Removal of chromium (VI) from aqueous solutions using the calcined magnetic composite hydrotalcite-iron oxide: kinetic and thermodynamic equilibrium studies
Autor(a) principal: | |
---|---|
Data de Publicação: | 2013 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | LOCUS Repositório Institucional da UFV |
Texto Completo: | http://dx.doi.org/10.1590/S0100-40422013000300012 http://www.locus.ufv.br/handle/123456789/17464 |
Resumo: | In this work, hydrotalcite, a layered double hydroxide, had its ion exchange properties combined with the magnetic properties of iron oxide to produce a magnetic adsorbent, HT-Fe 500. These magnetic composites can be used as adsorbents for anionic contaminants in water and subsequently removed from the medium by a simple magnetic process. Removal of chromium (VI) from aqueous solutions using HT-Fe 500 was achieved using batch adsorption experiments. The adsorption capacity, calculated with the Langmuir-Freundlich model showed to be dependent on temperature, reaching values of 25.93 and 48.31 mg g-1, respectively, for temperatures of 25 and 30 ºC |
id |
UFV_1ab45febd28a610e79704f3594b60517 |
---|---|
oai_identifier_str |
oai:locus.ufv.br:123456789/17464 |
network_acronym_str |
UFV |
network_name_str |
LOCUS Repositório Institucional da UFV |
repository_id_str |
2145 |
spelling |
Bellato, Carlos RobertoPessoa, Kenia DiasFontes, Maurício Paulo FerreiraToledo, Thiago Vinícius2018-02-07T16:17:41Z2018-02-07T16:17:41Z2013-01-231678-7064http://dx.doi.org/10.1590/S0100-40422013000300012http://www.locus.ufv.br/handle/123456789/17464In this work, hydrotalcite, a layered double hydroxide, had its ion exchange properties combined with the magnetic properties of iron oxide to produce a magnetic adsorbent, HT-Fe 500. These magnetic composites can be used as adsorbents for anionic contaminants in water and subsequently removed from the medium by a simple magnetic process. Removal of chromium (VI) from aqueous solutions using HT-Fe 500 was achieved using batch adsorption experiments. The adsorption capacity, calculated with the Langmuir-Freundlich model showed to be dependent on temperature, reaching values of 25.93 and 48.31 mg g-1, respectively, for temperatures of 25 and 30 ºCengQuímica Novav. 36, n. 3, p. 419-425, 2013Chromium (VI)AdsorptionHydrotalcite-iron oxide compositeRemoval of chromium (VI) from aqueous solutions using the calcined magnetic composite hydrotalcite-iron oxide: kinetic and thermodynamic equilibrium studiesinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfinfo:eu-repo/semantics/openAccessreponame:LOCUS Repositório Institucional da UFVinstname:Universidade Federal de Viçosa (UFV)instacron:UFVORIGINALartigo.pdfartigo.pdfTexto completoapplication/pdf757042https://locus.ufv.br//bitstream/123456789/17464/1/artigo.pdfc9e465a4376a1a5366653b7a36248984MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://locus.ufv.br//bitstream/123456789/17464/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52THUMBNAILartigo.pdf.jpgartigo.pdf.jpgIM Thumbnailimage/jpeg6501https://locus.ufv.br//bitstream/123456789/17464/3/artigo.pdf.jpg34fbb4f2e499fd6b25ca4e2d4b611763MD53123456789/174642018-02-07 