Chemical profile and bioprospecting of cocoa beans analyzed by paper spray mass spectrometry
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Research, Society and Development |
Texto Completo: | https://rsdjournal.org/index.php/rsd/article/view/6882 |
Resumo: | The quality cocoa derived products have increasingly received greater recognition and relevance both by consumers and producers. Cocoa beans are the main components responsible for much of the cocoa agro-industrial chain being currently valued for the bioactive properties found in the species' by-products, creating a great interest in exploring the potentials of cocoa. Much of the work that aims to evaluate the compounds found in the fruit's beans employ HPLC, UHPLC and LC-MS. In this work Paper Spray Mass Spectrometry (PS-MS) was employed as a method for characterizing and bioprospecting the chemical profile of cocoa beans (Theobroma cacao) of the forrasteiro variety grown in the Trans-Amazonian region of the Brazilian State of Pará. Methanolic extracts were prepared from samples of cocoa beans and evaluated in the negative and positive ionization modes. In the positive ionization mode it was possible to identify 11 compounds, comprising the classes of methylxanthines (18.2%), phenylpropanoids (9.1%), steroids (27.3%) and flavonoids (45.5%), while in the negative ionization mode, it was possible to identify 55 compounds among hydroxybenzoic acids (16.4%), phenylpropanoids (20.0%), flavonoids (52.7%), sugars and glycosides (10.9%). PS-MS proved to be an effective method for the evaluation of cocoa bean samples, being able to identify a total of sixty-six compounds. The bioactive properties attributed to cocoa were confirmed in the samples analyzed by the compounds identified through PS-MS whilst also indicating the quality of the raw material and describing its chemical profile, contributing to a greater understanding of its attributes. |
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Chemical profile and bioprospecting of cocoa beans analyzed by paper spray mass spectrometryPerfil químico y bioprospección de granos de cacao analizados por espectrometría de masas con ionización por paper sprayPerfil químico e bioprospecção de amêndoas de cacau analisadas por espectrometria de massas com ionização por paper sprayPS-MSTheobroma cacaoCompuestos bioactivos20-HidroxiecdisonaClovamida.PS-MSTheobroma cacaoBioactive compounds20-HydroxyecdysoneClovamide.PS-MSTheobroma cacaoCompostos bioativos20-HidroxiecdisonaClovamida.The quality cocoa derived products have increasingly received greater recognition and relevance both by consumers and producers. Cocoa beans are the main components responsible for much of the cocoa agro-industrial chain being currently valued for the bioactive properties found in the species' by-products, creating a great interest in exploring the potentials of cocoa. Much of the work that aims to evaluate the compounds found in the fruit's beans employ HPLC, UHPLC and LC-MS. In this work Paper Spray Mass Spectrometry (PS-MS) was employed as a method for characterizing and bioprospecting the chemical profile of cocoa beans (Theobroma cacao) of the forrasteiro variety grown in the Trans-Amazonian region of the Brazilian State of Pará. Methanolic extracts were prepared from samples of cocoa beans and evaluated in the negative and positive ionization modes. In the positive ionization mode it was possible to identify 11 compounds, comprising the classes of methylxanthines (18.2%), phenylpropanoids (9.1%), steroids (27.3%) and flavonoids (45.5%), while in the negative ionization mode, it was possible to identify 55 compounds among hydroxybenzoic acids (16.4%), phenylpropanoids (20.0%), flavonoids (52.7%), sugars and glycosides (10.9%). PS-MS proved to be an effective method for the evaluation of cocoa bean samples, being able to identify a total of sixty-six compounds. The bioactive properties attributed to cocoa were confirmed in the samples analyzed by the compounds identified through PS-MS whilst also indicating the quality of the raw material and describing its chemical profile, contributing to a greater understanding of its attributes.Productos derivados del cacao han recibido cada vez más reconocimiento y relevancia tanto por parte de los consumidores como de los productores. Los granos de cacao son los principales componentes responsables de gran parte de la cadena agroindustrial del cacao que actualmente se valora por las propiedades bioactivas que se encuentran en sus subproductos, lo que crea un gran interés en explorar los potenciales del cacao. Trabajos que objetivan evaluar los compuestos en semillas de la fruta emplean HPLC, UHPLC y LC-MS. Este trabajo empleó la espectrometría de masas por paper spray (PS-MS) como método para caracterizar y