THIOPHENE CRACKING USING MAGNESIUM MODIFIED BETA ZEOLITE
Autor(a) principal: | |
---|---|
Data de Publicação: | 2018 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | The Journal of Engineering and Exact Sciences |
Texto Completo: | https://periodicos.ufv.br/jcec/article/view/2563 |
Resumo: | The development of additives for FCC catalysts aiming at a greater sulfur removal in the gasoline fraction has been a priority with tougher environmental legislation demands. In this context, this study has evaluated the effect of magnesium modified beta zeolite on n-hexane cracking, and the catalytic conversion of thiophene added as contaminant. Catalytic tests’ results, performed at low conversion at 400 ºC with a WHSV of 0.83 s-1 indicate that magnesium addition increased n-hexane cracking from 37.7 to 53.6% in mols, but favored the formation of alkylated sulfur compounds over H2S production. |
id |
UFV-6_e8bf8077371f63c561c04bcdf48bbf6b |
---|---|
oai_identifier_str |
oai:ojs.periodicos.ufv.br:article/2563 |
network_acronym_str |
UFV-6 |
network_name_str |
The Journal of Engineering and Exact Sciences |
repository_id_str |
|
spelling |
THIOPHENE CRACKING USING MAGNESIUM MODIFIED BETA ZEOLITECatalytic crackingBeta zeolitesThiopheneThe development of additives for FCC catalysts aiming at a greater sulfur removal in the gasoline fraction has been a priority with tougher environmental legislation demands. In this context, this study has evaluated the effect of magnesium modified beta zeolite on n-hexane cracking, and the catalytic conversion of thiophene added as contaminant. Catalytic tests’ results, performed at low conversion at 400 ºC with a WHSV of 0.83 s-1 indicate that magnesium addition increased n-hexane cracking from 37.7 to 53.6% in mols, but favored the formation of alkylated sulfur compounds over H2S production.Universidade Federal de Viçosa - UFV2018-10-23info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufv.br/jcec/article/view/256310.18540/jcecvl4iss4pp0378-0382The Journal of Engineering and Exact Sciences; Vol. 4 No. 4 (2018); 0378-0382The Journal of Engineering and Exact Sciences; Vol. 4 Núm. 4 (2018); 0378-0382The Journal of Engineering and Exact Sciences; v. 4 n. 4 (2018); 0378-03822527-1075reponame:The Journal of Engineering and Exact Sciencesinstname:Universidade Federal de Viçosa (UFV)instacron:UFVporhttps://periodicos.ufv.br/jcec/article/view/2563/1082Santos, Ronaldo CostaAlmeida, Daniel FreireFonseca, Fernanda Silva Costada Silva, Diego Santanade Oliveira, Angelica AmaralPontes, Danilo de AguiarPontes, Luiz Antônio Magalhãesinfo:eu-repo/semantics/openAccess2019-10-02T22:02:12Zoai:ojs.periodicos.ufv.br:article/2563Revistahttp://www.seer.ufv.br/seer/rbeq2/index.php/req2/oai2527-10752527-1075opendoar:2019-10-02T22:02:12The Journal of Engineering and Exact Sciences - Universidade Federal de Viçosa (UFV)false |
dc.title.none.fl_str_mv |
THIOPHENE CRACKING USING MAGNESIUM MODIFIED BETA ZEOLITE |
title |
THIOPHENE CRACKING USING MAGNESIUM MODIFIED BETA ZEOLITE |
spellingShingle |
THIOPHENE CRACKING USING MAGNESIUM MODIFIED BETA ZEOLITE Santos, Ronaldo Costa Catalytic cracking Beta zeolites Thiophene |
title_short |
THIOPHENE CRACKING USING MAGNESIUM MODIFIED BETA ZEOLITE |
title_full |
THIOPHENE CRACKING USING MAGNESIUM MODIFIED BETA ZEOLITE |
title_fullStr |
THIOPHENE CRACKING USING MAGNESIUM MODIFIED BETA ZEOLITE |
title_full_unstemmed |
THIOPHENE CRACKING USING MAGNESIUM MODIFIED BETA ZEOLITE |
title_sort |
THIOPHENE CRACKING USING MAGNESIUM MODIFIED BETA ZEOLITE |
author |
Santos, Ronaldo Costa |
author_facet |
Santos, Ronaldo Costa Almeida, Daniel Freire Fonseca, Fernanda Silva Costa da Silva, Diego Santana de Oliveira, Angelica Amaral Pontes, Danilo de Aguiar Pontes, Luiz Antônio Magalhães |
author_role |
author |
author2 |
Almeida, Daniel Freire Fonseca, Fernanda Silva Costa da Silva, Diego Santana de Oliveira, Angelica Amaral Pontes, Danilo de Aguiar Pontes, Luiz Antônio Magalhães |
author2_role |
author author author author author author |
dc.contributor.author.fl_str_mv |
Santos, Ronaldo Costa Almeida, Daniel Freire Fonseca, Fernanda Silva Costa da Silva, Diego Santana de Oliveira, Angelica Amaral Pontes, Danilo de Aguiar Pontes, Luiz Antônio Magalhães |
dc.subject.por.fl_str_mv |
Catalytic cracking Beta zeolites Thiophene |
topic |
Catalytic cracking Beta zeolites Thiophene |
description |
The development of additives for FCC catalysts aiming at a greater sulfur removal in the gasoline fraction has been a priority with tougher environmental legislation demands. In this context, this study has evaluated the effect of magnesium modified beta zeolite on n-hexane cracking, and the catalytic conversion of thiophene added as contaminant. Catalytic tests’ results, performed at low conversion at 400 ºC with a WHSV of 0.83 s-1 indicate that magnesium addition increased n-hexane cracking from 37.7 to 53.6% in mols, but favored the formation of alkylated sulfur compounds over H2S production. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-10-23 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://periodicos.ufv.br/jcec/article/view/2563 10.18540/jcecvl4iss4pp0378-0382 |
url |
https://periodicos.ufv.br/jcec/article/view/2563 |
identifier_str_mv |
10.18540/jcecvl4iss4pp0378-0382 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
https://periodicos.ufv.br/jcec/article/view/2563/1082 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Federal de Viçosa - UFV |
publisher.none.fl_str_mv |
Universidade Federal de Viçosa - UFV |
dc.source.none.fl_str_mv |
The Journal of Engineering and Exact Sciences; Vol. 4 No. 4 (2018); 0378-0382 The Journal of Engineering and Exact Sciences; Vol. 4 Núm. 4 (2018); 0378-0382 The Journal of Engineering and Exact Sciences; v. 4 n. 4 (2018); 0378-0382 2527-1075 reponame:The Journal of Engineering and Exact Sciences instname:Universidade Federal de Viçosa (UFV) instacron:UFV |
instname_str |
Universidade Federal de Viçosa (UFV) |
instacron_str |
UFV |
institution |
UFV |
reponame_str |
The Journal of Engineering and Exact Sciences |
collection |
The Journal of Engineering and Exact Sciences |
repository.name.fl_str_mv |
The Journal of Engineering and Exact Sciences - Universidade Federal de Viçosa (UFV) |
repository.mail.fl_str_mv |
|
_version_ |
1798313320075231232 |