Ozone treatment for pesticide removal from carrots: Optimization by response surface methodology

Detalhes bibliográficos
Autor(a) principal: Souza, Lauana Pellanda de
Data de Publicação: 2017
Outros Autores: Faroni, Lêda Rita D'Antonino, Heleno, Fernanda Fernandes, Pinto, Frederico Garcia, Queiroz, Maria Eliana Lopes Ribeiro de, Prates, Lucas Henrique Figueiredo
Tipo de documento: Artigo
Idioma: eng
Título da fonte: LOCUS Repositório Institucional da UFV
Texto Completo: https://doi.org/10.1016/j.foodchem.2017.09.134
http://www.locus.ufv.br/handle/123456789/18742
Resumo: The present study aimed to optimize ozone (O3) treatments, as gas and dissolved in water, to remove difenoconazole and linuron in carrots. We employed a central composite design to study three variables governing the efficacy of treatments: O3 concentration, temperature and treatment time. The temperature did not influence the efficacy of treatments. The removal percentage of pesticides increases with increases in ozone concentration and the time of treatment. O3 application promoted the removal of more than 80% of pesticides when the roots were exposed for approximately 120 min at 5 and 10 mg L−1, respectively, in treatments with O3 as gas and dissolved in water. After storage, pesticide removal was higher than 98% for difenoconazole and 95% for linuron. The degradation products from the pesticides resulting from treatment were monitored, but none were found. This is the first report demonstrating the removal of difenoconazole and linuron from carrots by ozone.
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spelling Souza, Lauana Pellanda deFaroni, Lêda Rita D'AntoninoHeleno, Fernanda FernandesPinto, Frederico GarciaQueiroz, Maria Eliana Lopes Ribeiro dePrates, Lucas Henrique Figueiredo2018-04-17T10:58:08Z2018-04-17T10:58:08Z2017-09-260308-8146https://doi.org/10.1016/j.foodchem.2017.09.134http://www.locus.ufv.br/handle/123456789/18742The present study aimed to optimize ozone (O3) treatments, as gas and dissolved in water, to remove difenoconazole and linuron in carrots. We employed a central composite design to study three variables governing the efficacy of treatments: O3 concentration, temperature and treatment time. The temperature did not influence the efficacy of treatments. The removal percentage of pesticides increases with increases in ozone concentration and the time of treatment. O3 application promoted the removal of more than 80% of pesticides when the roots were exposed for approximately 120 min at 5 and 10 mg L−1, respectively, in treatments with O3 as gas and dissolved in water. After storage, pesticide removal was higher than 98% for difenoconazole and 95% for linuron. The degradation products from the pesticides resulting from treatment were monitored, but none were found. This is the first report demonstrating the removal of difenoconazole and linuron from carrots by ozone.engFood Chemistryv. 243, p. 435–441, março 2018Elsevier B.V. or its licensors or contributorsinfo:eu-repo/semantics/openAccessDaucus carota L.DifenoconazoleLinuronStorageSolid-liquid extraction with low temperature partitionGas chromatographyOzone treatment for pesticide removal from carrots: Optimization by response surface methodologyinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfreponame:LOCUS Repositório Institucional da UFVinstname:Universidade Federal de Viçosa (UFV)instacron:UFVORIGINALartigo.pdfartigo.pdfartigoapplication/pdf490772https://locus.ufv.br//bitstream/123456789/18742/1/artigo.pdf8694b719cd9b8b96d9a2fec7d3c883bfMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://locus.ufv.br//bitstream/123456789/18742/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52THUMBNAILartigo.pdf.jpgartigo.pdf.jpgIM Thumbnailimage/jpeg5932https://locus.ufv.br//bitstream/123456789/18742/3/artigo.pdf.jpgc6cb4114d52cb2586fcdfe177458a416MD53123456789/187422018-04-17 23:00:39.056oai:locus.ufv.br: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Repositório InstitucionalPUBhttps://www.locus.ufv.br/oai/requestfabiojreis@ufv.bropendoar:21452018-04-18T02:00:39LOCUS Repositório Institucional da UFV - Universidade Federal de Viçosa (UFV)false
dc.title.en.fl_str_mv Ozone treatment for pesticide removal from carrots: Optimization by response surface methodology
title Ozone treatment for pesticide removal from carrots: Optimization by response surface methodology
spellingShingle Ozone treatment for pesticide removal from carrots: Optimization by response surface methodology
Souza, Lauana Pellanda de
Daucus carota L.
