APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE

Detalhes bibliográficos
Autor(a) principal: Hoga, Heloisa Emi
Data de Publicação: 2018
Outros Autores: Torres, Ricardo Belchior
Tipo de documento: Artigo
Idioma: por
Título da fonte: The Journal of Engineering and Exact Sciences
Texto Completo: https://periodicos.ufv.br/jcec/article/view/2494
Resumo: In the present study, experimental data of excess molar volumes ( ) of binary liquid mixtures of methyl tert butyl ether (MTBE) + methanol, or + ethanol, or + 1-propanol, or + 2-propanol, or + 1-butanol, or + 1-pentanol, or + 1-hexanol have been used to test the applicability of the Prigogine-Flory-Patterson theory (PFP) as a function of composition at different temperatures and atmospheric pressure. According to the model, interactional contribution is the most important one to explain the behavior. It may be observed that the PFP theory reproduces the main features of the experimental data by using only one fitted parameter adjusted. Good agreements between the experimental results and the theory were obtained for all the systems studied.
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spelling APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSUREAPLICAÇÃO DA TEORIA PRIGOGINE-FLORY-PATTERSON AO VOLUME MOLAR EXCESSO DE SOLUÇÕES LÍQUIDAS BINÁRIAS DE {METIL TERC BUTIL ÉTER (MTBE) + ALCOÓIS} A DIFERENTES TEMPERATURAS E PRESSÃO ATMOSFÉRICAMethyl tert butyl etherAlcoholsExcess molar volumePrigogine-Flory-Patterson theoryMetil terc butil éterÁlcooisVolume molar excessoTeoria Prigogine-Flory-PattersonIn the present study, experimental data of excess molar volumes ( ) of binary liquid mixtures of methyl tert butyl ether (MTBE) + methanol, or + ethanol, or + 1-propanol, or + 2-propanol, or + 1-butanol, or + 1-pentanol, or + 1-hexanol have been used to test the applicability of the Prigogine-Flory-Patterson theory (PFP) as a function of composition at different temperatures and atmospheric pressure. According to the model, interactional contribution is the most important one to explain the behavior. It may be observed that the PFP theory reproduces the main features of the experimental data by using only one fitted parameter adjusted. Good agreements between the experimental results and the theory were obtained for all the systems studied.No presente estudo, dados experimentais de volume molar excesso ( ) de soluções líquidas binárias de metil terc butl éter (MTBE) + metanol, ou + etanol, ou + 1-propanol, ou + 2-propanol, ou + 1-butanol, ou + 1-pentanol, ou + 1-hexanol foram usados para testar a aplicabilidade da Teoria Prigogine-Flory-Patterson (PFP Theory), como função da composição a diferentes temperaturas e pressão atmosférica. De acordo com o modelo, a contribuição interacional é a mais importante para descrever o comportamento do  . Foi observado que a Teoria PFP reproduz os dados experimentais usando apenas um parâmetro ajustável. Para todos os sistemas estudados foi obtida uma boa concordância entre os resultados experimentais e a Teoria.Universidade Federal de Viçosa - UFV2018-03-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufv.br/jcec/article/view/249410.18540/jcecvl4iss1pp0085-0091The Journal of Engineering and Exact Sciences; Vol. 4 No. 1 (2018); 0085-0091The Journal of Engineering and Exact Sciences; Vol. 4 Núm. 1 (2018); 0085-0091The Journal of Engineering and Exact Sciences; v. 4 n. 1 (2018); 0085-00912527-1075reponame:The Journal of Engineering and Exact Sciencesinstname:Universidade Federal de Viçosa (UFV)instacron:UFVporhttps://periodicos.ufv.br/jcec/article/view/2494/1045Hoga, Heloisa EmiTorres, Ricardo Belchiorinfo:eu-repo/semantics/openAccess2018-12-05T12:57:22Zoai:ojs.periodicos.ufv.br:article/2494Revistahttp://www.seer.ufv.br/seer/rbeq2/index.php/req2/oai2527-10752527-1075opendoar:2018-12-05T12:57:22The Journal of Engineering and Exact Sciences - Universidade Federal de Viçosa (UFV)false
