Synthesis and Physico-Chemical Characterization of Biomaterial CaO Obtained from Chicken Egg Shells
Autor(a) principal: | |
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Data de Publicação: | 2022 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Research, Society and Development |
Texto Completo: | https://rsdjournal.org/index.php/rsd/article/view/30807 |
Resumo: | The high consumption of chicken eggs produces tons of eggshells daily, generating a serious environmental problem, since they are improperly disposed of in sanitary landfills. This residue is mostly composed of calcium carbonate (CaCO3), a precursor for obtaining calcium oxide (CaO). Thus, this work aimed to obtain CaO from hen eggshells in order to confirm its characteristics as a biomaterial due to structural, chemical and thermal analysis for industrial purposes, which can be applied in the area of catalysis. For this, the samples were calcined at different temperatures (650, 700, 800 and 900 °C) with a residence time of two hours. The in natura and synthesized samples were analyzed by XRD, FTIR and TGA/DrTGA. The diffractograms confirmed the presence of CaCO3 as the main phase for the in natura eggshells, and for the samples calcined at different temperatures, CaO was formed as the main phase. The absorption bands showed the appearance of Ca-O binding for all calcined samples. In addition, for those subjected to 650 and 700 °C, C-O absorption bands were also found, attributed to the presence of CaCO3. The thermogravimetric curves, in turn, showed that all calcined samples were characterized as stable, as they did not present significant variation in their respective masses as a function of the programmed time and temperature. Thus, this residue is an excellent alternative and sustainable source for the production of CaO as a biomaterial. |
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Synthesis and Physico-Chemical Characterization of Biomaterial CaO Obtained from Chicken Egg ShellsSíntesis y Caracterización Físico-Química de Biomaterial CaO Obtenido de Cáscaras de Huevo de GallinaSíntese e Caracterização Físico-Química do Biomaterial CaO Obtido de Cascas de Ovos de GalinhaCascas de ovosCarbonato de cálcioCalcinaçãoÓxido de cálcioBiomaterial.EggshellsCalcium carbonateCalcinationCalcium oxideBiomaterial.Cáscaras de huevoCarbonato de calcioCalcinaciónÓxido de calcioBiomaterial.The high consumption of chicken eggs produces tons of eggshells daily, generating a serious environmental problem, since they are improperly disposed of in sanitary landfills. This residue is mostly composed of calcium carbonate (CaCO3), a precursor for obtaining calcium oxide (CaO). Thus, this work aimed to obtain CaO from hen eggshells in order to confirm its characteristics as a biomaterial due to structural, chemical and thermal analysis for industrial purposes, which can be applied in the area of catalysis. For this, the samples were calcined at different temperatures (650, 700, 800 and 900 °C) with a residence time of two hours. The in natura and synthesized samples were analyzed by XRD, FTIR and TGA/DrTGA. The diffractograms confirmed the presence of CaCO3 as the main phase for the in natura eggshells, and for the samples calcined at different temperatures, CaO was formed as the main phase. The absorption bands showed the appearance of Ca-O binding for all calcined samples. In addition, for those subjected to 650 and 700 °C, C-O absorption bands were also found, attributed to the presence of CaCO3. The thermogravimetric curves, in turn, showed that all calcined samples were characterized as stable, as they did not present significant variation in their respective masses as a function of the programmed time and temperature. Thus, this residue is an excellent alternative and sustainable source for the production of CaO as a biomaterial.El alto consumo de huevos de gallina produce toneladas de cáscaras de huevo diariamente, generando un grave problema ambiental, ya que son desechados indebidamente en rellenos sanitarios. Este residuo está compuesto mayoritariamente por carbonato de calcio (CaCO3), precursor para la obtención de óxido de calcio (CaO). Así, este trabajo tuvo como objetivo obtener CaO a partir de cáscaras de huevo de gallina con el fin de confirmar sus características como biomaterial debido al análisis estructural, químico y térmico con fines industriales, que pueda ser aplicado en el área de catálisis. Para ello, las muestras se calcinaron a