Reduction (H-2-TPR), Scanning Electron Microscopy (SEM/EDX) and Adsorption-Desorption of nitrogen (BET area). The reactions were carried out at 750 degrees C and 1 atm for 5 hours. The catalysts were studied with different nickel content: 0, 5, 10 and 15% (related to total weight of catalyst, wt%). In both reactions, the catalyst containing the mixture of the three oxides (NiO/PrO2/ZrO2) with 15% nickel (15NiPrZr catalyst) showed the best activity for the conversion of the reactants into Syngas and showed high selectivity for H-2 and CO. The results suggest that the promoter PrO2 and the Ni degrees centers are in a good proportion in the catalyst with 15% Ni. Our results showed that low nickel concentrations in the catalyst led to high metallic dispersion; however, very low nickel concentrations did not favor the methane transformation into Syngas. The catalyst containing only NiO/ZrO2 in the mixture was not sufficient for the catalysis. The presence of the promoter PrO2 was very important for the catalysis of the POM. |
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Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel contentReforming methanePartial-oxidationSyngasNickel-contentPraseodymiumIn this work the behavior of NiO-PrO2-ZrO2 catalysts containing various nickel loadings was evaluated in the partial oxidation of methane and oxidative-reforming reactions of methane. The catalysts were characterized by X-Ray Diffraction Analysis (in situ-XRD), Temperature Programmed Reduction (H-2-TPR), Scanning Electron Microscopy (SEM/EDX) and Adsorption-Desorption of nitrogen (BET area). The reactions were carried out at 750 degrees C and 1 atm for 5 hours. The catalysts were studied with different nickel content: 0, 5, 10 and 15% (related to total weight of catalyst, wt%). In both reactions, the catalyst containing the mixture of the three oxides (NiO/PrO2/ZrO2) with 15% nickel (15NiPrZr catalyst) showed the best activity for the conversion of the reactants into Syngas and showed high selectivity for H-2 and CO. The results suggest that the promoter PrO2 and the Ni degrees centers are in a good proportion in the catalyst with 15% Ni. Our results showed that low nickel concentrations in the catalyst led to high metallic dispersion; however, very low nickel concentrations did not favor the methane transformation into Syngas. The catalyst containing only NiO/ZrO2 in the mixture was not sufficient for the catalysis. The presence of the promoter PrO2 was very important for the catalysis of the POM.Univ Fed Sao Paulo, Inst Mar, BR-11070100 Santos, SP, BrazilUniv Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, BrazilUniv Fed Sao Carlos, Dept Engn Quim, BR-13565905 Sao Carlos, SP, BrazilUniv Fed Sao Paulo, Inst Mar, BR-11070100 Santos, SP, BrazilWeb of ScienceBrazilian Soc Chemical EngUniversidade Federal de São Paulo (UNIFESP)Asencios, Yvan Jesus Olortiga [UNIFESP]Marcos, Francielle Candian FirminoAssaf, Jose MansurAssaf, Elisabete Moreira2020-08-14T13:44:17Z2020-08-14T13:44:17Z2016info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion627-636application/pdfhttps://dx.doi.org/10.1590/0104-6632.20160333s20150056Brazilian Journal Of Chemical Engineering. Sao Paulo, v. 33, n. 3, p. 627-636, 2016.10.1590/0104-6632.20160333s20150056S0104-66322016000300627.pdf0104-6632S0104-66322016000300627https://repositorio.unifesp.br/handle/11600/57573WOS:000389234200020engBrazilian Journal Of Chemical Engineering20th Brazilian Congress of Chemical Engineering (COBEQ)Sao Pauloinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UNIFESPinstname:Universidade Federal de São Paulo (UNIFESP)instacron:UNIFESP2024-08-08T22:21:46Zoai:repositorio.unifesp.br/:11600/57573Repositório InstitucionalPUBhttp://www.repositorio.unifesp.br/oai/requestbiblioteca.csp@unifesp.bropendoar:34652024-08-08T22:21:46Repositório Institucional da UNIFESP - Universidade Federal de São Paulo (UNIFESP)false |
dc.title.none.fl_str_mv |
Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content |
title |
Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content |
spellingShingle |
Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content Asencios, Yvan Jesus Olortiga [UNIFESP] Reforming methane Partial-oxidation Syngas Nickel-content Praseodymium |
