Otimização de poliuretanos para protetores de linhas flexíveis sujeitos ao desgaste abrasivo
Autor(a) principal: | |
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Data de Publicação: | 2007 |
Tipo de documento: | Dissertação |
Idioma: | por |
Título da fonte: | Repositório Institucional da UFU |
Texto Completo: | https://repositorio.ufu.br/handle/123456789/14800 |
Resumo: | n the last year the Petrobras Company gone self sufficiency of Brazil in the production of petroleum, It s take great effort to achieve technology in the exploration of deeper oil-well offshore. The extraction of petroleum deeper off-shore is make through flexible pipes that has multi layers of metal materials and polymeric materials, connected semi-submersible platform. This flexible pipes into contact with surface marine, in the area of touchdown point (TDP), sufferable abrasive wear. Currently the flexible pipes, at the TDP, are protected with bi part sleeve made in elastomer of polyurethane. This type of polyurethane has shown high performance against abrasive wear, when compared another polymers materials. This work has the objective of optimize the performance of elastômeros of polyurethane against abrasion wear at the TDP. This optimization was carried through formulation of various combinations of isocyanate and poliol, raw material by production of elastomer of polyurethane, with addition of solid lubricant molybdenum disulfide in the half of formulation. The evaluation of the molybdenum disulfide in the polyurethane was carried through structural characterization. The mechanical properties of formulations were carried through standard test methods for tension, elongation, tear strength, hardness, and rebound resilience. The wear resistance of formulations was carried through standard test methods for abrasion resistance according to the DIN 53.516 and Simulator of Interaction Marine-Mechanical in Sleeve (SIMMC), that it was development to evaluate sufferable abrasive wear for flexible pipe. The formulation of high performance had been submitted hydrolysis in hydrostatic compressive test equipment with heating. A correlation was looked among the properties obtained in the mathematical model efficient in the theoretical reproduction of the abrasive wear produced by SIMMC. In the end of this work got two formulations with high performance against wear abrasion. |
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Otimização de poliuretanos para protetores de linhas flexíveis sujeitos ao desgaste abrasivoOptimization of Polyurethanes for Protection of Flexible Pipes Subject at Abrasion WearLinhas flexíveisDesgaste abrasivoElastômero de poliuretanoLubrificanteElastômerosFlexible pipeAbrasive wearElastomer of polyurethaneLubricantCNPQ::ENGENHARIAS::ENGENHARIA MECANICAn the last year the Petrobras Company gone self sufficiency of Brazil in the production of petroleum, It s take great effort to achieve technology in the exploration of deeper oil-well offshore. The extraction of petroleum deeper off-shore is make through flexible pipes that has multi layers of metal materials and polymeric materials, connected semi-submersible platform. This flexible pipes into contact with surface marine, in the area of touchdown point (TDP), sufferable abrasive wear. Currently the flexible pipes, at the TDP, are protected with bi part sleeve made in elastomer of polyurethane. This type of polyurethane has shown high performance against abrasive wear, when compared another polymers materials. This work has the objective of optimize the performance of elastômeros of polyurethane against abrasion wear at the TDP. This optimization was carried through formulation of various combinations of isocyanate and poliol, raw material by production of elastomer of polyurethane, with addition of solid lubricant molybdenum disulfide in the half of formulation. The evaluation of the molybdenum disulfide in the polyurethane was carried through structural characterization. The mechanical properties of formulations were carried through standard test methods for tension, elongation, tear strength, hardness, and rebound resilience. The wear resistance of formulations was carried through standard test methods for abrasion resistance according to the DIN 53.516 and Simulator of Interaction Marine-Mechanical in Sleeve (SIMMC), that it was development to evaluate sufferable abrasive wear for flexible pipe. The formulation of high performance had been submitted hydrolysis in hydrostatic compressive test equipment with heating. A correlation was looked among the properties obtained in the mathematical