diferentes temperaturas (650, 700, 800 y 900 °C) con un tiempo de residencia de dos horas. Las muestras in natura y sintetizadas fueron analizadas por XRD, FTIR y TGA/DrTGA. Los difractogramas confirmaron la presencia de CaCO3 como fase principal para las cáscaras de huevo in natura, y para las muestras calcinadas a diferentes temperaturas se formó CaO como fase principal. Las bandas de absorción mostraron la apariencia de unión Ca-O para todas las muestras calcinadas. Además, para los sometidos a 650 y 700 °C también se encontraron bandas de absorción de C-O, atribuidas a la presencia de CaCO3. Las curvas termogravimétricas, a su vez, mostraron que todas las muestras calcinadas se caracterizaron como estables, ya que no presentaron variación significativa en sus respectivas masas en función del tiempo y temperatura programados. Por lo tanto, este residuo es una excelente fuente alternativa y sostenible para la producción de CaO como biomaterial.O consumo elevado de ovo de galinha produz diariamente toneladas de cascas de ovos, gerando um grave problema ambiental, uma vez que são descartadas de forma inadequada em aterros sanitários. Este resíduo é composto, em sua maior parte, por carbonato de cálcio (CaCO3), um precursor para a obtenção do óxido de cálcio (CaO). Assim, neste trabalho objetivou-se obter CaO a partir das cascas de ovos de galinha a fim de confirmar suas características como um biomaterial em função de análise estrutural, química e térmica para fins industriais, podendo ser aplicado na área da catálise. Para tanto, as amostras foram calcinadas em diferentes temperaturas (650, 700, 800 e 900 °C) com tempo de permanência de duas horas. As amostras in natura e sintetizadas foram analisadas por DRX, FTIR e TGA/DrTGA. Os difratogramas confirmaram a presença de CaCO3 como fase principal para as cascas de ovo in natura, sendo que para as amostras calcinadas em diferentes temperaturas ocorreu a formação CaO como fase principal. As bandas de absorção evidenciaram o aparecimento da ligação Ca-O para todas as amostras calcinadas. Além disto, para aquelas submetidas a 650 e 700 °C, foram ainda encontradas bandas de absorção de C-O, atribuídas à presença do CaCO3. As curvas termogravimétricas, por sua vez, mostraram que todas as amostras calcinadas se caracterizaram como estáveis, pois não apresentaram variação significativa em suas respectivas massas em função do tempo e temperatura programados. Desta forma, esse resíduo é uma excelente fonte alternativa e sustentável para a produção de CaO como biomaterial.Research, Society and Development2022-06-26info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://rsdjournal.org/index.php/rsd/article/view/3080710.33448/rsd-v11i8.30807Research, Society and Development; Vol. 11 No. 8; e45311830807Research, Society and Development; Vol. 11 Núm. 8; e45311830807Research, Society and Development; v. 11 n. 8; e453118308072525-3409reponame:Research, Society and Developmentinstname:Universidade Federal de Itajubá (UNIFEI)instacron:UNIFEIporhttps://rsdjournal.org/index.php/rsd/article/view/30807/26696Copyright (c) 2022 Angélica Oliveira de Alencar; Taffarel Eloi de Moura; Pollyana Caetano Ribeiro Fernandes; Elvia Leal; Joelda Dantashttps://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessAlencar, Angélica Oliveira deMoura, Taffarel Eloi deFernandes, Pollyana Caetano Ribeiro Leal, ElviaDantas, Joelda2022-07-01T13:34:06Zoai:ojs.pkp.sfu.ca:article/30807Revistahttps://rsdjournal.org/index.php/rsd/indexPUBhttps://rsdjournal.org/index.php/rsd/oairsd.articles@gmail.com2525-34092525-3409opendoar:2024-01-17T09:47:25.810160Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)false |
dc.title.none.fl_str_mv |
Synthesis and Physico-Chemical Characterization of Biomaterial CaO Obtained from Chicken Egg Shells Síntesis y Caracterización Físico-Química de Biomaterial CaO Obtenido de Cáscaras de Huevo de Gallina Síntese e Caracterização Físico-Química do Biomaterial CaO Obtido de Cascas de Ovos de Galinha |
title |
Synthesis and Physico-Chemical Characterization of Biomaterial CaO Obtained from Chicken Egg Shells |
spellingShingle |
Synthesis and Physico-Chemical Characterization of Biomaterial CaO Obtained from Chicken Egg Shells Alencar, Angélica Oliveira de Cascas de ovos Carbonato de cálcio Calcinação Óxido de cálcio Biomaterial. Eggshells Calcium carbonate Calcination Calcium oxide Biomaterial. Cáscaras de huevo Carbonato de calcio Calcinación Óxido de calcio Biomaterial. |
