Sistema aquoso bifásico: uma alternativa eficiente para extração de íons
Autor(a) principal: | |
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Data de Publicação: | 2006 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | LOCUS Repositório Institucional da UFV |
Texto Completo: | http://dx.doi.org/10.1590/S0100-40422006000600031 http://www.locus.ufv.br/handle/123456789/17035 |
Resumo: | Solvent extraction has been successfully applied to metal ion preconcentration and often meant the use of toxic organic diluents. However, regulatory pressure is increasingly focusing on the use and disposal of organic solvents, and thus the development of nonhazardous alternatives is important. In this review, we examine the application of aqueous biphasic systems (ABS) to extraction of ions, analyzing their potential and limitations and suggest that ABSs could be an efficient substitute for oil/water biphasic systems. ABSs are formed by mixing certain inorganic salts and water-soluble polymers, or by mixing two water-soluble polymers. |
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Silva, Maria do Carmo Hespanhol daSilva, Luis Henrique Mendes daPaggioli, Fernanda JürgensenCoimbra, Jane Sélia ReisMinim, Luis Antonio2018-01-31T10:37:51Z2018-01-31T10:37:51Z2006-07-0616787064http://dx.doi.org/10.1590/S0100-40422006000600031http://www.locus.ufv.br/handle/123456789/17035Solvent extraction has been successfully applied to metal ion preconcentration and often meant the use of toxic organic diluents. However, regulatory pressure is increasingly focusing on the use and disposal of organic solvents, and thus the development of nonhazardous alternatives is important. In this review, we examine the application of aqueous biphasic systems (ABS) to extraction of ions, analyzing their potential and limitations and suggest that ABSs could be an efficient substitute for oil/water biphasic systems. ABSs are formed by mixing certain inorganic salts and water-soluble polymers, or by mixing two water-soluble polymers.porQuímica NovaVol. 29, N. 6, p. 1332-1339, Nov./Dec. 2006Aqueous biphasic systemMetal ionsGreen chemistrySistema aquoso bifásico: uma alternativa eficiente para extração de íonsinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfinfo:eu-repo/semantics/openAccessreponame:LOCUS Repositório Institucional da UFVinstname:Universidade Federal de Viçosa (UFV)instacron:UFVORIGINALartigo.pdfartigo.pdfTexto completoapplication/pdf202514https://locus.ufv.br//bitstream/123456789/17035/1/artigo.pdf47f94db40edec46bda66cbc7c414ddb3MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://locus.ufv.br//bitstream/123456789/17035/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52THUMBNAILartigo.pdf.jpgartigo.pdf.jpgIM Thumbnailimage/jpeg6105https://locus.ufv.br//bitstream/123456789/17035/3/artigo.pdf.jpg7fc07dd603b040b215ad8db516a72fd6MD53123456789/170352018-01-31 22:00:43.605oai:locus.ufv.br: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Repositório InstitucionalPUBhttps://www.locus.ufv.br/oai/requestfabiojreis@ufv.bropendoar:21452018-02-01T01:00:43LOCUS Repositório Institucional da UFV - Universidade Federal de Viçosa (UFV)false |
dc.title.pt-BR.fl_str_mv |
Sistema aquoso bifásico: uma alternativa eficiente para extração de íons |
title |
Sistema aquoso bifásico: uma alternativa eficiente para extração de íons |
spellingShingle |
Sistema aquoso bifásico: uma alternativa eficiente para extração de íons Silva, Maria do Carmo Hespanhol da Aqueous biphasic system Metal ions Green chemistry |
title_short |
Sistema aquoso bifásico: uma alternativa eficiente para extração de íons |
title_full |
Sistema aquoso bifásico: uma alternativa eficiente para extração de íons |
title_fullStr |
Sistema aquoso bifásico: uma alternativa eficiente para extração de íons |
title_full_unstemmed |
Sistema aquoso bifásico: uma alternativa eficiente para extração de íons |
title_sort |
Sistema aquoso bifásico: uma alternativa eficiente para extração de íons |
author |
Silva, Maria do Carmo Hespanhol da |
author_facet |
Silva, Maria do Carmo Hespanhol da Silva, Luis Henrique Mendes da Paggioli, Fernanda Jürgensen Coimbra, Jane Sélia Reis Minim, Luis Antonio |
author_role |
author |
author2 |
Silva, Luis Henrique Mendes da Paggioli, Fernanda Jürgensen Coimbra, Jane Sélia Reis Minim, Luis Antonio |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Silva, Maria do Carmo Hespanhol da Silva, Luis Henrique Mendes da Paggioli, Fernanda Jürgensen Coimbra, Jane Sélia Reis Minim, Luis Antonio |
dc.subject.pt-BR.fl_str_mv |
Aqueous biphasic system Metal ions Green chemistry |
topic |
Aqueous biphasic system Metal ions Green chemistry |
description |
Solvent extraction has been successfully applied to metal ion preconcentration and often meant the use of toxic organic diluents. However, regulatory pressure is increasingly focusing on the use and disposal of organic solvents, and thus the development of nonhazardous alternatives is important. In this review, we examine the application of aqueous biphasic systems (ABS) to extraction of ions, analyzing their potential and limitations and suggest that ABSs could be an efficient substitute for oil/water biphasic systems. ABSs are formed by mixing certain inorganic salts and water-soluble polymers, or by mixing two water-soluble polymers. |
publishDate |
2006 |
dc.date.issued.fl_str_mv |
2006-07-06 |
dc.date.accessioned.fl_str_mv |
2018-01-31T10:37:51Z |
dc.date.available.fl_str_mv |
2018-01-31T10:37:51Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1590/S0100-40422006000600031 http://www.locus.ufv.br/handle/123456789/17035 |
dc.identifier.issn.none.fl_str_mv |
16787064 |
identifier_str_mv |
16787064 |
url |
http://dx.doi.org/10.1590/S0100-40422006000600031 http://www.locus.ufv.br/handle/123456789/17035 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.ispartofseries.pt-BR.fl_str_mv |
Vol. 29, N. 6, p. 1332-1339, Nov./Dec. 2006 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
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application/pdf |
dc.publisher.none.fl_str_mv |
Química Nova |
publisher.none.fl_str_mv |
Química Nova |
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LOCUS Repositório Institucional da UFV |
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LOCUS Repositório Institucional da UFV |
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