Evaluation of the temperature effect on vegetable oils by chemical analysis and ultraviolet-visible spectroscopy

Detalhes bibliográficos
Autor(a) principal: Araújo, Ana Paula Caixeta
Data de Publicação: 2018
Outros Autores: do Monte, Adamo Ferreira Gomes, Batista, Fabiana Regina Xavier
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Bioscience journal (Online)
Texto Completo: https://seer.ufu.br/index.php/biosciencejournal/article/view/39934
Resumo: Several methodologies could be used to characterize vegetable oil besides estimating thermal modification provided by high temperatures. These techniques are used as a proper tool to determine compositional and functional analysis of food ingredients and finished products. In general, vegetable oils are extracted from seeds like the rapeseed (canola oil) soybean (soybean oil), among others. In the current work vegetable oils such as canola and soybean were heated at a temperature of 100°C from 1h up to 28 h and the degraded products were measured to assess the oil stability at temperature. The determination of acid number, peroxide value and iodine number by chemical analysis was carried out for the estimation of the oxidative heat stability of these oils. Ultraviolet-visible spectroscopy strategy was also used to better comprehend this phenomenon, since it greatly improve the performance of measurements, in order to step up sensitivity. The findings demonstrated that vegetable oils thermal deteriorated as seen in the batocromic displacement of the samples heated and increasing the specific absorption in 350 nm. These data were capable to highlight the differences observed in the degree of unsaturation of oils.
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spelling Evaluation of the temperature effect on vegetable oils by chemical analysis and ultraviolet-visible spectroscopy Avaliação do efeito da temperature em óleos vegetais por analyses químicas e espectroscopia ultravioleta visívelSoybeanCanolaAcid numberPeroxide valueIodine numberUltraviolet–visible spectroscopyAgricultural SciencesSeveral methodologies could be used to characterize vegetable oil besides estimating thermal modification provided by high temperatures. These techniques are used as a proper tool to determine compositional and functional analysis of food ingredients and finished products. In general, vegetable oils are extracted from seeds like the rapeseed (canola oil) soybean (soybean oil), among others. In the current work vegetable oils such as canola and soybean were heated at a temperature of 100°C from 1h up to 28 h and the degraded products were measured to assess the oil stability at temperature. The determination of acid number, peroxide value and iodine number by chemical analysis was carried out for the estimation of the oxidative heat stability of these oils. Ultraviolet-visible spectroscopy strategy was also used to better comprehend this phenomenon, since it greatly improve the performance of measurements, in order to step up sensitivity. The findings demonstrated that vegetable oils thermal deteriorated as seen in the batocromic displacement of the samples heated and increasing the specific absorption in 350 nm. These data were capable to highlight the differences observed in the degree of unsaturation of oils.Inúmeras metodologias podem ser utilizadas para caracterizar óleos vegetais, além de estimar modificações térmicas ocasionadas por altas temperaturas. Estas técnicas são usadas como ferramentas específicas paradeterminar a composição e função de ingredientes em alimentos e em produtos finais processados. Em geral, óleos vegetais são extraídos de sementes como a colza ou soja, entre outros. No presente trabalho, óleos vegetais como canola e soja foram aquecidos a temperatura de 100 °C entre 1 e 28 horas e os produtos de degradação foram medidos para avaliar a estabilidade do óleo na temperatura. As determinações da acidez, índice de peróxido e índice de iodo por análises químicas foram realizadas para estimar a estabilidade e a oxidação térmica dos óleos. A espectroscopia ultravioleta visível foi uma estratégia também utilizada para melhor compreender este fenômeno, uma vez que esta técnica aumenta o desempenho nas quantificações e quando se objetiva o incremento na sensibilidade. Os resultados demonstraram a deterioração térmica dos óleos vegetais através do deslocamento batocrômico das amostras aquecidas e o aumento da absorção a 350 nm. Estes dados ressaltam as diferenças observadas no grau de insaturação dos óleos. EDUFU2018-12-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://seer.ufu.br/index.php/biosciencejournal/article/view/3993410.14393/BJ-v34n6a2018-39934Bioscience Journal ; Vol. 34 (2018): Supplement 1; 28-36Bioscience Journal ; v. 34 (2018): Supplement 1; 28-361981-3163reponame:Bioscience journal (Online)instname:Universidade Federal de Uberlândia (UFU)instacron:UFUenghttps://seer.ufu.br/index.php/biosciencejournal/article/view/39934/24771Brazil; ContemporaryCopyright (c) 2018 Ana Paula Caixeta Araújo, Adamo Ferreira Gomes do Monte, Fabiana Regina Xavier Batistahttps://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessAraújo, Ana Paula Caixetado Monte, Adamo Ferreira GomesBatista, Fabiana Regina Xavier2022-03-23T11:07:58Zoai:ojs.www.seer.ufu.br:article/39934Revistahttps://seer.ufu.br/index.php/biosciencejournalPUBhttps://seer.ufu.br/index.php/biosciencejournal/oaibiosciencej@ufu.br||1981-31631516-3725opendoar:2022-03-23T11:07:58Bioscience journal (Online) - Universidade Federal de Uberlândia (UFU)false
