DEA and DSC study of cubic silsesquioxane epoxy resin nanocomposites

Detalhes bibliográficos
Autor(a) principal: Filho, Newton Luiz Dias [UNESP]
Data de Publicação: 2006
Outros Autores: De Aquino, Hermes Adolfo [UNESP]
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://hdl.handle.net/11449/224749
Resumo: Non-isothermal dielectric analysis (DEA) and differential scanning calorimetry (DSC) techniques were used to study the epoxy nanocomposites prepared by reacting 1,3,5,7,9,11,13,15-octa[dimethylsiloxypropylglycidylether] pentaciclo [9.5.1.13,9.15'15.17,13] octasilsesquioxane (ODPG) with methylenedianiline (MDA). Loss factor (ε) and activation energy were calculated by DEA. The relationships between the loss factor, the activation energy, the structure of the network, and the mechanical properties were investigated. Activation energies determined by DEA and DSC, heat of polymerization, fracture toughness and tensile modulus show the same profile for mechanical properties with respect to ODPG content.
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spelling DEA and DSC study of cubic silsesquioxane epoxy resin nanocompositesNon-isothermal dielectric analysis (DEA) and differential scanning calorimetry (DSC) techniques were used to study the epoxy nanocomposites prepared by reacting 1,3,5,7,9,11,13,15-octa[dimethylsiloxypropylglycidylether] pentaciclo [9.5.1.13,9.15'15.17,13] octasilsesquioxane (ODPG) with methylenedianiline (MDA). Loss factor (ε) and activation energy were calculated by DEA. The relationships between the loss factor, the activation energy, the structure of the network, and the mechanical properties were investigated. Activation energies determined by DEA and DSC, heat of polymerization, fracture toughness and tensile modulus show the same profile for mechanical properties with respect to ODPG content.Departamento de Física e Química UNESP-Universidade Estadual Paulista, Caixa Postal 31, 15385-000 Ilha Solteira- SPDepartamento de Física e Química UNESP-Universidade Estadual Paulista, Caixa Postal 31, 15385-000 Ilha Solteira- SPUniversidade Estadual Paulista (UNESP)Filho, Newton Luiz Dias [UNESP]De Aquino, Hermes Adolfo [UNESP]2022-04-28T20:07:42Z2022-04-28T20:07:42Z2006-04-28info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article1-18E-Polymers, p. 1-18.1618-7229http://hdl.handle.net/11449/2247492-s2.0-33646360802Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengE-Polymersinfo:eu-repo/semantics/openAccess2024-07-10T14:07:57Zoai:repositorio.unesp.br:11449/224749Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T20:34:41.558173Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv DEA and DSC study of cubic silsesquioxane epoxy resin nanocomposites
title DEA and DSC study of cubic silsesquioxane epoxy resin nanocomposites
spellingShingle DEA and DSC study of cubic silsesquioxane epoxy resin nanocomposites
Filho, Newton Luiz Dias [UNESP]
title_short DEA and DSC study of cubic silsesquioxane epoxy resin nanocomposites
title_full DEA and DSC study of cubic silsesquioxane epoxy resin nanocomposites
title_fullStr DEA and DSC study of cubic silsesquioxane epoxy resin nanocomposites
title_full_unstemmed DEA and DSC study of cubic silsesquioxane epoxy resin nanocomposites
title_sort DEA and DSC study of cubic silsesquioxane epoxy resin nanocomposites
author Filho, Newton Luiz Dias [UNESP]
author_facet Filho, Newton Luiz Dias [UNESP]
De Aquino, Hermes Adolfo [UNESP]
author_role author
author2 De Aquino, Hermes Adolfo [UNESP]
author2_role author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (UNESP)
dc.contributor.author.fl_str_mv Filho, Newton Luiz Dias [UNESP]
De Aquino, Hermes Adolfo [UNESP]
description Non-isothermal dielectric analysis (DEA) and differential scanning calorimetry (DSC) techniques were used to study the epoxy nanocomposites prepared by reacting 1,3,5,7,9,11,13,15-octa[dimethylsiloxypropylglycidylether] pentaciclo [9.5.1.13,9.15'15.17,13] octasilsesquioxane (ODPG) with methylenedianiline (MDA). Loss factor (ε) and activation energy were calculated by DEA. The relationships between the loss factor, the activation energy, the structure of the network, and the mechanical properties were investigated. Activation energies determined by DEA and DSC, heat of polymerization, fracture toughness and tensile modulus show the same profile for mechanical properties with respect to ODPG content.
publishDate 2006
dc.date.none.fl_str_mv 2006-04-28
2022-04-28T20:07:42Z
2022-04-28T20:07:42Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv E-Polymers, p. 1-18.
1618-7229
http://hdl.handle.net/11449/224749
2-s2.0-33646360802
identifier_str_mv E-Polymers, p. 1-18.
1618-7229
2-s2.0-33646360802
url http://hdl.handle.net/11449/224749
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv E-Polymers
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 1-18
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1808129223034929152

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