title_short |
Synthesis and Physico-Chemical Characterization of Biomaterial CaO Obtained from Chicken Egg Shells |
title_full |
Synthesis and Physico-Chemical Characterization of Biomaterial CaO Obtained from Chicken Egg Shells |
title_fullStr |
Synthesis and Physico-Chemical Characterization of Biomaterial CaO Obtained from Chicken Egg Shells |
title_full_unstemmed |
Synthesis and Physico-Chemical Characterization of Biomaterial CaO Obtained from Chicken Egg Shells |
title_sort |
Synthesis and Physico-Chemical Characterization of Biomaterial CaO Obtained from Chicken Egg Shells |
author |
Alencar, Angélica Oliveira de |
author_facet |
Alencar, Angélica Oliveira de Moura, Taffarel Eloi de Fernandes, Pollyana Caetano Ribeiro Leal, Elvia Dantas, Joelda |
author_role |
author |
author2 |
Moura, Taffarel Eloi de Fernandes, Pollyana Caetano Ribeiro Leal, Elvia Dantas, Joelda |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Alencar, Angélica Oliveira de Moura, Taffarel Eloi de Fernandes, Pollyana Caetano Ribeiro Leal, Elvia Dantas, Joelda |
dc.subject.por.fl_str_mv |
Cascas de ovos Carbonato de cálcio Calcinação Óxido de cálcio Biomaterial. Eggshells Calcium carbonate Calcination Calcium oxide Biomaterial. Cáscaras de huevo Carbonato de calcio Calcinación Óxido de calcio Biomaterial. |
topic |
Cascas de ovos Carbonato de cálcio Calcinação Óxido de cálcio Biomaterial. Eggshells Calcium carbonate Calcination Calcium oxide Biomaterial. Cáscaras de huevo Carbonato de calcio Calcinación Óxido de calcio Biomaterial. |
description |
The high consumption of chicken eggs produces tons of eggshells daily, generating a serious environmental problem, since they are improperly disposed of in sanitary landfills. This residue is mostly composed of calcium carbonate (CaCO3), a precursor for obtaining calcium oxide (CaO). Thus, this work aimed to obtain CaO from hen eggshells in order to confirm its characteristics as a biomaterial due to structural, chemical and thermal analysis for industrial purposes, which can be applied in the area of catalysis. For this, the samples were calcined at different temperatures (650, 700, 800 and 900 °C) with a residence time of two hours. The in natura and synthesized samples were analyzed by XRD, FTIR and TGA/DrTGA. The diffractograms confirmed the presence of CaCO3 as the main phase for the in natura eggshells, and for the samples calcined at different temperatures, CaO was formed as the main phase. The absorption bands showed the appearance of Ca-O binding for all calcined samples. In addition, for those subjected to 650 and 700 °C, C-O absorption bands were also found, attributed to the presence of CaCO3. The thermogravimetric curves, in turn, showed that all calcined samples were characterized as stable, as they did not present significant variation in their respective masses as a function of the programmed time and temperature. Thus, this residue is an excellent alternative and sustainable source for the production of CaO as a biomaterial. |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022-06-26 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://rsdjournal.org/index.php/rsd/article/view/30807 10.33448/rsd-v11i8.30807 |
url |
https://rsdjournal.org/index.php/rsd/article/view/30807 |
identifier_str_mv |
10.33448/rsd-v11i8.30807 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
https://rsdjournal.org/index.php/rsd/article/view/30807/26696 |
dc.rights.driver.fl_str_mv |
https://creativecommons.org/licenses/by/4.0 info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by/4.0 |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Research, Society and Development |
publisher.none.fl_str_mv |
Research, Society and Development |
dc.source.none.fl_str_mv |
Research, Society and Development; Vol. 11 No. 8; e45311830807 Research, Society and Development; Vol. 11 Núm. 8; e45311830807 Research, Society and Development; v. 11 n. 8; e45311830807 2525-3409 reponame:Research, Society and Development instname:Universidade Federal de Itajubá (UNIFEI) instacron:UNIFEI |
instname_str |
Universidade Federal de Itajubá (UNIFEI) |
instacron_str |
UNIFEI |
institution |
UNIFEI |
reponame_str |
Research, Society and Development |
collection |
Research, Society and Development |
repository.name.fl_str_mv |
Research, Society and Development - Universidade Federal de Itajubá (UNIFEI) |
repository.mail.fl_str_mv |
rsd.articles@gmail.com |
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1797052767733284864 |