Arsenic and trace metals in water and sediment of the velhas river, southeastern iron quadrangle region, Minas Gerais, Brazil
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | LOCUS Repositório Institucional da UFV |
Texto Completo: | http://dx.doi.org/10.21577/0100-4042.20170275 http://www.locus.ufv.br/handle/123456789/24746 |
Resumo: | This work was undertaken in the Velhas River Basin, in the municipalities of Rio Acima, Nova Lima, Raposos and Sabará, upstream of the city of Belo Horizonte in Minas Gerais State, Brazil. Velhas River provides the public water supply for much of this region. The gold and iron mining activities in the Velhas River yield considerable amounts of suspended solids as well as metals to the hydrological system of the region. Thus, the present study sought to evaluate the concentrations of arsenic and trace metals in the waters and their distribution and mobility in sediment by BCR sequential extraction. Arsenic concentrations in the water samples were between 78.1 and 85.3 μg L -1 , which exceeded 10 μg L -1 (maximum limit permitted by Brazilian environmental regulations for water destined to human consumption, CONAMA Resolution 357/2005). The sequential extraction of the sediment showed considerable amounts of As (20%), Cd (55%), Co (56%), Cr (16%), Cu (23%), Ni (29%), Pb (47%) and Zn (71%) associated with the geochemical fractions considered potentially available for the remobilization to the aquatic environment. The presence of the elements in these fractions indicated high ecotoxicological risk and potential harm to the health of the local population. |
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Silva, Danilo de C.Bellato, Carlos R.Marques Neto, José de O.Fontes, Maurício P. F.2019-04-24T13:35:46Z2019-04-24T13:35:46Z2018-091678-7064http://dx.doi.org/10.21577/0100-4042.20170275http://www.locus.ufv.br/handle/123456789/24746This work was undertaken in the Velhas River Basin, in the municipalities of Rio Acima, Nova Lima, Raposos and Sabará, upstream of the city of Belo Horizonte in Minas Gerais State, Brazil. Velhas River provides the public water supply for much of this region. The gold and iron mining activities in the Velhas River yield considerable amounts of suspended solids as well as metals to the hydrological system of the region. Thus, the present study sought to evaluate the concentrations of arsenic and trace metals in the waters and their distribution and mobility in sediment by BCR sequential extraction. Arsenic concentrations in the water samples were between 78.1 and 85.3 μg L -1 , which exceeded 10 μg L -1 (maximum limit permitted by Brazilian environmental regulations for water destined to human consumption, CONAMA Resolution 357/2005). The sequential extraction of the sediment showed considerable amounts of As (20%), Cd (55%), Co (56%), Cr (16%), Cu (23%), Ni (29%), Pb (47%) and Zn (71%) associated with the geochemical fractions considered potentially available for the remobilization to the aquatic environment. The presence of the elements in these fractions indicated high ecotoxicological risk and potential harm to the health of the local population.engQuímica Novav. 41, n. 9, p. 1011-1018, set. 2018BCR-sequential extractionFractionationArsenicTrace metalsBioavailabilityArsenic and trace metals in water and sediment of the velhas river, southeastern iron quadrangle region, Minas Gerais, Brazilinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfinfo:eu-repo/semantics/openAccessreponame:LOCUS Repositório Institucional da UFVinstname:Universidade Federal de Viçosa (UFV)instacron:UFVORIGINALartigo.pdfartigo.pdfartigoapplication/pdf1971681https://locus.ufv.br//bitstream/123456789/24746/1/artigo.pdf90045188d9ee38058a100ac042883077MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://locus.ufv.br//bitstream/123456789/24746/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52123456789/247462019-04-24 10:38:43.442oai:locus.ufv.br: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Repositório InstitucionalPUBhttps://www.locus.ufv.br/oai/requestfabiojreis@ufv.bropendoar:21452019-04-24T13:38:43LOCUS Repositório Institucional da UFV - Universidade Federal de Viçosa (UFV)false |
