Synthesis of new porphyrin/fullerene supramolecular assemblies: a spectroscopic and electrochemical investigation of their coordination equilibrium in solution
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2010 |
| Outros Autores: | , , , , , , |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | LOCUS Repositório Institucional da UFV |
| Texto Completo: | https://doi.org/10.1016/j.tet.2010.10.066 http://www.locus.ufv.br/handle/123456789/21613 |
| Resumo: | Two new fullerene ligands have been designed to provide relatively simple frameworks to build supramolecular systems containing both fullerene and Zn-porphyrin moieties. The coordination of the fullerene ligands to the Zn-porphyrin was supported by UV–vis titration, nuclear magnetic resonance and electrochemical data. The resulting spectrophotometric data were processed both graphically and computationally to yield the stoichiometry, stability constant, and molar absorptivity of the species in equilibrium |
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Synthesis of new porphyrin/fullerene supramolecular assemblies: a spectroscopic and electrochemical investigation of their coordination equilibrium in solutionSupramolecular complexZn-porphyrinFullerene-C60SQUADTwo new fullerene ligands have been designed to provide relatively simple frameworks to build supramolecular systems containing both fullerene and Zn-porphyrin moieties. The coordination of the fullerene ligands to the Zn-porphyrin was supported by UV–vis titration, nuclear magnetic resonance and electrochemical data. The resulting spectrophotometric data were processed both graphically and computationally to yield the stoichiometry, stability constant, and molar absorptivity of the species in equilibriumTetrahedron2018-09-04T11:20:14Z2018-09-04T11:20:14Z2010-10-20info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlepdfapplication/pdf0040-4020https://doi.org/10.1016/j.tet.2010.10.066http://www.locus.ufv.br/handle/123456789/21613engVolume 67, Issue 1, Pages 228-235, January 2011Santos, Leandro J.Silva, Dayse Carvalho daRebouças, Júlio S.Alves, Marcos R. A.Idemori, Ynara M.Matencio, TulioFreitas, Rossimiriam P.Alves, Rosemeire B.info:eu-repo/semantics/openAccessreponame:LOCUS Repositório Institucional da UFVinstname:Universidade Federal de Viçosa (UFV)instacron:UFV2024-07-12T08:35:50Zoai:locus.ufv.br:123456789/21613Repositório InstitucionalPUBhttps://www.locus.ufv.br/oai/requestfabiojreis@ufv.bropendoar:21452024-07-12T08:35:50LOCUS Repositório Institucional da UFV - Universidade Federal de Viçosa (UFV)false |
| dc.title.none.fl_str_mv |
Synthesis of new porphyrin/fullerene supramolecular assemblies: a spectroscopic and electrochemical investigation of their coordination equilibrium in solution |
| title |
Synthesis of new porphyrin/fullerene supramolecular assemblies: a spectroscopic and electrochemical investigation of their coordination equilibrium in solution |
| spellingShingle |
Synthesis of new porphyrin/fullerene supramolecular assemblies: a spectroscopic and electrochemical investigation of their coordination equilibrium in solution Santos, Leandro J. Supramolecular complex Zn-porphyrin Fullerene-C60 SQUAD |
| title_short |
Synthesis of new porphyrin/fullerene supramolecular assemblies: a spectroscopic and electrochemical investigation of their coordination equilibrium in solution |
| title_full |
Synthesis of new porphyrin/fullerene supramolecular assemblies: a spectroscopic and electrochemical investigation of their coordination equilibrium in solution |
| title_fullStr |
Synthesis of new porphyrin/fullerene supramolecular assemblies: a spectroscopic and electrochemical investigation of their coordination equilibrium in solution |
| title_full_unstemmed |
Synthesis of new porphyrin/fullerene supramolecular assemblies: a spectroscopic and electrochemical investigation of their coordination equilibrium in solution |
| title_sort |
Synthesis of new porphyrin/fullerene supramolecular assemblies: a spectroscopic and electrochemical investigation of their coordination equilibrium in solution |
| author |
Santos, Leandro J. |
| author_facet |
Santos, Leandro J. Silva, Dayse Carvalho da Rebouças, Júlio S. Alves, Marcos R. A. Idemori, Ynara M. Matencio, Tulio Freitas, Rossimiriam P. Alves, Rosemeire B. |
| author_role |
author |
| author2 |
Silva, Dayse Carvalho da Rebouças, Júlio S. Alves, Marcos R. A. Idemori, Ynara M. Matencio, Tulio Freitas, Rossimiriam P. Alves, Rosemeire B. |
| author2_role |
author author author author author author author |
| dc.contributor.author.fl_str_mv |
Santos, Leandro J. Silva, Dayse Carvalho da Rebouças, Júlio S. Alves, Marcos R. A. Idemori, Ynara M. Matencio, Tulio Freitas, Rossimiriam P. Alves, Rosemeire B. |
| dc.subject.por.fl_str_mv |
Supramolecular complex Zn-porphyrin Fullerene-C60 SQUAD |
| topic |
Supramolecular complex Zn-porphyrin Fullerene-C60 SQUAD |
| description |
Two new fullerene ligands have been designed to provide relatively simple frameworks to build supramolecular systems containing both fullerene and Zn-porphyrin moieties. The coordination of the fullerene ligands to the Zn-porphyrin was supported by UV–vis titration, nuclear magnetic resonance and electrochemical data. The resulting spectrophotometric data were processed both graphically and computationally to yield the stoichiometry, stability constant, and molar absorptivity of the species in equilibrium |
| publishDate |
2010 |
| dc.date.none.fl_str_mv |
2010-10-20 2018-09-04T11:20:14Z 2018-09-04T11:20:14Z |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.uri.fl_str_mv |
0040-4020 https://doi.org/10.1016/j.tet.2010.10.066 http://www.locus.ufv.br/handle/123456789/21613 |
| identifier_str_mv |
0040-4020 |
| url |
https://doi.org/10.1016/j.tet.2010.10.066 http://www.locus.ufv.br/handle/123456789/21613 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
Volume 67, Issue 1, Pages 228-235, January 2011 |
| dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
pdf application/pdf |
| dc.publisher.none.fl_str_mv |
Tetrahedron |
| publisher.none.fl_str_mv |
Tetrahedron |
| dc.source.none.fl_str_mv |
reponame:LOCUS Repositório Institucional da UFV instname:Universidade Federal de Viçosa (UFV) instacron:UFV |
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Universidade Federal de Viçosa (UFV) |
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UFV |
| institution |
UFV |
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LOCUS Repositório Institucional da UFV |
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LOCUS Repositório Institucional da UFV |
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LOCUS Repositório Institucional da UFV - Universidade Federal de Viçosa (UFV) |
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fabiojreis@ufv.br |
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1822610732685983744 |