bioprospectar el perfil químico de granos de cacao (Theobroma cacao) de la variedad forrasteiro cultivada en el estado brasileño de Pará. Extractos metanólicos se prepararon con muestras de granos de cacao y se evaluaron en modos de ionización negativa y positiva. En el modo de ionización positiva, fue posible identificar 11 compuestos, que comprenden las clases metilxantinas (18.2%), fenilpropanoides (9.1%), esteroides (27.3%) y flavonoides (45.5%), mientras que en el modo de ionización negativa, fue posible identificar 55 compuestos entre ácidos hidroxibenzoicos (16.4%), fenilpropanoides (20.0%), flavonoides (52.7%), azúcares y glucósidos (10.9%). PS-MS demostró ser eficaz para la evaluación de muestras de granos de cacao, identificando un total de 66 compuestos. Las propiedades bioactivas atribuidas al cacao se confirmaron en muestras analizadas por los compuestos identificados a través de PS-MS al tiempo que indicaban la calidad de materia prima y describían su perfil químico, contribuyendo a una mayor comprensión de sus atributos.A qualidade dos produtos derivados do cacau tem cada vez mais recebido reconhecimento e relevância tanto pelos consumidores quanto produtores do fruto. As amêndoas são os principais componentes responsáveis por grande parte da cadeia agroindustrial sendo atualmente valorizadas pelas propriedades bioativas contidas nos subprodutos da espécie, gerando um grande interesse na exploração dos potenciais do cacau. Grande parte dos trabalhos que objetivam avaliar os compostos encontrados nas amêndoas do fruto empregam HPLC, UHPLC e LC-MS. Este trabalho objetivou empregar a técnica de Espectrometria de Massas com Ionização por Paper Spray (PS-MS) para o estudo do perfil químico e de bioprospecção de amêndoas de cacau (Theobroma cacao) da variedade forasteiro cultivados na região Transamazônica do Pará. Foram preparados extratos metanólicos de amostras de amêndoas de cacau e em seguida avaliadas nos modos de ionização negativo e positivo. Os resultados demonstram que no modo positivo foi possível identificar 11 compostos, constituintes das classes das metilxantinas (18,2%), fenilpropanoides (9,1%), esteróides (27,3%) e flavonóides (45,5%), já no modo de ionização negativa foi possível identificar 55 compostos entre ácidos hidroxibenzóicos (16,4%), fenilpropanoides (20,0%), flavonoides (52,7%), açúcares e glicosídeos (10,9%). A metodologia empregada de PS-MS se demonstrou eficaz para a avaliação das amostras, possibilitando identificar no total sessenta e seis compostos. As propriedades bioativas atribuídas ao cacau foram confirmadas nas amostras analisadas pelos compostos identificados por PS-MS indicando a qualidade da matéria prima e descrevendo o seu perfil químico e contribuindo para o maior entendimento dos seus atributos.Research, Society and Development2020-08-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://rsdjournal.org/index.php/rsd/article/view/688210.33448/rsd-v9i8.6882Research, Society and Development; Vol. 9 No. 8; e975986882Research, Society and Development; Vol. 9 Núm. 8; e975986882Research, Society and Development; v. 9 n. 8; e9759868822525-3409reponame:Research, Society and Developmentinstname:Universidade Federal de Itajubá (UNIFEI)instacron:UNIFEIenghttps://rsdjournal.org/index.php/rsd/article/view/6882/6086Copyright (c) 2020 Afonso Henrique de Oliveira Júnior, Ana Luiza Coeli Cruz Ramos, Mayara Neves Santos Guedes, Miriã Cristina Pereira Fagundes, Rodinei Augusti, Júlio Onésio Ferreira Melohttp://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessOliveira Júnior, Afonso Henrique deRamos, Ana Luiza Coeli CruzGuedes, Mayara Neves SantosFagundes, Miriã Cristina PereiraAugusti, RodineiMelo, Júlio Onésio Ferreira2020-08-20T18:00:17Zoai:ojs.pkp.sfu.ca:article/6882Revistahttps://rsdjournal.org/index.php/rsd/indexPUBhttps://rsdjournal.org/index.php/rsd/oairsd.articles@gmail.com2525-34092525-3409opendoar:2024-01-17T09:29:50.123581Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)false |
dc.title.none.fl_str_mv |
Chemical profile and bioprospecting of cocoa beans analyzed by paper spray mass spectrometry Perfil químico y bioprospección de granos de cacao analizados por espectrometría de masas con ionización por paper spray Perfil químico e bioprospecção de amêndoas de cacau analisadas por espectrometria de massas com ionização por paper spray |
title |
Chemical profile and bioprospecting of cocoa beans analyzed by paper spray mass spectrometry |
spellingShingle |
Chemical profile and bioprospecting of cocoa beans analyzed by paper spray mass spectrometry Oliveira Júnior, Afonso Henrique de PS-MS Theobroma cacao Compuestos bioactivos 20-Hidroxiecdisona Clovamida. PS-MS Theobroma cacao Bioactive compounds 20-Hydroxyecdysone Clovamide. PS-MS Theobroma cacao Compostos bioativos 20-Hidroxiecdisona Clovamida. |