22:00:59.652oai:locus.ufv.br:123456789/17464Tk9URTogUExBQ0UgWU9VUiBPV04gTElDRU5TRSBIRVJFClRoaXMgc2FtcGxlIGxpY2Vuc2UgaXMgcHJvdmlkZWQgZm9yIGluZm9ybWF0aW9uYWwgcHVycG9zZXMgb25seS4KCk5PTi1FWENMVVNJVkUgRElTVFJJQlVUSU9OIExJQ0VOU0UKCkJ5IHNpZ25pbmcgYW5kIHN1Ym1pdHRpbmcgdGhpcyBsaWNlbnNlLCB5b3UgKHRoZSBhdXRob3Iocykgb3IgY29weXJpZ2h0Cm93bmVyKSBncmFudHMgdG8gRFNwYWNlIFVuaXZlcnNpdHkgKERTVSkgdGhlIG5vbi1leGNsdXNpdmUgcmlnaHQgdG8gcmVwcm9kdWNlLAp0cmFuc2xhdGUgKGFzIGRlZmluZWQgYmVsb3cpLCBhbmQvb3IgZGlzdHJpYnV0ZSB5b3VyIHN1Ym1pc3Npb24gKGluY2x1ZGluZwp0aGUgYWJzdHJhY3QpIHdvcmxkd2lkZSBpbiBwcmludCBhbmQgZWxlY3Ryb25pYyBmb3JtYXQgYW5kIGluIGFueSBtZWRpdW0sCmluY2x1ZGluZyBidXQgbm90IGxpbWl0ZWQgdG8gYXVkaW8gb3IgdmlkZW8uCgpZb3UgYWdyZWUgdGhhdCBEU1UgbWF5LCB3aXRob3V0IGNoYW5naW5nIHRoZSBjb250ZW50LCB0cmFuc2xhdGUgdGhlCnN1Ym1pc3Npb24gdG8gYW55IG1lZGl1bSBvciBmb3JtYXQgZm9yIHRoZSBwdXJwb3NlIG9mIHByZXNlcnZhdGlvbi4KCllvdSBhbHNvIGFncmVlIHRoYXQgRFNVIG1heSBrZWVwIG1vcmUgdGhhbiBvbmUgY29weSBvZiB0aGlzIHN1Ym1pc3Npb24gZm9yCnB1cnBvc2VzIG9mIHNlY3VyaXR5LCBiYWNrLXVwIGFuZCBwcmVzZXJ2YXRpb24uCgpZb3UgcmVwcmVzZW50IHRoYXQgdGhlIHN1Ym1pc3Npb24gaXMgeW91ciBvcmlnaW5hbCB3b3JrLCBhbmQgdGhhdCB5b3UgaGF2ZQp0aGUgcmlnaHQgdG8gZ3JhbnQgdGhlIHJpZ2h0cyBjb250YWluZWQgaW4gdGhpcyBsaWNlbnNlLiBZb3UgYWxzbyByZXByZXNlbnQKdGhhdCB5b3VyIHN1Ym1pc3Npb24gZG9lcyBub3QsIHRvIHRoZSBiZXN0IG9mIHlvdXIga25vd2xlZGdlLCBpbmZyaW5nZSB1cG9uCmFueW9uZSdzIGNvcHlyaWdodC4KCklmIHRoZSBzdWJtaXNzaW9uIGNvbnRhaW5zIG1hdGVyaWFsIGZvciB3aGljaCB5b3UgZG8gbm90IGhvbGQgY29weXJpZ2h0LAp5b3UgcmVwcmVzZW50IHRoYXQgeW91IGhhdmUgb2J0YWluZWQgdGhlIHVucmVzdHJpY3RlZCBwZXJtaXNzaW9uIG9mIHRoZQpjb3B5cmlnaHQgb3duZXIgdG8gZ3JhbnQgRFNVIHRoZSByaWdodHMgcmVxdWlyZWQgYnkgdGhpcyBsaWNlbnNlLCBhbmQgdGhhdApzdWNoIHRoaXJkLXBhcnR5IG93bmVkIG1hdGVyaWFsIGlzIGNsZWFybHkgaWRlbnRpZmllZCBhbmQgYWNrbm93bGVkZ2VkCndpdGhpbiB0aGUgdGV4dCBvciBjb250ZW50IG9mIHRoZSBzdWJtaXNzaW9uLgoKSUYgVEhFIFNVQk1JU1NJT04gSVMgQkFTRUQgVVBPTiBXT1JLIFRIQVQgSEFTIEJFRU4gU1BPTlNPUkVEIE9SIFNVUFBPUlRFRApCWSBBTiBBR0VOQ1kgT1IgT1JHQU5JWkFUSU9OIE9USEVSIFRIQU4gRFNVLCBZT1UgUkVQUkVTRU5UIFRIQVQgWU9VIEhBVkUKRlVMRklMTEVEIEFOWSBSSUdIVCBPRiBSRVZJRVcgT1IgT1RIRVIgT0JMSUdBVElPTlMgUkVRVUlSRUQgQlkgU1VDSApDT05UUkFDVCBPUiBBR1JFRU1FTlQuCgpEU1Ugd2lsbCBjbGVhcmx5IGlkZW50aWZ5IHlvdXIgbmFtZShzKSBhcyB0aGUgYXV0aG9yKHMpIG9yIG93bmVyKHMpIG9mIHRoZQpzdWJtaXNzaW9uLCBhbmQgd2lsbCBub3QgbWFrZSBhbnkgYWx0ZXJhdGlvbiwgb3RoZXIgdGhhbiBhcyBhbGxvd2VkIGJ5IHRoaXMKbGljZW5zZSwgdG8geW91ciBzdWJtaXNzaW9uLgo=Repositório InstitucionalPUBhttps://www.locus.ufv.br/oai/requestfabiojreis@ufv.bropendoar:21452018-02-08T01:00:59LOCUS Repositório Institucional da UFV - Universidade Federal de Viçosa (UFV)false |
dc.title.en.fl_str_mv |
Removal of chromium (VI) from aqueous solutions using the calcined magnetic composite hydrotalcite-iron oxide: kinetic and thermodynamic equilibrium studies |
title |
Removal of chromium (VI) from aqueous solutions using the calcined magnetic composite hydrotalcite-iron oxide: kinetic and thermodynamic equilibrium studies |
spellingShingle |
Removal of chromium (VI) from aqueous solutions using the calcined magnetic composite hydrotalcite-iron oxide: kinetic and thermodynamic equilibrium studies Bellato, Carlos Roberto Chromium (VI) Adsorption Hydrotalcite-iron oxide composite |
title_short |
Removal of chromium (VI) from aqueous solutions using the calcined magnetic composite hydrotalcite-iron oxide: kinetic and thermodynamic equilibrium studies |
title_full |
Removal of chromium (VI) from aqueous solutions using the calcined magnetic composite hydrotalcite-iron oxide: kinetic and thermodynamic equilibrium studies |
title_fullStr |
