MPolSys Modeler, a tool for computational modeling of linear polymer systems
Autor(a) principal: | |
---|---|
Data de Publicação: | 2021 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Research, Society and Development |
Texto Completo: | https://rsdjournal.org/index.php/rsd/article/view/24007 |
Resumo: | The computational study of intermolecular relationships of a given material can be used as a route for predicting quantities impossible or difficult to be determined experimentally. Furthermore properties of new materials can also be predicted by techniques of this type, when they are still in the modeling phase. This technique reproduces the classical dynamic relationships between the constituent elements of the material, atoms or unicorpuscular approximations of molecules, from interaction potential models called force fields. This work aims to develop a tool that performs the composition of linear polymeric chain systems through a self-avoided walk. For this, the concept of self-experimentation of long walks (SAWLC) was used, together with the Python language to develop MpolSys Modeler. This tool is a non-overlapping polymer chain generator, which in turn generates outputs that can be used as input to Moltemplate. To validate the tool's results, experiments were carried out in which the numbers and polymerization chains of the simulated polymer were varied, observing the overlap or not of the molecules that make up the simulation. At the end of the simulations, there were positive results that indicate a promising usage of the tool for the creation of polymers with a high number of chains and degrees of polymerization. |
id |
UNIFEI_275fa5db2ea843fd033891162c6c8b02 |
---|---|
oai_identifier_str |
oai:ojs.pkp.sfu.ca:article/24007 |
network_acronym_str |
UNIFEI |
network_name_str |
Research, Society and Development |
repository_id_str |
|
spelling |
MPolSys Modeler, a tool for computational modeling of linear polymer systemsMpolSys Modeler, una herramienta para el modelado computacional de sistemas de polímeros linealesMPolSys Modeler, uma ferramenta para modelagem computacional de sistemas poliméricos linearesMPolSysMoltemplateSAWLCPolímero.MPolsysMoltemplateSAWLCPolymer.MPolSysMoltemplateSAWLCPolímero.The computational study of intermolecular relationships of a given material can be used as a route for predicting quantities impossible or difficult to be determined experimentally. Furthermore properties of new materials can also be predicted by techniques of this type, when they are still in the modeling phase. This technique reproduces the classical dynamic relationships between the constituent elements of the material, atoms or unicorpuscular approximations of molecules, from interaction potential models called force fields. This work aims to develop a tool that performs the composition of linear polymeric chain systems through a self-avoided walk. For this, the concept of self-experimentation of long walks (SAWLC) was used, together with the Python language to develop MpolSys Modeler. This tool is a non-overlapping polymer chain generator, which in turn generates outputs that can be used as input to Moltemplate. To validate the tool's results, experiments were carried out in which the numbers and polymerization chains of the simulated polymer were varied, observing the overlap or not of the molecules that make up the simulation. At the end of the simulations, there were positive results that indicate a promising usage of the tool for the creation of polymers with a high number of chains and degrees of polymerization.El estudio computacional de las relaciones intermoleculares de un material dado puede usarse como una ruta para predecir cantidades que son imposibles o difíciles de determinar experimentalmente. Las propiedades de los nuevos materiales también pueden predecirse mediante técnicas de este tipo, cuando aún se encuentran en la fase de modelado. Esta técnica reproduce las relaciones dinámicas clásicas entre los elementos constituyentes del material, átomos o aproximaciones de interacciones unicorpusculares de moléculas, a partir de modelos potenciales denominados campos de fuerza. Este trabajo tiene como objetivo desarrollar una herramienta que realice la composición de sistemas de cadenas poliméricas lineales a través de un paseo autoevitado. Para ello, se utilizó el concepto de SAWLC (caminata autoevitante de largas distancias), junto con el lenguaje Python 3 para desarrollar MpolSys Modeler. Esta herramienta es un generador de cadenas de polímeros que no se superponen, que a su vez genera salidas que se pueden utilizar como entrada para Moltemplate. Para validar los resultados de la herramienta, se realizaron experimentos en los que se variaron los números y las cadenas de polimerización del polímero simulado, observando el solapamiento o no de las moléculas que componen la simulación. Al final de las simulaciones, se obtuvieron resultados positivos que indican una posibilidad prometedora de utilizar la herramienta para la creación de polímeros con alto número de cadenas y grados de polimerización.O estudo computacional das relações intermoleculares de um determinado material pode ser usado como uma rota para prever quantidades que são impossíveis ou difíceis de determinar experimentalmente. Propriedades de novos materiais também podem ser previstas por técnicas desse tipo, quando ainda estão em fase de modelagem. Esta técnica reproduz as relações dinâmicas clássicas entre os elementos constituintes do material, átomos ou aproximações de interações unicorpusculares de moléculas, a partir de modelos potenciais denominados campos de força. Este trabalho tem como objetivo desenvolver uma ferramenta que realiza a composição de sistemas de cadeias poliméricas lineares por meio de uma caminhada auto evitada. Para isso, foi utilizado o conceito de SAWLC (caminhadas auto-evitantes de longas distâncias), em conjunto com a linguagem Python 3 para desenvolver MPolSys Modeler. Esta ferramenta é um gerador de cadeia de polímero não sobreposto, que por sua vez gera saídas que podem ser usadas como entrada para