Casting and inkjet printable photochromic films based on polymethylmethacrylate – Phosphotungstic acid

Detalhes bibliográficos
Autor(a) principal: Espindola, A.
Data de Publicação: 2019
Outros Autores: Gonçalves, N. S., Nalin, M. [UNESP], Ribeiro, S. J.L. [UNESP], Barud, H. S., Molina, C.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1016/j.optmat.2019.109345
http://hdl.handle.net/11449/188008
Resumo: The incorporation of polyoxometalates in suitable matrices has been a main effort to produce transparent photochromic materials. Polymeric films based on high transparent polymethylmethacrylate (PMMA) containing phosphotungstic acid (PWA) have been obtained by casting and also by inkjet printing. In this investigation, polymeric PMMA matrix containing PWA were developed in an appropriate ratio of CH2Cl2/THF solvents to provide suitable transparent solution. PMMA/PWA composites obtained by casting were characterized by IR-ATR, Raman, XRD, TG/DTG, UV–Vis. Inkjet printing solution were characterized by surface tension (ST), viscosity and contact angle (CA) on glass substrate and films by optical microscopy. Infrared-ATR and Raman spectroscopies showed that the polyoxometalate structure was preserved in the polymeric matrix and the interaction between them occurred due to electrostatic forces. XRD indicated that PMMA and photochromic films were amorphous and display thermal stability up to 300 °C. Upon the UV irradiation, transparent films become blue and the photobleaching process were performed as a function of the temperature in a presence of air. These high transparent and photosensitive photochromic films present potential application as coating by casting and miniatured devices by inkjet printing.
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spelling Casting and inkjet printable photochromic films based on polymethylmethacrylate – Phosphotungstic acidCastingInkjet printingPhosphotungstic acidPhotochromicPolymethylmethacrylateThe incorporation of polyoxometalates in suitable matrices has been a main effort to produce transparent photochromic materials. Polymeric films based on high transparent polymethylmethacrylate (PMMA) containing phosphotungstic acid (PWA) have been obtained by casting and also by inkjet printing. In this investigation, polymeric PMMA matrix containing PWA were developed in an appropriate ratio of CH2Cl2/THF solvents to provide suitable transparent solution. PMMA/PWA composites obtained by casting were characterized by IR-ATR, Raman, XRD, TG/DTG, UV–Vis. Inkjet printing solution were characterized by surface tension (ST), viscosity and contact angle (CA) on glass substrate and films by optical microscopy. Infrared-ATR and Raman spectroscopies showed that the polyoxometalate structure was preserved in the polymeric matrix and the interaction between them occurred due to electrostatic forces. XRD indicated that PMMA and photochromic films were amorphous and display thermal stability up to 300 °C. Upon the UV irradiation, transparent films become blue and the photobleaching process were performed as a function of the temperature in a presence of air. These high transparent and photosensitive photochromic films present potential application as coating by casting and miniatured devices by inkjet printing.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Deparment of Chemistry Federal University of São Paulo (UNIFESP)Chemistry Institute São Paulo State University - UNESP AraraquaraUniversity of Araraquara – UniaraChemistry Institute São Paulo State University - UNESP AraraquaraFAPESP: 2012/02708-8FAPESP: 2013/07793-6Universidade de São Paulo (USP)Universidade Estadual Paulista (Unesp)University of Araraquara – UniaraEspindola, A.Gonçalves, N. S.Nalin, M. [UNESP]Ribeiro, S. J.L. [UNESP]Barud, H. S.Molina, C.2019-10-06T15:54:15Z2019-10-06T15:54:15Z2019-10-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1016/j.optmat.2019.109345Optical Materials, v. 96.0925-3467http://hdl.handle.net/11449/18800810.1016/j.optmat.2019.1093452-s2.0-85071240916Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengOptical Materialsinfo:eu-repo/semantics/openAccess2021-10-23T12:24:09Zoai:repositorio.unesp.br:11449/188008Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462021-10-23T12:24:09Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Casting and inkjet printable photochromic films based on polymethylmethacrylate – Phosphotungstic acid
title Casting and inkjet printable photochromic films based on polymethylmethacrylate – Phosphotungstic acid
spellingShingle Casting and inkjet printable photochromic films based on polymethylmethacrylate – Phosphotungstic acid
Espindola, A.
Casting
Inkjet printing
Phosphotungstic acid
Photochromic
Polymethylmethacrylate
title_short Casting and inkjet printable photochromic films based on polymethylmethacrylate – Phosphotungstic acid
title_full Casting and inkjet printable photochromic films based on polymethylmethacrylate – Phosphotungstic acid
title_fullStr Casting and inkjet printable photochromic films based on polymethylmethacrylate – Phosphotungstic acid
title_full_unstemmed Casting and inkjet printable photochromic films based on polymethylmethacrylate – Phosphotungstic acid
title_sort Casting and inkjet printable photochromic films based on polymethylmethacrylate – Phosphotungstic acid
author Espindola, A.
author_facet Espindola, A.
Gonçalves, N. S.
Nalin, M. [UNESP]
Ribeiro, S. J.L. [UNESP]
Barud, H. S.
Molina, C.
author_role author
author2 Gonçalves, N. S.
Nalin, M. [UNESP]
Ribeiro, S. J.L. [UNESP]
Barud, H. S.
Molina, C.
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade de São Paulo (USP)
Universidade Estadual Paulista (Unesp)
University of Araraquara – Uniara
dc.contributor.author.fl_str_mv Espindola, A.
Gonçalves, N. S.
Nalin, M. [UNESP]
Ribeiro, S. J.L. [UNESP]
Barud, H. S.
Molina, C.
dc.subject.por.fl_str_mv Casting
Inkjet printing
Phosphotungstic acid
Photochromic
Polymethylmethacrylate
topic Casting
Inkjet printing
Phosphotungstic acid
Photochromic
Polymethylmethacrylate
description The incorporation of polyoxometalates in suitable matrices has been a main effort to produce transparent photochromic materials. Polymeric films based on high transparent polymethylmethacrylate (PMMA) containing phosphotungstic acid (PWA) have been obtained by casting and also by inkjet printing. In this investigation, polymeric PMMA matrix containing PWA were developed in an appropriate ratio of CH2Cl2/THF solvents to provide suitable transparent solution. PMMA/PWA composites obtained by casting were characterized by IR-ATR, Raman, XRD, TG/DTG, UV–Vis. Inkjet printing solution were characterized by surface tension (ST), viscosity and contact angle (CA) on glass substrate and films by optical microscopy. Infrared-ATR and Raman spectroscopies showed that the polyoxometalate structure was preserved in the polymeric matrix and the interaction between them occurred due to electrostatic forces. XRD indicated that PMMA and photochromic films were amorphous and display thermal stability up to 300 °C. Upon the UV irradiation, transparent films become blue and the photobleaching process were performed as a function of the temperature in a presence of air. These high transparent and photosensitive photochromic films present potential application as coating by casting and miniatured devices by inkjet printing.
publishDate 2019
dc.date.none.fl_str_mv 2019-10-06T15:54:15Z
2019-10-06T15:54:15Z
2019-10-01
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1016/j.optmat.2019.109345
Optical Materials, v. 96.
0925-3467
http://hdl.handle.net/11449/188008
10.1016/j.optmat.2019.109345
2-s2.0-85071240916
url http://dx.doi.org/10.1016/j.optmat.2019.109345
http://hdl.handle.net/11449/188008
identifier_str_mv Optical Materials, v. 96.
0925-3467
10.1016/j.optmat.2019.109345
2-s2.0-85071240916
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Optical Materials
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
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