Sorption and desorption of ametryn in different types of soils
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Bioscience journal (Online) |
Texto Completo: | https://seer.ufu.br/index.php/biosciencejournal/article/view/42433 |
Resumo: | Knowledge of factors related to the dynamics of herbicides in the environment is of fundamental importance to predicting the behavior of herbicides in soils with different attributes, to select appropriate dosages, as well as to avoid harmful effects on the environment and subsequent crops. The objective of this work was to evaluate the sorption and desorption of ametryn in seven soils with different attributes. Initially, the equilibrium time was determined by the "Batch Equilibrium". Then, it was performed the sorption test with different concentrations (0.5; 1; 2; 4; 8; 16; 24 and 32 mg L-1) of ametryn in 0.01 mol L-1 CaCl2. 10 mL of these solutions were added to samples of 2.00 g of each soil, remaining under rotary shaking for 4 hours. After centrifugation and filtration, the ametryn concentration in the supernatant was determined by high-performance liquid chromatography. Desorption was evaluated using the tubes containing 16 mg L-1 prior to sorption testing. The results indicated that the sorption and desorption of ametryn depend on the physicochemical attributes of the soil. Sorption was higher in soils with high organic matter content and high ion exchange capacity, while desorption was inversely proportional to sorption. |
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Sorption and desorption of ametryn in different types of soilsSorção e dessorção do ametryn em diferentes tipos de solosCarryoverChemical controlHerbicide.Weed.Agricultural Sciences Knowledge of factors related to the dynamics of herbicides in the environment is of fundamental importance to predicting the behavior of herbicides in soils with different attributes, to select appropriate dosages, as well as to avoid harmful effects on the environment and subsequent crops. The objective of this work was to evaluate the sorption and desorption of ametryn in seven soils with different attributes. Initially, the equilibrium time was determined by the "Batch Equilibrium". Then, it was performed the sorption test with different concentrations (0.5; 1; 2; 4; 8; 16; 24 and 32 mg L-1) of ametryn in 0.01 mol L-1 CaCl2. 10 mL of these solutions were added to samples of 2.00 g of each soil, remaining under rotary shaking for 4 hours. After centrifugation and filtration, the ametryn concentration in the supernatant was determined by high-performance liquid chromatography. Desorption was evaluated using the tubes containing 16 mg L-1 prior to sorption testing. The results indicated that the sorption and desorption of ametryn depend on the physicochemical attributes of the soil. Sorption was higher in soils with high organic matter content and high ion exchange capacity, while desorption was inversely proportional to sorption.O conhecimento dos fatores relacionados à dinâmica de herbicidas no ambiente é de fundamental importância para prever o comportamento de herbicidas em solos com diferentes atributos e para seleção de dosagens adequadas, bem como para evitar efeitos prejudiciais ao ambiente e às culturas subsequentes. O objetivo do trabalho foi avaliar a sorção e dessorção do ametryn em sete solos com diferentes atributos. Inicialmente, foi determinado o tempo de equilíbrio pelo método “Batch Equilibrium”. Em seguida foi realizado o ensaio de sorção com diferentes concentrações (0,5; 1; 2; 4; 8; 16; 24 e 32 mg L-1) de ametryn em CaCl2 0,01 mol L-1. Foram adicionadas 10 mL destas soluções a amostras de 2,00 g de cada solo, permanecendo sob agitação rotatória por 4 horas. Após centrifugação e filtração, a concentração do ametryn no sobrenadante foi determinada por cromatografia líquida de alta eficiência. A dessorção foi avaliada utilizando os tubos que continham 16 mg L-1 antes do ensaio de sorção. Os resultados indicaram que a sorção e a dessorção do ametryn depende dos atributos físico-químicos do solo. A sorção foi maior em solos com alto teor matéria orgânica e alta capacidade de troca iônica, enquanto que a dessorção foi inversamente proporcional à sorção.EDUFU2019-12-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://seer.ufu.br/index.php/biosciencejournal/article/view/4243310.14393/BJ-v35n6a2019-42433Bioscience Journal ; Vol. 35 No. 6 (2019): Nov./Dec.; 1718-1727Bioscience Journal ; v. 35 n. 6 (2019): Nov./Dec.; 1718-17271981-3163reponame:Bioscience journal (Online)instname:Universidade Federal de Uberlândia (UFU)instacron:UFUenghttps://seer.ufu.br/index.php/biosciencejournal/article/view/42433/27452Brazil; ContemporaryCopyright (c) 2019 Alanna Oliveira Cortez, Paulo Sérgio Fernandes das Chagas, Tatiane Severo Silva, Daniel Valadão Silva, Claudia Daianny Melo Freitas, Juliana de Paiva Pamplona, Hélida Campos de Mesquita, Matheus de Freitas Souzahttps://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessCortez, Alanna Oliveiradas Chagas, Paulo Sérgio FernandesSilva, Tatiane SeveroSilva, Daniel ValadãoFreitas, Claudia Daianny MeloPamplona, Juliana de Paivade Mesquita, Hélida CamposSouza, Matheus de Freitas2022-01-23T23:01:38Zoai:ojs.www.seer.ufu.br:article/42433Revistahttps://seer.ufu.br/index.php/biosciencejournalPUBhttps://seer.ufu.br/index.php/biosciencejournal/oaibiosciencej@ufu.br||1981-31631516-3725opendoar:2022-01-23T23:01:38Bioscience journal (Online) - Universidade Federal de Uberlândia (UFU)false |
