Synthesis, characterization magnetic and electrical of aluminate copper ferrite

Detalhes bibliográficos
Autor(a) principal: Ribeiro, Vander Alkmin dos Santos
Data de Publicação: 2021
Outros Autores: Oliveira, Valesca Donizete de, Rubinger, Rero Marques, Oliveira, Adhimar Flávio, Mendonça, Claudiney Sales Pereira
Tipo de documento: Artigo
Idioma: por
Título da fonte: Research, Society and Development
Texto Completo: https://rsdjournal.org/index.php/rsd/article/view/17314
Resumo: Currently, ferrites have been the subject of much research due to their advantages and properties that can be easily manipulated, thus being of great technological and scientific interest. Therefore, the distribution of cations and magnetic interactions highlight an important role in these materials and, therefore, have their scientific importance. The relationships between chemical composition, crystal structure, magnetic and electrical behavior were investigated in copper aluminum ferrites. The CuAlXFe2-XO4 ferrites, where x = 0.0; 0.5; 1.0, and 1.5 were obtained by the conventional ceramic method, the solid-state reaction between iron, aluminum, and copper oxides. The oxide mixture was pre-sintered for 24 hours at 800°C and then sintered at 1100°C for 8 hours. The magnetic properties were measured by a vibrating sample magnetometer and determined from the hysteresis graph, noting that it has a moderate magnetic material behavior due to the magnetization curve profile and coercivity values ​​(~223kA/m). The electrical conductivity of the pellets was obtained from voltage-by-current characteristics as a function of temperature. The electrical conductivity of the pellets was obtained from voltage-by-current characteristics as a function of temperature. The dependence of electrical conductivity with the temperature of copper aluminate ferrites with different compositions presented a semiconductor behavior and with the increase of the material resistivity with the increase of the aluminum content, it occurs due to its conductive property. It was also observed that the saturation magnetization decreases with increasing aluminum concentration, showing the behavior of a soft paramagnetic material.
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spelling Synthesis, characterization magnetic and electrical of aluminate copper ferrite Síntesis, caracterización magnética y eléctrica de ferrita de cobre aluminatoSíntese, caracterização magnética e elétrica da ferrita de aluminato de cobre FerritasPropriedades magnéticasCondutividade elétricaEnergia de ativação.FerritesMagnetic propertiesElectric conductivityActivation energy.FerritasPropiedades magnéticasConductividad eléctricaEnergía de activación.Currently, ferrites have been the subject of much research due to their advantages and properties that can be easily manipulated, thus being of great technological and scientific interest. Therefore, the distribution of cations and magnetic interactions highlight an important role in these materials and, therefore, have their scientific importance. The relationships between chemical composition, crystal structure, magnetic and electrical behavior were investigated in copper aluminum ferrites. The CuAlXFe2-XO4 ferrites, where x = 0.0; 0.5; 1.0, and 1.5 were obtained by the conventional ceramic method, the solid-state reaction between iron, aluminum, and copper oxides. The oxide mixture was pre-sintered for 24 hours at 800°C and then sintered at 1100°C for 8 hours. The magnetic properties were measured by a vibrating sample magnetometer and determined from the hysteresis graph, noting that it has a moderate magnetic material behavior due to the magnetization curve profile and coercivity values ​​(~223kA/m). The electrical conductivity of the pellets was obtained from voltage-by-current characteristics as a function of temperature. The electrical conductivity of the pellets was obtained from voltage-by-current characteristics as a function of temperature. The dependence of electrical conductivity with the temperature of copper aluminate ferrites with different compositions presented a semiconductor behavior and with the increase of the material resistivity with the increase of the aluminum content, it occurs due to its conductive property. It was also observed that the saturation magnetization decreases with increasing aluminum concentration, showing the behavior of a soft paramagnetic material.En la actualidad, las ferritas han sido objeto de mucha investigación debido a sus ventajas y propiedades de fácil manipulación, siendo así de gran interés tecnológico y científico. Por tanto, la distribución de cationes y las interacciones magnéticas destacan un papel importante en estos materiales y, por tanto, tienen su importancia científica. Se investigaron las relaciones entre la composición