PRODUCTION OF BIODIESEL FROM HYDROSTERIFICATION REACTION

Detalhes bibliográficos
Autor(a) principal: de Mello, Bruna Tais Ferreira
Data de Publicação: 2020
Outros Autores: Filho, Lúcio Cardoso, da Silva, Camila
Tipo de documento: Artigo
Idioma: por
Título da fonte: UNINGÁ Review
Texto Completo: https://revista.uninga.br/uningareviews/article/view/3522
Resumo: Fatty acid esters (Biodiesel) are commonly produced by homogeneous basic catalytic transesterification reaction, whose sensitivity to the presence of water and free fatty acids (FFAs) in the raw material is one of the main drawbacks. The search for production processes that allow the use of vegetable oils with less added value is of interest to the biofuel industry. A promising alternative is hydroesterification, whose first stage is the hydrolysis of triacylglycerols, producing FFAs and glycerol products. Therefore, instead of decreasing acidity of the raw material through refining, the hydrolysis stage purposely increases its acidity. Then, glycerol is removed and the FFAs are subjected to an esterification reaction to produce fatty acid esters and water as a by-product. Therefore, this work presents a literature review, which has as main focus the production of biodiesel from hydroesterification. Alternative raw materials with potential in the current market are also presented. It was possible to verify that hydroesterification offers advantages when compared to conventional reactions. When carried out under conditions of high temperature and pressure, it can reduce the difficulties associated with the use of catalysts, becoming a promising alternative to be used as a method of biodiesel production.
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spelling PRODUCTION OF BIODIESEL FROM HYDROSTERIFICATION REACTIONPRODUÇÃO DE BIODIESEL A PARTIR DA REAÇÃO DE HIDROESTERIFICAÇÃOÁcidos graxos livresBiodiselEsterificaçãoHidróliseBiodieselEsterificationFree fatty acidsHydrolysisFatty acid esters (Biodiesel) are commonly produced by homogeneous basic catalytic transesterification reaction, whose sensitivity to the presence of water and free fatty acids (FFAs) in the raw material is one of the main drawbacks. The search for production processes that allow the use of vegetable oils with less added value is of interest to the biofuel industry. A promising alternative is hydroesterification, whose first stage is the hydrolysis of triacylglycerols, producing FFAs and glycerol products. Therefore, instead of decreasing acidity of the raw material through refining, the hydrolysis stage purposely increases its acidity. Then, glycerol is removed and the FFAs are subjected to an esterification reaction to produce fatty acid esters and water as a by-product. Therefore, this work presents a literature review, which has as main focus the production of biodiesel from hydroesterification. Alternative raw materials with potential in the current market are also presented. It was possible to verify that hydroesterification offers advantages when compared to conventional reactions. When carried out under conditions of high temperature and pressure, it can reduce the difficulties associated with the use of catalysts, becoming a promising alternative to be used as a method of biodiesel production.Ésteres de ácidos graxos (Biodiesel) são comumente produzidos pela reação de transesterificação catalítica básica homogênea, cuja sensibilidade à presença de água e ácidos graxos livres (AGLs) na matéria-prima é um dos principais inconvenientes. A busca por processos de produção que permitem o uso de óleos vegetais com menor valor agregado é de interesse da indústria do biocombustível. Uma alternativa promissora é a hidroesterificação, cuja primeira etapa é a hidrólise de triacilgliceróis produzindo AGLs e glicerol, portanto, ao invés de diminuir a acidez da matéria-prima por meio do refino, a etapa de hidrólise aumenta propositalmente a sua acidez. Em seguida, o glicerol é removido e os AGLs são submetidos à reação de esterificação para produção dos ésteres de ácidos graxos e água como subproduto. Diante disso, neste trabalho é apresentada a revisão da literatura, com enfoque principal na produção de biodiesel a partir da hidroesterificação, bem como as matérias‑primas alternativas com potencial no mercado atual. Foi possível constatar que a hidroesterificação apresenta diversas vantagens em relação à reação convencional. Se realizada em condições de alta temperatura e pressão, pode reduzir as dificuldades associadas ao uso de catalisadores, tornando-se uma alternativa promissora a ser empregada como método de produção