Selective hydrogenation of 1,3-butadiene by transition metal compounds immobilized in 1-butyl-3-methyl imidazolium room temperature ionic liquids

Detalhes bibliográficos
Autor(a) principal: Consorti, Crestina S.
Data de Publicação: 2003
Outros Autores: Umpierre, Alexandre P., Souza, Roberto F. de, Dupont, Jairton, Suarez, Paulo A. Z.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UnB
Texto Completo: http://repositorio.unb.br/handle/10482/26062
https://dx.doi.org/10.1590/S0103-50532003000300010
Resumo: The compounds [Co(acac)2], [Co(acac)3], [Fe(acac)3] and [Ni(acac)2] (acac = acetylacetonate) dissolved in 1-butyl-3-methyl imidazolium tetrafluoroborate (1), trifluoromethanesulphonate (2) or hexafluorophosphate (3) catalyze the reduction of 1,3-butadiene into butenes in a typical two-phase catalytic reaction. The 1,3-butadiene conversion, the selectivity and turnover frequencies (TOF) are strongly dependent on the nature of the transition metal catalyst precursor and the ionic liquid. For [Co(acac)2] dissolved in 1, kinetic studies strongly suggest that the reaction takes place in the ionic solution bulk, having an apparent activation energy for the overall process of 33.8 kJ mol-1. The recovered ionic catalyst solution can be reused several times without any significant changes on activity and selectivity.
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spelling Consorti, Crestina S.Umpierre, Alexandre P.Souza, Roberto F. deDupont, JairtonSuarez, Paulo A. Z.2017-12-07T04:38:30Z2017-12-07T04:38:30Z2003J. Braz. Chem. Soc.,v.14,n.3,p.401-405,2003http://repositorio.unb.br/handle/10482/26062https://dx.doi.org/10.1590/S0103-50532003000300010The compounds [Co(acac)2], [Co(acac)3], [Fe(acac)3] and [Ni(acac)2] (acac = acetylacetonate) dissolved in 1-butyl-3-methyl imidazolium tetrafluoroborate (1), trifluoromethanesulphonate (2) or hexafluorophosphate (3) catalyze the reduction of 1,3-butadiene into butenes in a typical two-phase catalytic reaction. The 1,3-butadiene conversion, the selectivity and turnover frequencies (TOF) are strongly dependent on the nature of the transition metal catalyst precursor and the ionic liquid. For [Co(acac)2] dissolved in 1, kinetic studies strongly suggest that the reaction takes place in the ionic solution bulk, having an apparent activation energy for the overall process of 33.8 kJ mol-1. The recovered ionic catalyst solution can be reused several times without any significant changes on activity and selectivity.Os complexos [Co(acac)2], [Co(acac)3], [Fe(acac)3] e [Ni(acac)2] (acac = acetilacetonato) dissolvidos em tetrafluoroborato de 1-butil-3-metilimidazônio (1), trifluorometanosulfonato de 1-butil-3-metilimidazólio (2) ou hexafluorofosfato de 1-butil-3-metilimidazólio (3), catalisam a hidrogenação de 1,3-butadieno em butenos em sistema catalítico tipicamente bifásico. A conversão do 1,3-butadieno, a seletividade e a freqüência de rotação (TOF) são fortemente dependentes do metal de transição e do líquido iônico. Para [Co(acac)2] dissolvido em 1, estudos cinéticos sugerem que a reação ocorre no meio líquido iônico, com uma energia aparente de ativação de of 33.8 kJ mol-1. A solução iônica do catalisador pode ser recuperada e reutilizada várias vezes sem mudanças perceptíveis na atividade e seletividade da reação.Em processamentoSociedade Brasileira de QuímicaSelective hydrogenation of 1,3-butadiene by transition metal compounds immobilized in 1-butyl-3-methyl imidazolium room temperature ionic liquidsinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlebiphasic hydrogenationionic liquidsdienescobalt catalystsinfo:eu-repo/semantics/openAccessengreponame:Repositório Institucional da UnBinstname:Universidade de Brasília (UnB)instacron:UNBORIGINAL15900.pdfapplication/pdf118373http://repositorio2.unb.br/jspui/bitstream/10482/26062/1/15900.pdf159867307554feeb92642cd65278cc50MD51open access10482/260622023-10-09 17:58:57.784open accessoai:repositorio2.unb.br:10482/26062Biblioteca Digital de Teses e DissertaçõesPUBhttps://repositorio.unb.br/oai/requestopendoar:2023-10-09T20:58:57Repositório Institucional da UnB - Universidade de Brasília (UnB)false
dc.title.pt_BR.fl_str_mv Selective hydrogenation of 1,3-butadiene by transition metal compounds immobilized in 1-butyl-3-methyl imidazolium room temperature ionic liquids
title Selective hydrogenation of 1,3-butadiene by transition metal compounds immobilized in 1-butyl-3-methyl imidazolium room temperature ionic liquids
spellingShingle Selective hydrogenation of 1,3-butadiene by transition metal compounds immobilized in 1-butyl-3-methyl imidazolium room temperature ionic liquids
Consorti, Crestina S.