Moltemplate. Para validar os resultados da ferramenta, foram realizados experimentos nos quais foram variados os números e as cadeias de polimerização do polímero simulado, observando-se a sobreposição ou não das moléculas que compõem a simulação. Ao final das simulações, houve resultados positivos que indicam uma possibilidade promissora de utilização da ferramenta para a criação de polímeros com elevado número de cadeias e graus de polimerização.Research, Society and Development2021-12-14info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://rsdjournal.org/index.php/rsd/article/view/2400710.33448/rsd-v10i16.24007Research, Society and Development; Vol. 10 No. 16; e359101624007Research, Society and Development; Vol. 10 Núm. 16; e359101624007Research, Society and Development; v. 10 n. 16; e3591016240072525-3409reponame:Research, Society and Developmentinstname:Universidade Federal de Itajubá (UNIFEI)instacron:UNIFEIenghttps://rsdjournal.org/index.php/rsd/article/view/24007/21007Copyright (c) 2021 Filipe Morais Frade de Faria; Reginaldo Gonçalves Leão Juniorhttps://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessFaria, Filipe Morais Frade de Leão Junior, Reginaldo Gonçalves 2021-12-20T11:03:07Zoai:ojs.pkp.sfu.ca:article/24007Revistahttps://rsdjournal.org/index.php/rsd/indexPUBhttps://rsdjournal.org/index.php/rsd/oairsd.articles@gmail.com2525-34092525-3409opendoar:2024-01-17T09:42:41.944767Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)false |
dc.title.none.fl_str_mv |
MPolSys Modeler, a tool for computational modeling of linear polymer systems MpolSys Modeler, una herramienta para el modelado computacional de sistemas de polímeros lineales MPolSys Modeler, uma ferramenta para modelagem computacional de sistemas poliméricos lineares |
title |
MPolSys Modeler, a tool for computational modeling of linear polymer systems |
spellingShingle |
MPolSys Modeler, a tool for computational modeling of linear polymer systems Faria, Filipe Morais Frade de MPolSys Moltemplate SAWLC Polímero. MPolsys Moltemplate SAWLC Polymer. MPolSys Moltemplate SAWLC Polímero. |
title_short |
MPolSys Modeler, a tool for computational modeling of linear polymer systems |
title_full |
MPolSys Modeler, a tool for computational modeling of linear polymer systems |
title_fullStr |
MPolSys Modeler, a tool for computational modeling of linear polymer systems |
title_full_unstemmed |
MPolSys Modeler, a tool for computational modeling of linear polymer systems |
title_sort |
MPolSys Modeler, a tool for computational modeling of linear polymer systems |
author |
Faria, Filipe Morais Frade de |
author_facet |
Faria, Filipe Morais Frade de Leão Junior, Reginaldo Gonçalves |
author_role |
author |
author2 |
Leão Junior, Reginaldo Gonçalves |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Faria, Filipe Morais Frade de Leão Junior, Reginaldo Gonçalves |
dc.subject.por.fl_str_mv |
MPolSys Moltemplate SAWLC Polímero. MPolsys Moltemplate SAWLC Polymer. MPolSys Moltemplate SAWLC Polímero. |
topic |
MPolSys Moltemplate SAWLC Polímero. MPolsys Moltemplate SAWLC Polymer. MPolSys Moltemplate SAWLC Polímero. |
description |
The computational study of intermolecular relationships of a given material can be used as a route for predicting quantities impossible or difficult to be determined experimentally. Furthermore properties of new materials can also be predicted by techniques of this type, when they are still in the modeling phase. This technique reproduces the classical dynamic relationships between the constituent elements of the material, atoms or unicorpuscular approximations of molecules, from interaction potential models called force fields. This work aims to develop a tool that performs the composition of linear polymeric chain systems through a self-avoided walk. For this, the concept of self-experimentation of long walks (SAWLC) was used, together with the Python language to develop MpolSys Modeler. This tool is a non-overlapping polymer chain generator, which in turn generates outputs that can be used as input to Moltemplate. To validate the tool's results, experiments were carried out in which the numbers and polymerization chains of the simulated polymer were varied, observing the overlap or not of the molecules that make up the simulation. At the end of the simulations, there were positive results that indicate a promising usage of the tool for the creation of polymers with a high number of chains and degrees of polymerization. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-12-14 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://rsdjournal.org/index.php/rsd/article/view/24007 10.33448/rsd-v10i16.24007 |
url |
https://rsdjournal.org/index.php/rsd/article/view/24007 |
identifier_str_mv |
10.33448/rsd-v10i16.24007 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
https://rsdjournal.org/index.php/rsd/article/view/24007/21007 |
dc.rights.driver.fl_str_mv |
Copyright (c) 2021 Filipe Morais Frade de Faria; Reginaldo Gonçalves Leão Junior https://creativecommons.org/licenses/by/4.0 info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
Copyright (c) 2021 Filipe Morais Frade de Faria; Reginaldo Gonçalves Leão Junior https://creativecommons.org/licenses/by/4.0 |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Research, Society and Development |
publisher.none.fl_str_mv |
Research, Society and Development |
dc.source.none.fl_str_mv |
Research, Society and Development; Vol. 10 No. 16; e359101624007 Research, Society and Development; Vol. 10 Núm. 16; e359101624007 Research, Society and Development; v. 10 n. 16; e359101624007 2525-3409 reponame:Research, Society and Development instname:Universidade Federal de Itajubá (UNIFEI) instacron:UNIFEI |
instname_str |
Universidade Federal de Itajubá (UNIFEI) |
instacron_str |
UNIFEI |
institution |
UNIFEI |
reponame_str |
Research, Society and Development |
collection |
Research, Society and Development |
repository.name.fl_str_mv |
Research, Society and Development - Universidade Federal de Itajubá (UNIFEI) |
repository.mail.fl_str_mv |
rsd.articles@gmail.com |
_version_ |
1797052698945650688 |