Difenoconazole
Linuron
Storage
Solid-liquid extraction with low temperature partition
Gas chromatography
title_short Ozone treatment for pesticide removal from carrots: Optimization by response surface methodology
title_full Ozone treatment for pesticide removal from carrots: Optimization by response surface methodology
title_fullStr Ozone treatment for pesticide removal from carrots: Optimization by response surface methodology
title_full_unstemmed Ozone treatment for pesticide removal from carrots: Optimization by response surface methodology
title_sort Ozone treatment for pesticide removal from carrots: Optimization by response surface methodology
author Souza, Lauana Pellanda de
author_facet Souza, Lauana Pellanda de
Faroni, Lêda Rita D'Antonino
Heleno, Fernanda Fernandes
Pinto, Frederico Garcia
Queiroz, Maria Eliana Lopes Ribeiro de
Prates, Lucas Henrique Figueiredo
author_role author
author2 Faroni, Lêda Rita D'Antonino
Heleno, Fernanda Fernandes
Pinto, Frederico Garcia
Queiroz, Maria Eliana Lopes Ribeiro de
Prates, Lucas Henrique Figueiredo
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Souza, Lauana Pellanda de
Faroni, Lêda Rita D'Antonino
Heleno, Fernanda Fernandes
Pinto, Frederico Garcia
Queiroz, Maria Eliana Lopes Ribeiro de
Prates, Lucas Henrique Figueiredo
dc.subject.pt-BR.fl_str_mv Daucus carota L.
Difenoconazole
Linuron
Storage
Solid-liquid extraction with low temperature partition
Gas chromatography
topic Daucus carota L.
Difenoconazole
Linuron
Storage
Solid-liquid extraction with low temperature partition
Gas chromatography
description The present study aimed to optimize ozone (O3) treatments, as gas and dissolved in water, to remove difenoconazole and linuron in carrots. We employed a central composite design to study three variables governing the efficacy of treatments: O3 concentration, temperature and treatment time. The temperature did not influence the efficacy of treatments. The removal percentage of pesticides increases with increases in ozone concentration and the time of treatment. O3 application promoted the removal of more than 80% of pesticides when the roots were exposed for approximately 120 min at 5 and 10 mg L−1, respectively, in treatments with O3 as gas and dissolved in water. After storage, pesticide removal was higher than 98% for difenoconazole and 95% for linuron. The degradation products from the pesticides resulting from treatment were monitored, but none were found. This is the first report demonstrating the removal of difenoconazole and linuron from carrots by ozone.
publishDate 2017
dc.date.issued.fl_str_mv 2017-09-26
dc.date.accessioned.fl_str_mv 2018-04-17T10:58:08Z
dc.date.available.fl_str_mv 2018-04-17T10:58:08Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
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dc.identifier.uri.fl_str_mv https://doi.org/10.1016/j.foodchem.2017.09.134
http://www.locus.ufv.br/handle/123456789/18742
dc.identifier.issn.none.fl_str_mv 0308-8146
identifier_str_mv 0308-8146
url https://doi.org/10.1016/j.foodchem.2017.09.134
http://www.locus.ufv.br/handle/123456789/18742
dc.language.iso.fl_str_mv eng
language eng
dc.relation.ispartofseries.pt-BR.fl_str_mv v. 243, p. 435–441, março 2018
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publisher.none.fl_str_mv Food Chemistry
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