Removal of chromium (VI) from aqueous solutions using the calcined magnetic composite hydrotalcite-iron oxide: kinetic and thermodynamic equilibrium studies |
title_full_unstemmed |
Removal of chromium (VI) from aqueous solutions using the calcined magnetic composite hydrotalcite-iron oxide: kinetic and thermodynamic equilibrium studies |
title_sort |
Removal of chromium (VI) from aqueous solutions using the calcined magnetic composite hydrotalcite-iron oxide: kinetic and thermodynamic equilibrium studies |
author |
Bellato, Carlos Roberto |
author_facet |
Bellato, Carlos Roberto Pessoa, Kenia Dias Fontes, Maurício Paulo Ferreira Toledo, Thiago Vinícius |
author_role |
author |
author2 |
Pessoa, Kenia Dias Fontes, Maurício Paulo Ferreira Toledo, Thiago Vinícius |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Bellato, Carlos Roberto Pessoa, Kenia Dias Fontes, Maurício Paulo Ferreira Toledo, Thiago Vinícius |
dc.subject.pt-BR.fl_str_mv |
Chromium (VI) Adsorption Hydrotalcite-iron oxide composite |
topic |
Chromium (VI) Adsorption Hydrotalcite-iron oxide composite |
description |
In this work, hydrotalcite, a layered double hydroxide, had its ion exchange properties combined with the magnetic properties of iron oxide to produce a magnetic adsorbent, HT-Fe 500. These magnetic composites can be used as adsorbents for anionic contaminants in water and subsequently removed from the medium by a simple magnetic process. Removal of chromium (VI) from aqueous solutions using HT-Fe 500 was achieved using batch adsorption experiments. The adsorption capacity, calculated with the Langmuir-Freundlich model showed to be dependent on temperature, reaching values of 25.93 and 48.31 mg g-1, respectively, for temperatures of 25 and 30 ºC |
publishDate |
2013 |
dc.date.issued.fl_str_mv |
2013-01-23 |
dc.date.accessioned.fl_str_mv |
2018-02-07T16:17:41Z |
dc.date.available.fl_str_mv |
2018-02-07T16:17:41Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1590/S0100-40422013000300012 http://www.locus.ufv.br/handle/123456789/17464 |
dc.identifier.issn.none.fl_str_mv |
1678-7064 |
identifier_str_mv |
1678-7064 |
url |
http://dx.doi.org/10.1590/S0100-40422013000300012 http://www.locus.ufv.br/handle/123456789/17464 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartofseries.pt-BR.fl_str_mv |
v. 36, n. 3, p. 419-425, 2013 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Química Nova |
publisher.none.fl_str_mv |
Química Nova |
dc.source.none.fl_str_mv |
reponame:LOCUS Repositório Institucional da UFV instname:Universidade Federal de Viçosa (UFV) instacron:UFV |
instname_str |
Universidade Federal de Viçosa (UFV) |
instacron_str |
UFV |
institution |
UFV |
reponame_str |
LOCUS Repositório Institucional da UFV |
collection |
LOCUS Repositório Institucional da UFV |
bitstream.url.fl_str_mv |
https://locus.ufv.br//bitstream/123456789/17464/1/artigo.pdf https://locus.ufv.br//bitstream/123456789/17464/2/license.txt https://locus.ufv.br//bitstream/123456789/17464/3/artigo.pdf.jpg |
bitstream.checksum.fl_str_mv |
c9e465a4376a1a5366653b7a36248984 8a4605be74aa9ea9d79846c1fba20a33 34fbb4f2e499fd6b25ca4e2d4b611763 |
bitstream.checksumAlgorithm.fl_str_mv |
MD5 MD5 MD5 |
repository.name.fl_str_mv |
LOCUS Repositório Institucional da UFV - Universidade Federal de Viçosa (UFV) |
repository.mail.fl_str_mv |
fabiojreis@ufv.br |
_version_ |
1801213106199724032 |