title_short |
Chemical profile and bioprospecting of cocoa beans analyzed by paper spray mass spectrometry |
title_full |
Chemical profile and bioprospecting of cocoa beans analyzed by paper spray mass spectrometry |
title_fullStr |
Chemical profile and bioprospecting of cocoa beans analyzed by paper spray mass spectrometry |
title_full_unstemmed |
Chemical profile and bioprospecting of cocoa beans analyzed by paper spray mass spectrometry |
title_sort |
Chemical profile and bioprospecting of cocoa beans analyzed by paper spray mass spectrometry |
author |
Oliveira Júnior, Afonso Henrique de |
author_facet |
Oliveira Júnior, Afonso Henrique de Ramos, Ana Luiza Coeli Cruz Guedes, Mayara Neves Santos Fagundes, Miriã Cristina Pereira Augusti, Rodinei Melo, Júlio Onésio Ferreira |
author_role |
author |
author2 |
Ramos, Ana Luiza Coeli Cruz Guedes, Mayara Neves Santos Fagundes, Miriã Cristina Pereira Augusti, Rodinei Melo, Júlio Onésio Ferreira |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Oliveira Júnior, Afonso Henrique de Ramos, Ana Luiza Coeli Cruz Guedes, Mayara Neves Santos Fagundes, Miriã Cristina Pereira Augusti, Rodinei Melo, Júlio Onésio Ferreira |
dc.subject.por.fl_str_mv |
PS-MS Theobroma cacao Compuestos bioactivos 20-Hidroxiecdisona Clovamida. PS-MS Theobroma cacao Bioactive compounds 20-Hydroxyecdysone Clovamide. PS-MS Theobroma cacao Compostos bioativos 20-Hidroxiecdisona Clovamida. |
topic |
PS-MS Theobroma cacao Compuestos bioactivos 20-Hidroxiecdisona Clovamida. PS-MS Theobroma cacao Bioactive compounds 20-Hydroxyecdysone Clovamide. PS-MS Theobroma cacao Compostos bioativos 20-Hidroxiecdisona Clovamida. |
description |
The quality cocoa derived products have increasingly received greater recognition and relevance both by consumers and producers. Cocoa beans are the main components responsible for much of the cocoa agro-industrial chain being currently valued for the bioactive properties found in the species' by-products, creating a great interest in exploring the potentials of cocoa. Much of the work that aims to evaluate the compounds found in the fruit's beans employ HPLC, UHPLC and LC-MS. In this work Paper Spray Mass Spectrometry (PS-MS) was employed as a method for characterizing and bioprospecting the chemical profile of cocoa beans (Theobroma cacao) of the forrasteiro variety grown in the Trans-Amazonian region of the Brazilian State of Pará. Methanolic extracts were prepared from samples of cocoa beans and evaluated in the negative and positive ionization modes. In the positive ionization mode it was possible to identify 11 compounds, comprising the classes of methylxanthines (18.2%), phenylpropanoids (9.1%), steroids (27.3%) and flavonoids (45.5%), while in the negative ionization mode, it was possible to identify 55 compounds among hydroxybenzoic acids (16.4%), phenylpropanoids (20.0%), flavonoids (52.7%), sugars and glycosides (10.9%). PS-MS proved to be an effective method for the evaluation of cocoa bean samples, being able to identify a total of sixty-six compounds. The bioactive properties attributed to cocoa were confirmed in the samples analyzed by the compounds identified through PS-MS whilst also indicating the quality of the raw material and describing its chemical profile, contributing to a greater understanding of its attributes. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-08-06 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://rsdjournal.org/index.php/rsd/article/view/6882 10.33448/rsd-v9i8.6882 |
url |
https://rsdjournal.org/index.php/rsd/article/view/6882 |
identifier_str_mv |
10.33448/rsd-v9i8.6882 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
https://rsdjournal.org/index.php/rsd/article/view/6882/6086 |
dc.rights.driver.fl_str_mv |
http://creativecommons.org/licenses/by/4.0 info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by/4.0 |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Research, Society and Development |
publisher.none.fl_str_mv |
Research, Society and Development |
dc.source.none.fl_str_mv |
Research, Society and Development; Vol. 9 No. 8; e975986882 Research, Society and Development; Vol. 9 Núm. 8; e975986882 Research, Society and Development; v. 9 n. 8; e975986882 2525-3409 reponame:Research, Society and Development instname:Universidade Federal de Itajubá (UNIFEI) instacron:UNIFEI |
instname_str |
Universidade Federal de Itajubá (UNIFEI) |
instacron_str |
UNIFEI |
institution |
UNIFEI |
reponame_str |
Research, Society and Development |
collection |
Research, Society and Development |
repository.name.fl_str_mv |
Research, Society and Development - Universidade Federal de Itajubá (UNIFEI) |
repository.mail.fl_str_mv |
rsd.articles@gmail.com |
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1797052738566094848 |