química, la estructura cristalina, el comportamiento magnético y eléctrico en ferritas de cobre y aluminio. Las ferritas CuAlXFe2-XO4, donde x = 0.0; 0,5; 1.0 y 1.5 se obtuvieron por el método cerámico convencional, la reacción en estado sólido entre óxidos de hierro, aluminio y cobre. La mezcla de óxidos se pre-sinterizó durante 24 horas a 800 ° C y luego se sinterizó a 1100 ° C durante 8 horas. Las propiedades magnéticas se midieron con un magnetómetro de muestra vibrante y se determinaron a partir del gráfico de histéresis, notando que tiene un comportamiento de material magnético moderado debido al perfil de la curva de magnetización y los valores de coercitividad (~ 223kA / m). La conductividad eléctrica de los gránulos se obtuvo a partir de las características de voltaje por corriente en función de la temperatura. La conductividad eléctrica de los gránulos se obtuvo a partir de las características voltaje por corriente en función de la temperatura. La dependencia de la conductividad eléctrica con la temperatura de las ferritas de aluminato de cobre con diferentes composiciones mostró un comportamiento semiconductor y con el aumento de la resistividad del material con el aumento del contenido de aluminio, se produce debido a su propiedad conductora. También se observó que la magnetización de saturación disminuye al aumentar la concentración de aluminio, mostrando el comportamiento de un material paramagnético y blando.Atualmente, as ferritas têm sido tema de muitas pesquisas devido as suas vantagens e propriedades que podem ser facilmente manipuladas, sendo assim de grande interesse tecnológico e científico. Para tanto, a distribuição dos cátions e interações magnéticas destacam um papel importante nestes materiais e, portanto, têm sua importância científica. As relações entre a composição química, estrutura cristalina, comportamento magnético e elétrico foram investigadas em ferritas de aluminato de cobre. As ferritas CuAlXFe2-XO4, onde x = 0,0; 0,5; 1,0 e 1,5 foram obtidas pelo método convencional de cerâmicas, reação estado-sólido entre os óxidos de ferro, alumínio e cobre.  A mistura de óxidos foram pré-sinterizadas por 24 horas a 800°C e depois sinterizadas a 1100°C durante 8h. As propriedades magnéticas foram medidas por um magnetômetro de amostra vibrante e determinadas a partir do gráfico de histerese, observando-se que possui um comportamento de um material magnético moderado devido ao perfil da curva de magnetização e valores de coercividade (~223kA/m). A condutividade elétrica das pastilhas foi obtida a partir de características de tensão pela corrente em função da temperatura. A dependência da condutividade elétrica com a temperatura das ferritas de aluminato de cobre com diferentes composições apresentou um comportamento semicondutor  e com o aumento da resistividade do material com o aumento do teor de alumínio ocorre devido à sua propriedade condutora. Também se observou que a magnetização de saturação diminui com o aumento da concentração de alumínio, apresentando comportamento de um material paramagnético e mole.Research, Society and Development2021-07-13info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://rsdjournal.org/index.php/rsd/article/view/1731410.33448/rsd-v10i8.17314Research, Society and Development; Vol. 10 No. 8; e31210817314Research, Society and Development; Vol. 10 Núm. 8; e31210817314Research, Society and Development; v. 10 n. 8; e312108173142525-3409reponame:Research, Society and Developmentinstname:Universidade Federal de Itajubá (UNIFEI)instacron:UNIFEIporhttps://rsdjournal.org/index.php/rsd/article/view/17314/15526Copyright (c) 2021 Vander Alkmin dos Santos Ribeiro; Valesca Donizete de Oliveira; Rero Marques Rubinger; Adhimar Flávio Oliveira; Claudiney Sales Pereira Mendonçahttps://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessRibeiro, Vander Alkmin dos Santos Oliveira, Valesca Donizete de Rubinger, Rero Marques Oliveira, Adhimar Flávio Mendonça, Claudiney Sales Pereira 2021-08-21T18:46:59Zoai:ojs.pkp.sfu.ca:article/17314Revistahttps://rsdjournal.org/index.php/rsd/indexPUBhttps://rsdjournal.org/index.php/rsd/oairsd.articles@gmail.com2525-34092525-3409opendoar:2024-01-17T09:37:41.060150Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)false
dc.title.none.fl_str_mv Synthesis, characterization magnetic and electrical of aluminate copper ferrite
Síntesis, caracterización magnética y eléctrica de ferrita de cobre aluminato
Síntese, caracterização magnética e elétrica da ferrita de aluminato de cobre
title Synthesis, characterization magnetic and electrical of aluminate copper ferrite
spellingShingle Synthesis, characterization magnetic and electrical of aluminate copper ferrite
Ribeiro, Vander Alkmin dos Santos
Ferritas
Propriedades magnéticas
Condutividade elétrica
Energia de ativação.