dc.title.none.fl_str_mv |
Sorption and desorption of ametryn in different types of soils Sorção e dessorção do ametryn em diferentes tipos de solos |
title |
Sorption and desorption of ametryn in different types of soils |
spellingShingle |
Sorption and desorption of ametryn in different types of soils Cortez, Alanna Oliveira Carryover Chemical control Herbicide. Weed. Agricultural Sciences |
title_short |
Sorption and desorption of ametryn in different types of soils |
title_full |
Sorption and desorption of ametryn in different types of soils |
title_fullStr |
Sorption and desorption of ametryn in different types of soils |
title_full_unstemmed |
Sorption and desorption of ametryn in different types of soils |
title_sort |
Sorption and desorption of ametryn in different types of soils |
author |
Cortez, Alanna Oliveira |
author_facet |
Cortez, Alanna Oliveira das Chagas, Paulo Sérgio Fernandes Silva, Tatiane Severo Silva, Daniel Valadão Freitas, Claudia Daianny Melo Pamplona, Juliana de Paiva de Mesquita, Hélida Campos Souza, Matheus de Freitas |
author_role |
author |
author2 |
das Chagas, Paulo Sérgio Fernandes Silva, Tatiane Severo Silva, Daniel Valadão Freitas, Claudia Daianny Melo Pamplona, Juliana de Paiva de Mesquita, Hélida Campos Souza, Matheus de Freitas |
author2_role |
author author author author author author author |
dc.contributor.author.fl_str_mv |
Cortez, Alanna Oliveira das Chagas, Paulo Sérgio Fernandes Silva, Tatiane Severo Silva, Daniel Valadão Freitas, Claudia Daianny Melo Pamplona, Juliana de Paiva de Mesquita, Hélida Campos Souza, Matheus de Freitas |
dc.subject.por.fl_str_mv |
Carryover Chemical control Herbicide. Weed. Agricultural Sciences |
topic |
Carryover Chemical control Herbicide. Weed. Agricultural Sciences |
description |
Knowledge of factors related to the dynamics of herbicides in the environment is of fundamental importance to predicting the behavior of herbicides in soils with different attributes, to select appropriate dosages, as well as to avoid harmful effects on the environment and subsequent crops. The objective of this work was to evaluate the sorption and desorption of ametryn in seven soils with different attributes. Initially, the equilibrium time was determined by the "Batch Equilibrium". Then, it was performed the sorption test with different concentrations (0.5; 1; 2; 4; 8; 16; 24 and 32 mg L-1) of ametryn in 0.01 mol L-1 CaCl2. 10 mL of these solutions were added to samples of 2.00 g of each soil, remaining under rotary shaking for 4 hours. After centrifugation and filtration, the ametryn concentration in the supernatant was determined by high-performance liquid chromatography. Desorption was evaluated using the tubes containing 16 mg L-1 prior to sorption testing. The results indicated that the sorption and desorption of ametryn depend on the physicochemical attributes of the soil. Sorption was higher in soils with high organic matter content and high ion exchange capacity, while desorption was inversely proportional to sorption. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019-12-02 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://seer.ufu.br/index.php/biosciencejournal/article/view/42433 10.14393/BJ-v35n6a2019-42433 |
url |
https://seer.ufu.br/index.php/biosciencejournal/article/view/42433 |
identifier_str_mv |
10.14393/BJ-v35n6a2019-42433 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
https://seer.ufu.br/index.php/biosciencejournal/article/view/42433/27452 |
dc.rights.driver.fl_str_mv |
https://creativecommons.org/licenses/by/4.0 info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by/4.0 |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.coverage.none.fl_str_mv |
Brazil; Contemporary |
dc.publisher.none.fl_str_mv |
EDUFU |
publisher.none.fl_str_mv |
EDUFU |
dc.source.none.fl_str_mv |
Bioscience Journal ; Vol. 35 No. 6 (2019): Nov./Dec.; 1718-1727 Bioscience Journal ; v. 35 n. 6 (2019): Nov./Dec.; 1718-1727 1981-3163 reponame:Bioscience journal (Online) instname:Universidade Federal de Uberlândia (UFU) instacron:UFU |
instname_str |
Universidade Federal de Uberlândia (UFU) |
instacron_str |
UFU |
institution |
UFU |
reponame_str |
Bioscience journal (Online) |
collection |
Bioscience journal (Online) |
repository.name.fl_str_mv |
Bioscience journal (Online) - Universidade Federal de Uberlândia (UFU) |
repository.mail.fl_str_mv |
biosciencej@ufu.br|| |
_version_ |
1797069080441651200 |