DESIGN OF NA INDUSTRIAL PROCESS FO GLYCERIN CARBONATE PRODUCION
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | The Journal of Engineering and Exact Sciences |
Texto Completo: | https://periodicos.ufv.br/jcec/article/view/2446941603022017121 |
Resumo: | Biodiesel industries generates large amounts of glycerin what creates a demand for its suitable destination, with a possible transformation into a valuable product. One of these products is the glycerin carbonate. This substance has an increasing market as raw material for cosmetics, drugs, polymers and specilatiy solvents among others. This work shows an industrial process for the production of glycerin carbonate which achieves near complete conversion. The studies wre made with the use of the software Aspen Plus®. All physical equilibrium properties were calculated by the NRTL method. A process flowsheet with basic control strategy is presented. It has been also made a preliminary economic analysis based on ultilities, raw materials and product costs |
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The Journal of Engineering and Exact Sciences |
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DESIGN OF NA INDUSTRIAL PROCESS FO GLYCERIN CARBONATE PRODUCIONPROJETO DE INSTALAÇÃO DE PRODUÇÃO INDUSTRIAL DE CARBONATO DE GLICERINAglycerinetransesterificationcatalysisglycerine carbonateGlicerinaTransesterificaçãoCatáliseCarbonato de glicerinaBiodiesel industries generates large amounts of glycerin what creates a demand for its suitable destination, with a possible transformation into a valuable product. One of these products is the glycerin carbonate. This substance has an increasing market as raw material for cosmetics, drugs, polymers and specilatiy solvents among others. This work shows an industrial process for the production of glycerin carbonate which achieves near complete conversion. The studies wre made with the use of the software Aspen Plus®. All physical equilibrium properties were calculated by the NRTL method. A process flowsheet with basic control strategy is presented. It has been also made a preliminary economic analysis based on ultilities, raw materials and product costsIndústrias de biodiesel geram grandes quantidades de glicerina, o que torna necessária a proposição de uma destinação viável e lucrativa para esse subproduto. Para dar destino à abundância da glicerina produzida, muitos pesquisadores e indústrias vêm purificando-a ou convertendo-a em produtos químicos valiosos, tais como carbonato de glicerina. O carbonato de glicerina é uma substância de ampla aplicação industrial, na indústria cosmética e de fármacos, na produção de polímeros, na utilização como solvente, entre outros. Este trabalho visa o estudo da produção de carbonato de glicerina capaz de atingir altas conversões, próximas a 100%, sendo avaliada a viabilidade de implementação de reciclo e tanque flash. Para a realização do mesmo foi utilizado o software Aspen Plus®, com o intuito da aplicação em escala industrial da transesterificação catalítica da glicerina, sendo feita também a análise de custos de reagentes e insumos, como água de resfriamento e vapor. A partir da obtenção de uma via simples de produzir carbonato de glicerina, a modelagem proposta neste trabalho foi baseada no modelo termodinâmico NRTL e em uma cinética de reação que pode atingir 98% de pureza, praticamente isento dos possíveis reagentes tóxicos que participam da reação. Universidade Federal de Viçosa - UFV2017-03-19info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufv.br/jcec/article/view/244694160302201712110.18540/jcecvl3iss2pp121-129The Journal of Engineering and Exact Sciences; Vol. 3 No. 2 (2017); 121-129The Journal of Engineering and Exact Sciences; Vol. 3 Núm. 2 (2017); 121-129The Journal of Engineering and Exact Sciences; v. 3 n. 2 (2017); 121-1292527-1075reponame:The Journal of Engineering and Exact Sciencesinstname:Universidade Federal de Viçosa (UFV)instacron:UFVporhttps://periodicos.ufv.br/jcec/article/view/2446941603022017121/pdfCeliberto, Beatriz PeragineFico, Caio CanaleRusso, GuilhermeName, Luccas LossanoBarros, Victor Manuel BetancourtFerreira, Newton Libânioinfo:eu-repo/semantics/openAccess2020-07-14T22:33:02Zoai:ojs.periodicos.ufv.br:article/2308Revistahttp://www.seer.ufv.br/seer/rbeq2/index.php/req2/oai2527-10752527-1075opendoar:2020-07-14T22:33:02The Journal of Engineering and Exact Sciences - Universidade Federal de Viçosa (UFV)false |