do biodiesel.Editora Uningá2020-08-31info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://revista.uninga.br/uningareviews/article/view/3522Uningá Review ; Vol. 35 (2020); eRUR3522Uningá Review ; v. 35 (2020); eRUR35222178-2571reponame:UNINGÁ Reviewinstname:Centro Universitário Uningáinstacron:UNINGAporhttps://revista.uninga.br/uningareviews/article/view/3522/2214Copyright (c) 2020 REVISTA UNINGÁ REVIEWinfo:eu-repo/semantics/openAccessde Mello, Bruna Tais FerreiraFilho, Lúcio Cardosoda Silva, Camila2023-10-17T15:05:53Zoai:ojs.revista.uninga.br:article/3522Revistahttps://revista.uninga.br/uningareviews/indexPUBhttps://revista.uninga.br/uningareviews/oairevistauningareview@uninga.edu.br || sec.revistas@uninga.edu.br2178-25712178-2571opendoar:2023-10-17T15:05:53UNINGÁ Review - Centro Universitário Uningáfalse
dc.title.none.fl_str_mv PRODUCTION OF BIODIESEL FROM HYDROSTERIFICATION REACTION
PRODUÇÃO DE BIODIESEL A PARTIR DA REAÇÃO DE HIDROESTERIFICAÇÃO
title PRODUCTION OF BIODIESEL FROM HYDROSTERIFICATION REACTION
spellingShingle PRODUCTION OF BIODIESEL FROM HYDROSTERIFICATION REACTION
de Mello, Bruna Tais Ferreira
Ácidos graxos livres
Biodisel
Esterificação
Hidrólise
Biodiesel
Esterification
Free fatty acids
Hydrolysis
title_short PRODUCTION OF BIODIESEL FROM HYDROSTERIFICATION REACTION
title_full PRODUCTION OF BIODIESEL FROM HYDROSTERIFICATION REACTION
title_fullStr PRODUCTION OF BIODIESEL FROM HYDROSTERIFICATION REACTION
title_full_unstemmed PRODUCTION OF BIODIESEL FROM HYDROSTERIFICATION REACTION
title_sort PRODUCTION OF BIODIESEL FROM HYDROSTERIFICATION REACTION
author de Mello, Bruna Tais Ferreira
author_facet de Mello, Bruna Tais Ferreira
Filho, Lúcio Cardoso
da Silva, Camila
author_role author
author2 Filho, Lúcio Cardoso
da Silva, Camila
author2_role author
author
dc.contributor.author.fl_str_mv de Mello, Bruna Tais Ferreira
Filho, Lúcio Cardoso
da Silva, Camila
dc.subject.por.fl_str_mv Ácidos graxos livres
Biodisel
Esterificação
Hidrólise
Biodiesel
Esterification
Free fatty acids
Hydrolysis
topic Ácidos graxos livres
Biodisel
Esterificação
Hidrólise
Biodiesel
Esterification
Free fatty acids
Hydrolysis
description Fatty acid esters (Biodiesel) are commonly produced by homogeneous basic catalytic transesterification reaction, whose sensitivity to the presence of water and free fatty acids (FFAs) in the raw material is one of the main drawbacks. The search for production processes that allow the use of vegetable oils with less added value is of interest to the biofuel industry. A promising alternative is hydroesterification, whose first stage is the hydrolysis of triacylglycerols, producing FFAs and glycerol products. Therefore, instead of decreasing acidity of the raw material through refining, the hydrolysis stage purposely increases its acidity. Then, glycerol is removed and the FFAs are subjected to an esterification reaction to produce fatty acid esters and water as a by-product. Therefore, this work presents a literature review, which has as main focus the production of biodiesel from hydroesterification. Alternative raw materials with potential in the current market are also presented. It was possible to verify that hydroesterification offers advantages when compared to conventional reactions. When carried out under conditions of high temperature and pressure, it can reduce the difficulties associated with the use of catalysts, becoming a promising alternative to be used as a method of biodiesel production.
publishDate 2020
dc.date.none.fl_str_mv 2020-08-31
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://revista.uninga.br/uningareviews/article/view/3522
url https://revista.uninga.br/uningareviews/article/view/3522
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv https://revista.uninga.br/uningareviews/article/view/3522/2214
dc.rights.driver.fl_str_mv Copyright (c) 2020 REVISTA UNINGÁ REVIEW
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Copyright (c) 2020 REVISTA UNINGÁ REVIEW
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Editora Uningá
publisher.none.fl_str_mv Editora Uningá
dc.source.none.fl_str_mv Uningá Review ; Vol. 35 (2020); eRUR3522
Uningá Review ; v. 35 (2020); eRUR3522
2178-2571
reponame:UNINGÁ Review
instname:Centro Universitário Uningá
instacron:UNINGA
instname_str Centro Universitário Uningá
instacron_str UNINGA
institution UNINGA
reponame_str UNINGÁ Review
collection UNINGÁ Review
repository.name.fl_str_mv UNINGÁ Review - Centro Universitário Uningá
repository.mail.fl_str_mv revistauningareview@uninga.edu.br || sec.revistas@uninga.edu.br
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