model efficient in the theoretical reproduction of the abrasive wear produced by SIMMC. In the end of this work got two formulations with high performance against wear abrasion.Mestre em Engenharia MecânicaNo último ano a Petrobras conseguiu a auto-suficiência do Brasil na produção de petróleo, isso graças aos esforços para dominar a tecnologia em exploração de poços cada vez mais profundos. A extração de petróleo em grandes profundidades é realizada através linhas flexíveis compostas por multicamadas de materiais metálicos e poliméricos, acopladas a plataformas flutuantes. Essas linhas ao entrarem em contato com o solo marinho, numa região chamada TDP, sofrem desgaste abrasivo. Atualmente as linhas flexíveis nessa região são protegidas com calhas bipartidas fabricadas em elastômero de poliuretano. Esse tipo de poliuretano tem mostrado um desempenho superior contra o desgaste abrasivo em relação a outros materiais poliméricos. O presente trabalho tem o objetivo de otimizar o desempenho de elastômeros de poliuretano contra o desgaste abrasivo no TDP. Essa otimização foi realizada formulando-se diversas combinações de isocianatos e polióis, matérias-primas básica na produção de elastômeros de poliuretano, com a adição do lubrificante sólido bissulfeto de molibdênio em metade das formulações. A avaliação dos efeitos causados pela adição de lubrificante nos poliuretanos foi realizada através de ensaios de caracterização. O comportamento mecânico das formulações foi avaliado através de ensaios normatizados de tração, alongamento, resistência ao rasgo, dureza e resiliência. O desempenho das formulações contra o desgaste abrasivo foi avaliado através de ensaio de abrasão DIN 53.516 e um Simulador de Interações Marítimo-Mecânicas em Calhas (SIMMC), que foi especialmente desenvolvido para avaliar o desgaste abrasivo sofrido pelas linhas flexíveis. Além desses ensaios, as formulações de melhor desempenho foram submetidas à hidrólise em câmara hiperbárica com aquecimento. Procurou-se correlacionar as propriedades obtidas em um modelo matemático eficaz na reprodução teórica do desgaste abrasivo produzido pelo SIMMC. E ao final do trabalho foram obtidos dois materiais com excelente resistência ao desgaste abrasivo.Universidade Federal de UberlândiaBRPrograma de Pós-graduação em Engenharia MecânicaEngenhariasUFUFranco, Sinésio Domingueshttp://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4786105Z3Raslan, Alberto Arnaldohttp://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4787991J4Marinelli, Alessandra Lucashttp://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4790804A4Santos, Fábio Cordeiro dos2016-06-22T18:39:58Z2008-06-092016-06-22T18:39:58Z2007-09-19info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisapplication/pdfapplication/pdfapplication/pdfapplication/pdfSANTOS, Fábio Cordeiro dos. Optimization of Polyurethanes for Protection of Flexible Pipes Subject at Abrasion Wear. 2007. 187 f. Dissertação (Mestrado em Engenharias) - Universidade Federal de Uberlândia, Uberlândia, 2007.https://repositorio.ufu.br/handle/123456789/14800porinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFUinstname:Universidade Federal de Uberlândia (UFU)instacron:UFU2016-06-23T07:05:33Zoai:repositorio.ufu.br:123456789/14800Repositório InstitucionalONGhttp://repositorio.ufu.br/oai/requestdiinf@dirbi.ufu.bropendoar:2016-06-23T07:05:33Repositório Institucional da UFU - Universidade Federal de Uberlândia (UFU)false |
dc.title.none.fl_str_mv |
Otimização de poliuretanos para protetores de linhas flexíveis sujeitos ao desgaste abrasivo Optimization of Polyurethanes for Protection of Flexible Pipes Subject at Abrasion Wear |
title |
Otimização de poliuretanos para protetores de linhas flexíveis sujeitos ao desgaste abrasivo |
spellingShingle |
Otimização de poliuretanos para protetores de linhas flexíveis sujeitos ao desgaste abrasivo Santos, Fábio Cordeiro dos Linhas flexíveis Desgaste abrasivo Elastômero de poliuretano Lubrificante Elastômeros Flexible pipe Abrasive wear Elastomer of polyurethane Lubricant CNPQ::ENGENHARIAS::ENGENHARIA MECANICA |
title_short |
Otimização de poliuretanos para protetores de linhas flexíveis sujeitos ao desgaste abrasivo |
title_full |
Otimização de poliuretanos para protetores de linhas flexíveis sujeitos ao desgaste abrasivo |
title_fullStr |
Otimização de poliuretanos para protetores de linhas flexíveis sujeitos ao desgaste abrasivo |
title_full_unstemmed |
Otimização de poliuretanos para protetores de linhas flexíveis sujeitos ao desgaste abrasivo |
title_sort |
Otimização de poliuretanos para protetores de linhas flexíveis sujeitos ao desgaste abrasivo |
