Molecular and crystal structure of Di(μ-N,S-thiocyanato)-bis[(N,N-dimethylbenzylamine-C2, N)palladium(II)]

Detalhes bibliográficos
Autor(a) principal: Mauro, Antonio Eduardo [UNESP]
Data de Publicação: 2009
Outros Autores: Netto, Adelino V.G. [UNESP], Moro, Antonio C. [UNESP], Ferreira, Janaina G. [UNESP], Santos, Regina H.A., de Almeida, Eduardo T.
Tipo de documento: Outros
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.2116/xraystruct.25.65
http://hdl.handle.net/11449/70994
Resumo: The cyclopalladated complex [Pd(C2,N-dmba)(μ-SCN)]2, where dmba = N,N-dimethylbenzylamine, was structurally characterized by single-crystal X-ray diffraction. This compound crystallizes in the monoclinic system, space group P21/n with a = 9.578(1)Å, b = 12.323(2)Å, c = 10.279(2)Å, β = 117.03(1)°, V = 1080.7(3)Å3, Z = 2. Each Pd(II) center displays a distorted square-planar coordination environment, formed by the C and N atoms from the dmba ligand, and one set of N and S atoms from the bridging SCN groups. 2009 © The Japan Society for Analytical Chemistry.
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spelling Molecular and crystal structure of Di(μ-N,S-thiocyanato)-bis[(N,N-dimethylbenzylamine-C2, N)palladium(II)]The cyclopalladated complex [Pd(C2,N-dmba)(μ-SCN)]2, where dmba = N,N-dimethylbenzylamine, was structurally characterized by single-crystal X-ray diffraction. This compound crystallizes in the monoclinic system, space group P21/n with a = 9.578(1)Å, b = 12.323(2)Å, c = 10.279(2)Å, β = 117.03(1)°, V = 1080.7(3)Å3, Z = 2. Each Pd(II) center displays a distorted square-planar coordination environment, formed by the C and N atoms from the dmba ligand, and one set of N and S atoms from the bridging SCN groups. 2009 © The Japan Society for Analytical Chemistry.Departamento de Química Geral e Inorgânica Instituto de Química de Araraquara-UNESP, C. P. 355, CEP 14801-970, Araraquara, S. P.Departamento de Química e Física Molecular Instituto de Química-USP, C. P. 780, CEP 13560-970, São Carlos, S. P.Departamento de Ciências Exatas-UNIFAL, CEP 37130-000, Alfenas, M. G.Departamento de Química Geral e Inorgânica Instituto de Química de Araraquara-UNESP, C. P. 355, CEP 14801-970, Araraquara, S. P.Universidade Estadual Paulista (Unesp)Universidade de São Paulo (USP)Mauro, Antonio Eduardo [UNESP]Netto, Adelino V.G. [UNESP]Moro, Antonio C. [UNESP]Ferreira, Janaina G. [UNESP]Santos, Regina H.A.de Almeida, Eduardo T.2014-05-27T11:23:54Z2014-05-27T11:23:54Z2009-05-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/other65-66application/pdfhttp://dx.doi.org/10.2116/xraystruct.25.65X-ray Structure Analysis Online, v. 25, n. 5, p. 65-66, 2009.1883-3578http://hdl.handle.net/11449/7099410.2116/xraystruct.25.652-s2.0-732491230482-s2.0-73249123048.pdf330022397081444879276770536508190000-0002-0057-7964Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengX-ray Structure Analysis Online0,175info:eu-repo/semantics/openAccess2024-12-04T13:01:34Zoai:repositorio.unesp.br:11449/70994Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestrepositoriounesp@unesp.bropendoar:29462024-12-04T13:01:34Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Molecular and crystal structure of Di(μ-N,S-thiocyanato)-bis[(N,N-dimethylbenzylamine-C2, N)palladium(II)]
title Molecular and crystal structure of Di(μ-N,S-thiocyanato)-bis[(N,N-dimethylbenzylamine-C2, N)palladium(II)]
spellingShingle Molecular and crystal structure of Di(μ-N,S-thiocyanato)-bis[(N,N-dimethylbenzylamine-C2, N)palladium(II)]
Mauro, Antonio Eduardo [UNESP]
title_short Molecular and crystal structure of Di(μ-N,S-thiocyanato)-bis[(N,N-dimethylbenzylamine-C2, N)palladium(II)]
title_full Molecular and crystal structure of Di(μ-N,S-thiocyanato)-bis[(N,N-dimethylbenzylamine-C2, N)palladium(II)]
title_fullStr Molecular and crystal structure of Di(μ-N,S-thiocyanato)-bis[(N,N-dimethylbenzylamine-C2, N)palladium(II)]
title_full_unstemmed Molecular and crystal structure of Di(μ-N,S-thiocyanato)-bis[(N,N-dimethylbenzylamine-C2, N)palladium(II)]
title_sort Molecular and crystal structure of Di(μ-N,S-thiocyanato)-bis[(N,N-dimethylbenzylamine-C2, N)palladium(II)]
author Mauro, Antonio Eduardo [UNESP]
author_facet Mauro, Antonio Eduardo [UNESP]
Netto, Adelino V.G. [UNESP]
Moro, Antonio C. [UNESP]
Ferreira, Janaina G. [UNESP]
Santos, Regina H.A.
de Almeida, Eduardo T.
author_role author
author2 Netto, Adelino V.G. [UNESP]
Moro, Antonio C. [UNESP]
Ferreira, Janaina G. [UNESP]
Santos, Regina H.A.
de Almeida, Eduardo T.
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (Unesp)
Universidade de São Paulo (USP)
dc.contributor.author.fl_str_mv Mauro, Antonio Eduardo [UNESP]
Netto, Adelino V.G. [UNESP]
Moro, Antonio C. [UNESP]
Ferreira, Janaina G. [UNESP]
Santos, Regina H.A.
de Almeida, Eduardo T.
description The cyclopalladated complex [Pd(C2,N-dmba)(μ-SCN)]2, where dmba = N,N-dimethylbenzylamine, was structurally characterized by single-crystal X-ray diffraction. This compound crystallizes in the monoclinic system, space group P21/n with a = 9.578(1)Å, b = 12.323(2)Å, c = 10.279(2)Å, β = 117.03(1)°, V = 1080.7(3)Å3, Z = 2. Each Pd(II) center displays a distorted square-planar coordination environment, formed by the C and N atoms from the dmba ligand, and one set of N and S atoms from the bridging SCN groups. 2009 © The Japan Society for Analytical Chemistry.
publishDate 2009
dc.date.none.fl_str_mv 2009-05-01
2014-05-27T11:23:54Z
2014-05-27T11:23:54Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/other
format other
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.2116/xraystruct.25.65
X-ray Structure Analysis Online, v. 25, n. 5, p. 65-66, 2009.
1883-3578
http://hdl.handle.net/11449/70994
10.2116/xraystruct.25.65
2-s2.0-73249123048
2-s2.0-73249123048.pdf
3300223970814448
7927677053650819
0000-0002-0057-7964
url http://dx.doi.org/10.2116/xraystruct.25.65
http://hdl.handle.net/11449/70994
identifier_str_mv X-ray Structure Analysis Online, v. 25, n. 5, p. 65-66, 2009.
1883-3578
10.2116/xraystruct.25.65
2-s2.0-73249123048
2-s2.0-73249123048.pdf
3300223970814448
7927677053650819
0000-0002-0057-7964
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv X-ray Structure Analysis Online
0,175
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 65-66
application/pdf
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv repositoriounesp@unesp.br
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