dc.title.none.fl_str_mv APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE
APLICAÇÃO DA TEORIA PRIGOGINE-FLORY-PATTERSON AO VOLUME MOLAR EXCESSO DE SOLUÇÕES LÍQUIDAS BINÁRIAS DE {METIL TERC BUTIL ÉTER (MTBE) + ALCOÓIS} A DIFERENTES TEMPERATURAS E PRESSÃO ATMOSFÉRICA
title APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE
spellingShingle APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE
Hoga, Heloisa Emi
Methyl tert butyl ether
Alcohols
Excess molar volume
Prigogine-Flory-Patterson theory
Metil terc butil éter
Álcoois
Volume molar excesso
Teoria Prigogine-Flory-Patterson
title_short APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE
title_full APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE
title_fullStr APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE
title_full_unstemmed APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE
title_sort APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE
author Hoga, Heloisa Emi
author_facet Hoga, Heloisa Emi
Torres, Ricardo Belchior
author_role author
author2 Torres, Ricardo Belchior
author2_role author
dc.contributor.author.fl_str_mv Hoga, Heloisa Emi
Torres, Ricardo Belchior
dc.subject.por.fl_str_mv Methyl tert butyl ether
Alcohols
Excess molar volume
Prigogine-Flory-Patterson theory
Metil terc butil éter
Álcoois
Volume molar excesso
Teoria Prigogine-Flory-Patterson
topic Methyl tert butyl ether
Alcohols
Excess molar volume
Prigogine-Flory-Patterson theory
Metil terc butil éter
Álcoois
Volume molar excesso
Teoria Prigogine-Flory-Patterson
description In the present study, experimental data of excess molar volumes ( ) of binary liquid mixtures of methyl tert butyl ether (MTBE) + methanol, or + ethanol, or + 1-propanol, or + 2-propanol, or + 1-butanol, or + 1-pentanol, or + 1-hexanol have been used to test the applicability of the Prigogine-Flory-Patterson theory (PFP) as a function of composition at different temperatures and atmospheric pressure. According to the model, interactional contribution is the most important one to explain the behavior. It may be observed that the PFP theory reproduces the main features of the experimental data by using only one fitted parameter adjusted. Good agreements between the experimental results and the theory were obtained for all the systems studied.
publishDate 2018
dc.date.none.fl_str_mv 2018-03-02
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://periodicos.ufv.br/jcec/article/view/2494
10.18540/jcecvl4iss1pp0085-0091
url https://periodicos.ufv.br/jcec/article/view/2494
identifier_str_mv 10.18540/jcecvl4iss1pp0085-0091
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv https://periodicos.ufv.br/jcec/article/view/2494/1045
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal de Viçosa - UFV
publisher.none.fl_str_mv Universidade Federal de Viçosa - UFV
dc.source.none.fl_str_mv The Journal of Engineering and Exact Sciences; Vol. 4 No. 1 (2018); 0085-0091
The Journal of Engineering and Exact Sciences; Vol. 4 Núm. 1 (2018); 0085-0091
The Journal of Engineering and Exact Sciences; v. 4 n. 1 (2018); 0085-0091
2527-1075
reponame:The Journal of Engineering and Exact Sciences
instname:Universidade Federal de Viçosa (UFV)
instacron:UFV
instname_str Universidade Federal de Viçosa (UFV)
instacron_str UFV
institution UFV
reponame_str The Journal of Engineering and Exact Sciences
collection The Journal of Engineering and Exact Sciences
repository.name.fl_str_mv The Journal of Engineering and Exact Sciences - Universidade Federal de Viçosa (UFV)
repository.mail.fl_str_mv
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