title_short |
Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content |
title_full |
Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content |
title_fullStr |
Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content |
title_full_unstemmed |
Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content |
title_sort |
Oxidative-reforming of methane and partial oxidation of methane reactions over nio/pro2/zro2 catalysts: effect of nickel content |
author |
Asencios, Yvan Jesus Olortiga [UNIFESP] |
author_facet |
Asencios, Yvan Jesus Olortiga [UNIFESP] Marcos, Francielle Candian Firmino Assaf, Jose Mansur Assaf, Elisabete Moreira |
author_role |
author |
author2 |
Marcos, Francielle Candian Firmino Assaf, Jose Mansur Assaf, Elisabete Moreira |
author2_role |
author author author |
dc.contributor.none.fl_str_mv |
Universidade Federal de São Paulo (UNIFESP) |
dc.contributor.author.fl_str_mv |
Asencios, Yvan Jesus Olortiga [UNIFESP] Marcos, Francielle Candian Firmino Assaf, Jose Mansur Assaf, Elisabete Moreira |
dc.subject.por.fl_str_mv |
Reforming methane Partial-oxidation Syngas Nickel-content Praseodymium |
topic |
Reforming methane Partial-oxidation Syngas Nickel-content Praseodymium |
description |
In this work the behavior of NiO-PrO2-ZrO2 catalysts containing various nickel loadings was evaluated in the partial oxidation of methane and oxidative-reforming reactions of methane. The catalysts were characterized by X-Ray Diffraction Analysis (in situ-XRD), Temperature Programmed Reduction (H-2-TPR), Scanning Electron Microscopy (SEM/EDX) and Adsorption-Desorption of nitrogen (BET area). The reactions were carried out at 750 degrees C and 1 atm for 5 hours. The catalysts were studied with different nickel content: 0, 5, 10 and 15% (related to total weight of catalyst, wt%). In both reactions, the catalyst containing the mixture of the three oxides (NiO/PrO2/ZrO2) with 15% nickel (15NiPrZr catalyst) showed the best activity for the conversion of the reactants into Syngas and showed high selectivity for H-2 and CO. The results suggest that the promoter PrO2 and the Ni degrees centers are in a good proportion in the catalyst with 15% Ni. Our results showed that low nickel concentrations in the catalyst led to high metallic dispersion; however, very low nickel concentrations did not favor the methane transformation into Syngas. The catalyst containing only NiO/ZrO2 in the mixture was not sufficient for the catalysis. The presence of the promoter PrO2 was very important for the catalysis of the POM. |
publishDate |
2016 |
dc.date.none.fl_str_mv |
2016 2020-08-14T13:44:17Z 2020-08-14T13:44:17Z |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://dx.doi.org/10.1590/0104-6632.20160333s20150056 Brazilian Journal Of Chemical Engineering. Sao Paulo, v. 33, n. 3, p. 627-636, 2016. 10.1590/0104-6632.20160333s20150056 S0104-66322016000300627.pdf 0104-6632 S0104-66322016000300627 https://repositorio.unifesp.br/handle/11600/57573 WOS:000389234200020 |
url |
https://dx.doi.org/10.1590/0104-6632.20160333s20150056 https://repositorio.unifesp.br/handle/11600/57573 |
identifier_str_mv |
Brazilian Journal Of Chemical Engineering. Sao Paulo, v. 33, n. 3, p. 627-636, 2016. 10.1590/0104-6632.20160333s20150056 S0104-66322016000300627.pdf 0104-6632 S0104-66322016000300627 WOS:000389234200020 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Brazilian Journal Of Chemical Engineering 20th Brazilian Congress of Chemical Engineering (COBEQ) |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
627-636 application/pdf |
dc.coverage.none.fl_str_mv |
Sao Paulo |
dc.publisher.none.fl_str_mv |
Brazilian Soc Chemical Eng |
publisher.none.fl_str_mv |
Brazilian Soc Chemical Eng |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UNIFESP instname:Universidade Federal de São Paulo (UNIFESP) instacron:UNIFESP |
instname_str |
Universidade Federal de São Paulo (UNIFESP) |
instacron_str |
UNIFESP |
institution |
UNIFESP |
reponame_str |
Repositório Institucional da UNIFESP |
collection |
Repositório Institucional da UNIFESP |
repository.name.fl_str_mv |
Repositório Institucional da UNIFESP - Universidade Federal de São Paulo (UNIFESP) |
repository.mail.fl_str_mv |
biblioteca.csp@unifesp.br |
_version_ |
1814268307208929280 |