Ferrites
Magnetic properties
Electric conductivity
Activation energy.
Ferritas
Propiedades magnéticas
Conductividad eléctrica
Energía de activación.
title_short Synthesis, characterization magnetic and electrical of aluminate copper ferrite
title_full Synthesis, characterization magnetic and electrical of aluminate copper ferrite
title_fullStr Synthesis, characterization magnetic and electrical of aluminate copper ferrite
title_full_unstemmed Synthesis, characterization magnetic and electrical of aluminate copper ferrite
title_sort Synthesis, characterization magnetic and electrical of aluminate copper ferrite
author Ribeiro, Vander Alkmin dos Santos
author_facet Ribeiro, Vander Alkmin dos Santos
Oliveira, Valesca Donizete de
Rubinger, Rero Marques
Oliveira, Adhimar Flávio
Mendonça, Claudiney Sales Pereira
author_role author
author2 Oliveira, Valesca Donizete de
Rubinger, Rero Marques
Oliveira, Adhimar Flávio
Mendonça, Claudiney Sales Pereira
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Ribeiro, Vander Alkmin dos Santos
Oliveira, Valesca Donizete de
Rubinger, Rero Marques
Oliveira, Adhimar Flávio
Mendonça, Claudiney Sales Pereira
dc.subject.por.fl_str_mv Ferritas
Propriedades magnéticas
Condutividade elétrica
Energia de ativação.
Ferrites
Magnetic properties
Electric conductivity
Activation energy.
Ferritas
Propiedades magnéticas
Conductividad eléctrica
Energía de activación.
topic Ferritas
Propriedades magnéticas
Condutividade elétrica
Energia de ativação.
Ferrites
Magnetic properties
Electric conductivity
Activation energy.
Ferritas
Propiedades magnéticas
Conductividad eléctrica
Energía de activación.
description Currently, ferrites have been the subject of much research due to their advantages and properties that can be easily manipulated, thus being of great technological and scientific interest. Therefore, the distribution of cations and magnetic interactions highlight an important role in these materials and, therefore, have their scientific importance. The relationships between chemical composition, crystal structure, magnetic and electrical behavior were investigated in copper aluminum ferrites. The CuAlXFe2-XO4 ferrites, where x = 0.0; 0.5; 1.0, and 1.5 were obtained by the conventional ceramic method, the solid-state reaction between iron, aluminum, and copper oxides. The oxide mixture was pre-sintered for 24 hours at 800°C and then sintered at 1100°C for 8 hours. The magnetic properties were measured by a vibrating sample magnetometer and determined from the hysteresis graph, noting that it has a moderate magnetic material behavior due to the magnetization curve profile and coercivity values ​​(~223kA/m). The electrical conductivity of the pellets was obtained from voltage-by-current characteristics as a function of temperature. The electrical conductivity of the pellets was obtained from voltage-by-current characteristics as a function of temperature. The dependence of electrical conductivity with the temperature of copper aluminate ferrites with different compositions presented a semiconductor behavior and with the increase of the material resistivity with the increase of the aluminum content, it occurs due to its conductive property. It was also observed that the saturation magnetization decreases with increasing aluminum concentration, showing the behavior of a soft paramagnetic material.
publishDate 2021
dc.date.none.fl_str_mv 2021-07-13
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://rsdjournal.org/index.php/rsd/article/view/17314
10.33448/rsd-v10i8.17314
url https://rsdjournal.org/index.php/rsd/article/view/17314
identifier_str_mv 10.33448/rsd-v10i8.17314
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv https://rsdjournal.org/index.php/rsd/article/view/17314/15526
dc.rights.driver.fl_str_mv https://creativecommons.org/licenses/by/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Research, Society and Development
publisher.none.fl_str_mv Research, Society and Development
dc.source.none.fl_str_mv Research, Society and Development; Vol. 10 No. 8; e31210817314
Research, Society and Development; Vol. 10 Núm. 8; e31210817314
Research, Society and Development; v. 10 n. 8; e31210817314
2525-3409
reponame:Research, Society and Development
instname:Universidade Federal de Itajubá (UNIFEI)
instacron:UNIFEI
instname_str Universidade Federal de Itajubá (UNIFEI)
instacron_str UNIFEI
institution UNIFEI
reponame_str Research, Society and Development
collection Research, Society and Development
repository.name.fl_str_mv Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)
repository.mail.fl_str_mv rsd.articles@gmail.com
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