Fabricação e caracterização de cerâmicas multifuncionais à base de CaSr3Cu3-xTi4O12 para aplicações ópticas e eletro-eletrônicas

• Autor(a) principal: Orrego Gonzalez, Santiago [UNESP]
• Data de Publicação: 2015
• Tipo de documento: Dissertação
• Idioma: por
• Título da fonte: Repositório Institucional da UNESP
• Texto Completo: http://hdl.handle.net/11449/126642; http://www.athena.biblioteca.unesp.br/exlibris/bd/cathedra/18-08-2015/000844670.pdf
• topic: Fotoluminescencia; Material cerâmico; Termogravimetria; Raios X - Difração; Photoluminescence

Ceramics of CaCu3Ti4O12 (CCTO) areof scientific interest due to their multi functionality. In this work, ceramic powders of CaSrCu3-xTi4O12 with x=0,00, 0,15, 0,30, 1,50, 2,70 and 3,00 were prepared. These powders were thermally characterized by the thermogravimetry technique, was concluded the need use of two calcination temperatures, 950ºC for samples with low content of Sr2+ and 1050ºC for those with high content. To the sample in powder structural characterization was realized with the DRX technique that reveals the presence of pure phase of CCTO for x = 0,00, the sample of x = 0,15 present the phase of CCTO and the phase of CaTiO3, which ones are present too in the sample of x = 0,30 combined with the phase of (Sr0,75Ca0,25)TiO3(SCTO). The samples of x = 1,50 and 2,70 show the CCTO phase the SCTO phase and finally the sample of x = 3,00 show the pure phase of SCTO. Also was made a study by Raman spectroscopy techique indicates the presence of characteristic modes of the CCTO phase in all the samples, this because the SCTO phase also show this type of vibrational modes in the [TiO6] cluster. Finally the optical and photoluminescent properties were characterized, by the UV-vis technique was determined the energy gap values, the samples of x = 0,00, 0,15, 0,30 show gap values of 2,03, 2,28 and 2,35 eV respectively. Meanwhile each of the samples of x = 1,50 e 2,70 show two energy gaps, on at 2,12 and the other at the 3,16 eV; finally the sample of x = 3,00 present a unique energy gap of 3.33 eV. The photoluminescent property present an improvement compared with the pure phase of CCTO for samples with x = 2,70 and 3,00, this is probably due t the presence of oxygen vacancies in the [ToO6] clusters. To the other samples, this property was negatively affected by the substitution of Cu2+ by Sr2+. This characterizations were newly made by using a single calcination temperature, 1050ºC, reducing the number of variables that influence in the...