Comparison of some properties of Cu(II) 2,3- , 3,5- and 2,6-dimethoxybenzoates

Detalhes bibliográficos
Autor(a) principal: Ferenc,W.
Data de Publicação: 2006
Outros Autores: Walków-Dziewulska,A., Sarzyski,J., Paszkowska,B.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Eclética Química
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702006000300001
Resumo: The physico-chemical properties and thermal stability in air of Cu(II) 2,3- , 3,5- and 2,6-dimethoxybenzoates were compared and the influence of the position of -OCH3 substituent on their thermal stability was investigated. The complexes are crystalline, hydrated salts with blue colour. The carboxylate ion is a bidentate chelating or bridging group. The thermal stability of analysed Cu(II) dimethoxybenzoates was studied in the temperature range of 293-1173 K. The positions of methoxy- groups in benzene ring influence the thermal properties of studied complexes. Their different thermal properties are markedly connected with the various influence of inductive, mesomeric and steric effects of -OCH3 substituent on the electron density in benzene ring. The magnetic susceptibilities of the complexes were measured over the range of 76-300 K and the magnetic moments were calculated. The results show that they form dimers.
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spelling Comparison of some properties of Cu(II) 2,3- , 3,5- and 2,6-dimethoxybenzoatesdimethoxybenzoatescomplexes of Cu(II)magnetic momentsthermal behaviorFTIR spectraThe physico-chemical properties and thermal stability in air of Cu(II) 2,3- , 3,5- and 2,6-dimethoxybenzoates were compared and the influence of the position of -OCH3 substituent on their thermal stability was investigated. The complexes are crystalline, hydrated salts with blue colour. The carboxylate ion is a bidentate chelating or bridging group. The thermal stability of analysed Cu(II) dimethoxybenzoates was studied in the temperature range of 293-1173 K. The positions of methoxy- groups in benzene ring influence the thermal properties of studied complexes. Their different thermal properties are markedly connected with the various influence of inductive, mesomeric and steric effects of -OCH3 substituent on the electron density in benzene ring. The magnetic susceptibilities of the complexes were measured over the range of 76-300 K and the magnetic moments were calculated. The results show that they form dimers.Fundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESP2006-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702006000300001Eclética Química v.31 n.3 2006reponame:Eclética Químicainstname:Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)instacron:UNESP10.1590/S0100-46702006000300001info:eu-repo/semantics/openAccessFerenc,W.Walków-Dziewulska,A.Sarzyski,J.Paszkowska,B.eng2006-12-18T00:00:00Zoai:scielo:S0100-46702006000300001Revistahttp://revista.iq.unesp.br/ojs/index.php/ecletica/PUBhttps://revista.iq.unesp.br/ojs/index.php/ecletica/oaiecletica@ctrlk.com.br||ecletica@iq.unesp.br1678-46181678-4618opendoar:2006-12-18T00:00Eclética Química - Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)false
dc.title.none.fl_str_mv Comparison of some properties of Cu(II) 2,3- , 3,5- and 2,6-dimethoxybenzoates
title Comparison of some properties of Cu(II) 2,3- , 3,5- and 2,6-dimethoxybenzoates
spellingShingle Comparison of some properties of Cu(II) 2,3- , 3,5- and 2,6-dimethoxybenzoates
Ferenc,W.
dimethoxybenzoates
complexes of Cu(II)
magnetic moments
thermal behavior
FTIR spectra
title_short Comparison of some properties of Cu(II) 2,3- , 3,5- and 2,6-dimethoxybenzoates
title_full Comparison of some properties of Cu(II) 2,3- , 3,5- and 2,6-dimethoxybenzoates
title_fullStr Comparison of some properties of Cu(II) 2,3- , 3,5- and 2,6-dimethoxybenzoates
title_full_unstemmed Comparison of some properties of Cu(II) 2,3- , 3,5- and 2,6-dimethoxybenzoates
title_sort Comparison of some properties of Cu(II) 2,3- , 3,5- and 2,6-dimethoxybenzoates
author Ferenc,W.
author_facet Ferenc,W.
Walków-Dziewulska,A.
Sarzyski,J.
Paszkowska,B.
author_role author
author2 Walków-Dziewulska,A.
Sarzyski,J.
Paszkowska,B.
author2_role author
author
author
dc.contributor.author.fl_str_mv Ferenc,W.
Walków-Dziewulska,A.
Sarzyski,J.
Paszkowska,B.
dc.subject.por.fl_str_mv dimethoxybenzoates
complexes of Cu(II)
magnetic moments
thermal behavior
FTIR spectra
topic dimethoxybenzoates
complexes of Cu(II)
magnetic moments
thermal behavior
FTIR spectra
description The physico-chemical properties and thermal stability in air of Cu(II) 2,3- , 3,5- and 2,6-dimethoxybenzoates were compared and the influence of the position of -OCH3 substituent on their thermal stability was investigated. The complexes are crystalline, hydrated salts with blue colour. The carboxylate ion is a bidentate chelating or bridging group. The thermal stability of analysed Cu(II) dimethoxybenzoates was studied in the temperature range of 293-1173 K. The positions of methoxy- groups in benzene ring influence the thermal properties of studied complexes. Their different thermal properties are markedly connected with the various influence of inductive, mesomeric and steric effects of -OCH3 substituent on the electron density in benzene ring. The magnetic susceptibilities of the complexes were measured over the range of 76-300 K and the magnetic moments were calculated. The results show that they form dimers.
publishDate 2006
dc.date.none.fl_str_mv 2006-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702006000300001
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702006000300001
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0100-46702006000300001
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Fundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESP
publisher.none.fl_str_mv Fundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESP
dc.source.none.fl_str_mv Eclética Química v.31 n.3 2006
reponame:Eclética Química
instname:Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Eclética Química
collection Eclética Química
repository.name.fl_str_mv Eclética Química - Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)
repository.mail.fl_str_mv ecletica@ctrlk.com.br||ecletica@iq.unesp.br
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