biphasic hydrogenation
ionic liquids
dienes
cobalt catalysts
title_short Selective hydrogenation of 1,3-butadiene by transition metal compounds immobilized in 1-butyl-3-methyl imidazolium room temperature ionic liquids
title_full Selective hydrogenation of 1,3-butadiene by transition metal compounds immobilized in 1-butyl-3-methyl imidazolium room temperature ionic liquids
title_fullStr Selective hydrogenation of 1,3-butadiene by transition metal compounds immobilized in 1-butyl-3-methyl imidazolium room temperature ionic liquids
title_full_unstemmed Selective hydrogenation of 1,3-butadiene by transition metal compounds immobilized in 1-butyl-3-methyl imidazolium room temperature ionic liquids
title_sort Selective hydrogenation of 1,3-butadiene by transition metal compounds immobilized in 1-butyl-3-methyl imidazolium room temperature ionic liquids
author Consorti, Crestina S.
author_facet Consorti, Crestina S.
Umpierre, Alexandre P.
Souza, Roberto F. de
Dupont, Jairton
Suarez, Paulo A. Z.
author_role author
author2 Umpierre, Alexandre P.
Souza, Roberto F. de
Dupont, Jairton
Suarez, Paulo A. Z.
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Consorti, Crestina S.
Umpierre, Alexandre P.
Souza, Roberto F. de
Dupont, Jairton
Suarez, Paulo A. Z.
dc.subject.keyword.pt_BR.fl_str_mv biphasic hydrogenation
ionic liquids
dienes
cobalt catalysts
topic biphasic hydrogenation
ionic liquids
dienes
cobalt catalysts
description The compounds [Co(acac)2], [Co(acac)3], [Fe(acac)3] and [Ni(acac)2] (acac = acetylacetonate) dissolved in 1-butyl-3-methyl imidazolium tetrafluoroborate (1), trifluoromethanesulphonate (2) or hexafluorophosphate (3) catalyze the reduction of 1,3-butadiene into butenes in a typical two-phase catalytic reaction. The 1,3-butadiene conversion, the selectivity and turnover frequencies (TOF) are strongly dependent on the nature of the transition metal catalyst precursor and the ionic liquid. For [Co(acac)2] dissolved in 1, kinetic studies strongly suggest that the reaction takes place in the ionic solution bulk, having an apparent activation energy for the overall process of 33.8 kJ mol-1. The recovered ionic catalyst solution can be reused several times without any significant changes on activity and selectivity.
publishDate 2003
dc.date.issued.fl_str_mv 2003
dc.date.accessioned.fl_str_mv 2017-12-07T04:38:30Z
dc.date.available.fl_str_mv 2017-12-07T04:38:30Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.citation.fl_str_mv J. Braz. Chem. Soc.,v.14,n.3,p.401-405,2003
dc.identifier.uri.fl_str_mv http://repositorio.unb.br/handle/10482/26062
dc.identifier.doi.pt_BR.fl_str_mv https://dx.doi.org/10.1590/S0103-50532003000300010
identifier_str_mv J. Braz. Chem. Soc.,v.14,n.3,p.401-405,2003
url http://repositorio.unb.br/handle/10482/26062
https://dx.doi.org/10.1590/S0103-50532003000300010
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv reponame:Repositório Institucional da UnB
instname:Universidade de Brasília (UnB)
instacron:UNB
instname_str Universidade de Brasília (UnB)
instacron_str UNB
institution UNB
reponame_str Repositório Institucional da UnB
collection Repositório Institucional da UnB
bitstream.url.fl_str_mv http://repositorio2.unb.br/jspui/bitstream/10482/26062/1/15900.pdf
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repository.name.fl_str_mv Repositório Institucional da UnB - Universidade de Brasília (UnB)
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