author |
Santos, Fábio Cordeiro dos |
author_facet |
Santos, Fábio Cordeiro dos |
author_role |
author |
dc.contributor.none.fl_str_mv |
Franco, Sinésio Domingues http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4786105Z3 Raslan, Alberto Arnaldo http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4787991J4 Marinelli, Alessandra Lucas http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4790804A4 |
dc.contributor.author.fl_str_mv |
Santos, Fábio Cordeiro dos |
dc.subject.por.fl_str_mv |
Linhas flexíveis Desgaste abrasivo Elastômero de poliuretano Lubrificante Elastômeros Flexible pipe Abrasive wear Elastomer of polyurethane Lubricant CNPQ::ENGENHARIAS::ENGENHARIA MECANICA |
topic |
Linhas flexíveis Desgaste abrasivo Elastômero de poliuretano Lubrificante Elastômeros Flexible pipe Abrasive wear Elastomer of polyurethane Lubricant CNPQ::ENGENHARIAS::ENGENHARIA MECANICA |
description |
n the last year the Petrobras Company gone self sufficiency of Brazil in the production of petroleum, It s take great effort to achieve technology in the exploration of deeper oil-well offshore. The extraction of petroleum deeper off-shore is make through flexible pipes that has multi layers of metal materials and polymeric materials, connected semi-submersible platform. This flexible pipes into contact with surface marine, in the area of touchdown point (TDP), sufferable abrasive wear. Currently the flexible pipes, at the TDP, are protected with bi part sleeve made in elastomer of polyurethane. This type of polyurethane has shown high performance against abrasive wear, when compared another polymers materials. This work has the objective of optimize the performance of elastômeros of polyurethane against abrasion wear at the TDP. This optimization was carried through formulation of various combinations of isocyanate and poliol, raw material by production of elastomer of polyurethane, with addition of solid lubricant molybdenum disulfide in the half of formulation. The evaluation of the molybdenum disulfide in the polyurethane was carried through structural characterization. The mechanical properties of formulations were carried through standard test methods for tension, elongation, tear strength, hardness, and rebound resilience. The wear resistance of formulations was carried through standard test methods for abrasion resistance according to the DIN 53.516 and Simulator of Interaction Marine-Mechanical in Sleeve (SIMMC), that it was development to evaluate sufferable abrasive wear for flexible pipe. The formulation of high performance had been submitted hydrolysis in hydrostatic compressive test equipment with heating. A correlation was looked among the properties obtained in the mathematical model efficient in the theoretical reproduction of the abrasive wear produced by SIMMC. In the end of this work got two formulations with high performance against wear abrasion. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007-09-19 2008-06-09 2016-06-22T18:39:58Z 2016-06-22T18:39:58Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/masterThesis |
format |
masterThesis |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
SANTOS, Fábio Cordeiro dos. Optimization of Polyurethanes for Protection of Flexible Pipes Subject at Abrasion Wear. 2007. 187 f. Dissertação (Mestrado em Engenharias) - Universidade Federal de Uberlândia, Uberlândia, 2007. https://repositorio.ufu.br/handle/123456789/14800 |
identifier_str_mv |
SANTOS, Fábio Cordeiro dos. Optimization of Polyurethanes for Protection of Flexible Pipes Subject at Abrasion Wear. 2007. 187 f. Dissertação (Mestrado em Engenharias) - Universidade Federal de Uberlândia, Uberlândia, 2007. |
url |
https://repositorio.ufu.br/handle/123456789/14800 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Federal de Uberlândia BR Programa de Pós-graduação em Engenharia Mecânica Engenharias UFU |
publisher.none.fl_str_mv |
Universidade Federal de Uberlândia BR Programa de Pós-graduação em Engenharia Mecânica Engenharias UFU |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFU instname:Universidade Federal de Uberlândia (UFU) instacron:UFU |
instname_str |
Universidade Federal de Uberlândia (UFU) |
instacron_str |
UFU |
institution |
UFU |
reponame_str |
Repositório Institucional da UFU |
collection |
Repositório Institucional da UFU |
repository.name.fl_str_mv |
Repositório Institucional da UFU - Universidade Federal de Uberlândia (UFU) |
repository.mail.fl_str_mv |
diinf@dirbi.ufu.br |
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1813711426932441088 |