dc.title.none.fl_str_mv Evaluation of the temperature effect on vegetable oils by chemical analysis and ultraviolet-visible spectroscopy
Avaliação do efeito da temperature em óleos vegetais por analyses químicas e espectroscopia ultravioleta visível
title Evaluation of the temperature effect on vegetable oils by chemical analysis and ultraviolet-visible spectroscopy
spellingShingle Evaluation of the temperature effect on vegetable oils by chemical analysis and ultraviolet-visible spectroscopy
Araújo, Ana Paula Caixeta
Soybean
Canola
Acid number
Peroxide value
Iodine number
Ultraviolet–visible spectroscopy
Agricultural Sciences
title_short Evaluation of the temperature effect on vegetable oils by chemical analysis and ultraviolet-visible spectroscopy
title_full Evaluation of the temperature effect on vegetable oils by chemical analysis and ultraviolet-visible spectroscopy
title_fullStr Evaluation of the temperature effect on vegetable oils by chemical analysis and ultraviolet-visible spectroscopy
title_full_unstemmed Evaluation of the temperature effect on vegetable oils by chemical analysis and ultraviolet-visible spectroscopy
title_sort Evaluation of the temperature effect on vegetable oils by chemical analysis and ultraviolet-visible spectroscopy
author Araújo, Ana Paula Caixeta
author_facet Araújo, Ana Paula Caixeta
do Monte, Adamo Ferreira Gomes
Batista, Fabiana Regina Xavier
author_role author
author2 do Monte, Adamo Ferreira Gomes
Batista, Fabiana Regina Xavier
author2_role author
author
dc.contributor.author.fl_str_mv Araújo, Ana Paula Caixeta
do Monte, Adamo Ferreira Gomes
Batista, Fabiana Regina Xavier
dc.subject.por.fl_str_mv Soybean
Canola
Acid number
Peroxide value
Iodine number
Ultraviolet–visible spectroscopy
Agricultural Sciences
topic Soybean
Canola
Acid number
Peroxide value
Iodine number
Ultraviolet–visible spectroscopy
Agricultural Sciences
description Several methodologies could be used to characterize vegetable oil besides estimating thermal modification provided by high temperatures. These techniques are used as a proper tool to determine compositional and functional analysis of food ingredients and finished products. In general, vegetable oils are extracted from seeds like the rapeseed (canola oil) soybean (soybean oil), among others. In the current work vegetable oils such as canola and soybean were heated at a temperature of 100°C from 1h up to 28 h and the degraded products were measured to assess the oil stability at temperature. The determination of acid number, peroxide value and iodine number by chemical analysis was carried out for the estimation of the oxidative heat stability of these oils. Ultraviolet-visible spectroscopy strategy was also used to better comprehend this phenomenon, since it greatly improve the performance of measurements, in order to step up sensitivity. The findings demonstrated that vegetable oils thermal deteriorated as seen in the batocromic displacement of the samples heated and increasing the specific absorption in 350 nm. These data were capable to highlight the differences observed in the degree of unsaturation of oils.
publishDate 2018
dc.date.none.fl_str_mv 2018-12-06
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://seer.ufu.br/index.php/biosciencejournal/article/view/39934
10.14393/BJ-v34n6a2018-39934
url https://seer.ufu.br/index.php/biosciencejournal/article/view/39934
identifier_str_mv 10.14393/BJ-v34n6a2018-39934
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv https://seer.ufu.br/index.php/biosciencejournal/article/view/39934/24771
dc.rights.driver.fl_str_mv https://creativecommons.org/licenses/by/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.coverage.none.fl_str_mv Brazil; Contemporary
dc.publisher.none.fl_str_mv EDUFU
publisher.none.fl_str_mv EDUFU
dc.source.none.fl_str_mv Bioscience Journal ; Vol. 34 (2018): Supplement 1; 28-36
Bioscience Journal ; v. 34 (2018): Supplement 1; 28-36
1981-3163
reponame:Bioscience journal (Online)
instname:Universidade Federal de Uberlândia (UFU)
instacron:UFU
instname_str Universidade Federal de Uberlândia (UFU)
instacron_str UFU
institution UFU
reponame_str Bioscience journal (Online)
collection Bioscience journal (Online)
repository.name.fl_str_mv Bioscience journal (Online) - Universidade Federal de Uberlândia (UFU)
repository.mail.fl_str_mv biosciencej@ufu.br||
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