dc.title.none.fl_str_mv |
DESIGN OF NA INDUSTRIAL PROCESS FO GLYCERIN CARBONATE PRODUCION PROJETO DE INSTALAÇÃO DE PRODUÇÃO INDUSTRIAL DE CARBONATO DE GLICERINA |
title |
DESIGN OF NA INDUSTRIAL PROCESS FO GLYCERIN CARBONATE PRODUCION |
spellingShingle |
DESIGN OF NA INDUSTRIAL PROCESS FO GLYCERIN CARBONATE PRODUCION Celiberto, Beatriz Peragine glycerine transesterification catalysis glycerine carbonate Glicerina Transesterificação Catálise Carbonato de glicerina |
title_short |
DESIGN OF NA INDUSTRIAL PROCESS FO GLYCERIN CARBONATE PRODUCION |
title_full |
DESIGN OF NA INDUSTRIAL PROCESS FO GLYCERIN CARBONATE PRODUCION |
title_fullStr |
DESIGN OF NA INDUSTRIAL PROCESS FO GLYCERIN CARBONATE PRODUCION |
title_full_unstemmed |
DESIGN OF NA INDUSTRIAL PROCESS FO GLYCERIN CARBONATE PRODUCION |
title_sort |
DESIGN OF NA INDUSTRIAL PROCESS FO GLYCERIN CARBONATE PRODUCION |
author |
Celiberto, Beatriz Peragine |
author_facet |
Celiberto, Beatriz Peragine Fico, Caio Canale Russo, Guilherme Name, Luccas Lossano Barros, Victor Manuel Betancourt Ferreira, Newton Libânio |
author_role |
author |
author2 |
Fico, Caio Canale Russo, Guilherme Name, Luccas Lossano Barros, Victor Manuel Betancourt Ferreira, Newton Libânio |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Celiberto, Beatriz Peragine Fico, Caio Canale Russo, Guilherme Name, Luccas Lossano Barros, Victor Manuel Betancourt Ferreira, Newton Libânio |
dc.subject.por.fl_str_mv |
glycerine transesterification catalysis glycerine carbonate Glicerina Transesterificação Catálise Carbonato de glicerina |
topic |
glycerine transesterification catalysis glycerine carbonate Glicerina Transesterificação Catálise Carbonato de glicerina |
description |
Biodiesel industries generates large amounts of glycerin what creates a demand for its suitable destination, with a possible transformation into a valuable product. One of these products is the glycerin carbonate. This substance has an increasing market as raw material for cosmetics, drugs, polymers and specilatiy solvents among others. This work shows an industrial process for the production of glycerin carbonate which achieves near complete conversion. The studies wre made with the use of the software Aspen Plus®. All physical equilibrium properties were calculated by the NRTL method. A process flowsheet with basic control strategy is presented. It has been also made a preliminary economic analysis based on ultilities, raw materials and product costs |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-03-19 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://periodicos.ufv.br/jcec/article/view/2446941603022017121 10.18540/jcecvl3iss2pp121-129 |
url |
https://periodicos.ufv.br/jcec/article/view/2446941603022017121 |
identifier_str_mv |
10.18540/jcecvl3iss2pp121-129 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
https://periodicos.ufv.br/jcec/article/view/2446941603022017121/pdf |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Federal de Viçosa - UFV |
publisher.none.fl_str_mv |
Universidade Federal de Viçosa - UFV |
dc.source.none.fl_str_mv |
The Journal of Engineering and Exact Sciences; Vol. 3 No. 2 (2017); 121-129 The Journal of Engineering and Exact Sciences; Vol. 3 Núm. 2 (2017); 121-129 The Journal of Engineering and Exact Sciences; v. 3 n. 2 (2017); 121-129 2527-1075 reponame:The Journal of Engineering and Exact Sciences instname:Universidade Federal de Viçosa (UFV) instacron:UFV |
instname_str |
Universidade Federal de Viçosa (UFV) |
instacron_str |
UFV |
institution |
UFV |
reponame_str |
The Journal of Engineering and Exact Sciences |
collection |
The Journal of Engineering and Exact Sciences |
repository.name.fl_str_mv |
The Journal of Engineering and Exact Sciences - Universidade Federal de Viçosa (UFV) |
repository.mail.fl_str_mv |
|
_version_ |
1808845243408187392 |