Properties of black soil humic acids from high altitude rocky complexes in Brazil
Autor(a) principal: | |
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Data de Publicação: | 2005 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | LOCUS Repositório Institucional da UFV |
Texto Completo: | https://doi.org/10.1016/j.geoderma.2004.11.020 http://www.locus.ufv.br/handle/123456789/22429 |
Resumo: | Forty two samples of black soils were collected from superficial horizons of the High Altitude Rocky Complex (HARC) that is situated on top of the most prominent mountain ranges of eastern Brazil. Our objective was to characterize the humic acids extracted from these pedoenvironments and evaluate the effect of natural paleo-fires on thermogravimetric properties, elemental composition, visible and infrared absorption of humic acids (HA). The high thermostability, low H:C ratio, and abundance in carboxylic groups, suggest that the HARC black soil HA present larger biostability and reactivity. The molecular characteristics indicated that HARC black soil HAs have a great contribution of transformed charred vegetable residues on its origin. This persistence and reactivity of black soil HA explain the capacity of these soils to maintain their cation exchange capacity, since the soil clay fraction is composed predominantly by low activity minerals. |
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Benites, Vinicius de MeloMendonça, Eduardo de SáSchaefer, Carlos Ernesto G. R.Novotny, Etelvino HenriqueReis, Efraim LázaroKer, João Carlos2018-10-31T10:54:15Z2018-10-31T10:54:15Z2005-01-0400167061https://doi.org/10.1016/j.geoderma.2004.11.020http://www.locus.ufv.br/handle/123456789/22429Forty two samples of black soils were collected from superficial horizons of the High Altitude Rocky Complex (HARC) that is situated on top of the most prominent mountain ranges of eastern Brazil. Our objective was to characterize the humic acids extracted from these pedoenvironments and evaluate the effect of natural paleo-fires on thermogravimetric properties, elemental composition, visible and infrared absorption of humic acids (HA). The high thermostability, low H:C ratio, and abundance in carboxylic groups, suggest that the HARC black soil HA present larger biostability and reactivity. The molecular characteristics indicated that HARC black soil HAs have a great contribution of transformed charred vegetable residues on its origin. This persistence and reactivity of black soil HA explain the capacity of these soils to maintain their cation exchange capacity, since the soil clay fraction is composed predominantly by low activity minerals.engGeodermav. 127, n. 1– 2, p. 104- 113, jul. 2005Elsevier B.V.info:eu-repo/semantics/openAccessHumic acidsTropical soilsCharcoalBlack carbonFTIRProperties of black soil humic acids from high altitude rocky complexes in Brazilinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfreponame:LOCUS Repositório Institucional da UFVinstname:Universidade Federal de Viçosa (UFV)instacron:UFVORIGINALartigo.pdfartigo.pdftexto completoapplication/pdf202736https://locus.ufv.br//bitstream/123456789/22429/1/artigo.pdfbae7f99001212dec0ab820585abcfda0MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://locus.ufv.br//bitstream/123456789/22429/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52123456789/224292018-10-31 07:56:04.616oai:locus.ufv.br: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Repositório InstitucionalPUBhttps://www.locus.ufv.br/oai/requestfabiojreis@ufv.bropendoar:21452018-10-31T10:56:04LOCUS Repositório Institucional da UFV - Universidade Federal de Viçosa (UFV)false |
dc.title.en.fl_str_mv |
Properties of black soil humic acids from high altitude rocky complexes in Brazil |
title |
Properties of black soil humic acids from high altitude rocky complexes in Brazil |
spellingShingle |
Properties of black soil humic acids from high altitude rocky complexes in Brazil Benites, Vinicius de Melo Humic acids Tropical soils Charcoal Black carbon FTIR |
title_short |
Properties of black soil humic acids from high altitude rocky complexes in Brazil |
title_full |
Properties of black soil humic acids from high altitude rocky complexes in Brazil |
title_fullStr |
Properties of black soil humic acids from high altitude rocky complexes in Brazil |
title_full_unstemmed |
Properties of black soil humic acids from high altitude rocky complexes in Brazil |
title_sort |
Properties of black soil humic acids from high altitude rocky complexes in Brazil |
author |
Benites, Vinicius de Melo |
author_facet |
Benites, Vinicius de Melo Mendonça, Eduardo de Sá Schaefer, Carlos Ernesto G. R. Novotny, Etelvino Henrique Reis, Efraim Lázaro Ker, João Carlos |
author_role |
author |
author2 |
Mendonça, Eduardo de Sá Schaefer, Carlos Ernesto G. R. Novotny, Etelvino Henrique Reis, Efraim Lázaro Ker, João Carlos |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Benites, Vinicius de Melo Mendonça, Eduardo de Sá Schaefer, Carlos Ernesto G. R. Novotny, Etelvino Henrique Reis, Efraim Lázaro Ker, João Carlos |
dc.subject.pt-BR.fl_str_mv |
Humic acids Tropical soils Charcoal Black carbon FTIR |
topic |
Humic acids Tropical soils Charcoal Black carbon FTIR |
description |
Forty two samples of black soils were collected from superficial horizons of the High Altitude Rocky Complex (HARC) that is situated on top of the most prominent mountain ranges of eastern Brazil. Our objective was to characterize the humic acids extracted from these pedoenvironments and evaluate the effect of natural paleo-fires on thermogravimetric properties, elemental composition, visible and infrared absorption of humic acids (HA). The high thermostability, low H:C ratio, and abundance in carboxylic groups, suggest that the HARC black soil HA present larger biostability and reactivity. The molecular characteristics indicated that HARC black soil HAs have a great contribution of transformed charred vegetable residues on its origin. This persistence and reactivity of black soil HA explain the capacity of these soils to maintain their cation exchange capacity, since the soil clay fraction is composed predominantly by low activity minerals. |
publishDate |
2005 |
dc.date.issued.fl_str_mv |
2005-01-04 |
dc.date.accessioned.fl_str_mv |
2018-10-31T10:54:15Z |
dc.date.available.fl_str_mv |
2018-10-31T10:54:15Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://doi.org/10.1016/j.geoderma.2004.11.020 http://www.locus.ufv.br/handle/123456789/22429 |
dc.identifier.issn.none.fl_str_mv |
00167061 |
identifier_str_mv |
00167061 |
url |
https://doi.org/10.1016/j.geoderma.2004.11.020 http://www.locus.ufv.br/handle/123456789/22429 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartofseries.pt-BR.fl_str_mv |
v. 127, n. 1– 2, p. 104- 113, jul. 2005 |
dc.rights.driver.fl_str_mv |
Elsevier B.V. info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
Elsevier B.V. |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Geoderma |
publisher.none.fl_str_mv |
Geoderma |
dc.source.none.fl_str_mv |
reponame:LOCUS Repositório Institucional da UFV instname:Universidade Federal de Viçosa (UFV) instacron:UFV |
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Universidade Federal de Viçosa (UFV) |
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UFV |
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UFV |
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LOCUS Repositório Institucional da UFV |
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LOCUS Repositório Institucional da UFV |
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LOCUS Repositório Institucional da UFV - Universidade Federal de Viçosa (UFV) |
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fabiojreis@ufv.br |
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