dc.title.en.fl_str_mv |
Arsenic and trace metals in water and sediment of the velhas river, southeastern iron quadrangle region, Minas Gerais, Brazil |
title |
Arsenic and trace metals in water and sediment of the velhas river, southeastern iron quadrangle region, Minas Gerais, Brazil |
spellingShingle |
Arsenic and trace metals in water and sediment of the velhas river, southeastern iron quadrangle region, Minas Gerais, Brazil Silva, Danilo de C. BCR-sequential extraction Fractionation Arsenic Trace metals Bioavailability |
title_short |
Arsenic and trace metals in water and sediment of the velhas river, southeastern iron quadrangle region, Minas Gerais, Brazil |
title_full |
Arsenic and trace metals in water and sediment of the velhas river, southeastern iron quadrangle region, Minas Gerais, Brazil |
title_fullStr |
Arsenic and trace metals in water and sediment of the velhas river, southeastern iron quadrangle region, Minas Gerais, Brazil |
title_full_unstemmed |
Arsenic and trace metals in water and sediment of the velhas river, southeastern iron quadrangle region, Minas Gerais, Brazil |
title_sort |
Arsenic and trace metals in water and sediment of the velhas river, southeastern iron quadrangle region, Minas Gerais, Brazil |
author |
Silva, Danilo de C. |
author_facet |
Silva, Danilo de C. Bellato, Carlos R. Marques Neto, José de O. Fontes, Maurício P. F. |
author_role |
author |
author2 |
Bellato, Carlos R. Marques Neto, José de O. Fontes, Maurício P. F. |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Silva, Danilo de C. Bellato, Carlos R. Marques Neto, José de O. Fontes, Maurício P. F. |
dc.subject.pt-BR.fl_str_mv |
BCR-sequential extraction Fractionation Arsenic Trace metals Bioavailability |
topic |
BCR-sequential extraction Fractionation Arsenic Trace metals Bioavailability |
description |
This work was undertaken in the Velhas River Basin, in the municipalities of Rio Acima, Nova Lima, Raposos and Sabará, upstream of the city of Belo Horizonte in Minas Gerais State, Brazil. Velhas River provides the public water supply for much of this region. The gold and iron mining activities in the Velhas River yield considerable amounts of suspended solids as well as metals to the hydrological system of the region. Thus, the present study sought to evaluate the concentrations of arsenic and trace metals in the waters and their distribution and mobility in sediment by BCR sequential extraction. Arsenic concentrations in the water samples were between 78.1 and 85.3 μg L -1 , which exceeded 10 μg L -1 (maximum limit permitted by Brazilian environmental regulations for water destined to human consumption, CONAMA Resolution 357/2005). The sequential extraction of the sediment showed considerable amounts of As (20%), Cd (55%), Co (56%), Cr (16%), Cu (23%), Ni (29%), Pb (47%) and Zn (71%) associated with the geochemical fractions considered potentially available for the remobilization to the aquatic environment. The presence of the elements in these fractions indicated high ecotoxicological risk and potential harm to the health of the local population. |
publishDate |
2018 |
dc.date.issued.fl_str_mv |
2018-09 |
dc.date.accessioned.fl_str_mv |
2019-04-24T13:35:46Z |
dc.date.available.fl_str_mv |
2019-04-24T13:35:46Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.21577/0100-4042.20170275 http://www.locus.ufv.br/handle/123456789/24746 |
dc.identifier.issn.none.fl_str_mv |
1678-7064 |
identifier_str_mv |
1678-7064 |
url |
http://dx.doi.org/10.21577/0100-4042.20170275 http://www.locus.ufv.br/handle/123456789/24746 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartofseries.pt-BR.fl_str_mv |
v. 41, n. 9, p. 1011-1018, set. 2018 |
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openAccess |
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Química Nova |
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