Electrochemical stability of binary TiNb for biomedical applications

Detalhes bibliográficos
Autor(a) principal: Reyes, K. M.
Data de Publicação: 2017
Outros Autores: Kuromoto, N. K., Alves Claro, A. P.R. [UNESP], Marino, C. E.B.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1088/2053-1591/aa6ee4
http://hdl.handle.net/11449/175028
Resumo: The Ti-Nb alloy binary system has been widely studied with regard to biomedical applications due to the high biocompatibility and excellent mechanical properties of the alloys. Regarding physicalchemical stability, Ti-Nb alloys maintain the properties of Ti metal, which is highly resistant to corrosion in aggressive media due to a spontaneous stable oxide layer (TiO2) formed on its surface. The objective of this study was to evaluate the corrosion resistance of the Ti-40Nb alloy in artificial blood. The thermodynamic stability was studied using the open circuit potential technique and the corrosion resistance was assessed by potentiodynamic measurements and electrochemical impedance spectroscopy. The electrochemical results indicated that the Ti-40Nb alloy has high corrosion resistance and good thermodynamic stability, with an OCP of around -485 mV, and the alloy remained electrochemically stable in potentiodynamic conditions with initial and final potentials of -1.0 V to +2.0 Vsce, respectively, in low current densities (∼μA cm-2) with an absence of hysteresis, aspure Ti. The results obtained showed that this specific alloy has the potential to be used in biomedical applications.
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spelling Electrochemical stability of binary TiNb for biomedical applicationsCorrosion resistanceElectrochemical stabilityTi-Nb alloysThe Ti-Nb alloy binary system has been widely studied with regard to biomedical applications due to the high biocompatibility and excellent mechanical properties of the alloys. Regarding physicalchemical stability, Ti-Nb alloys maintain the properties of Ti metal, which is highly resistant to corrosion in aggressive media due to a spontaneous stable oxide layer (TiO2) formed on its surface. The objective of this study was to evaluate the corrosion resistance of the Ti-40Nb alloy in artificial blood. The thermodynamic stability was studied using the open circuit potential technique and the corrosion resistance was assessed by potentiodynamic measurements and electrochemical impedance spectroscopy. The electrochemical results indicated that the Ti-40Nb alloy has high corrosion resistance and good thermodynamic stability, with an OCP of around -485 mV, and the alloy remained electrochemically stable in potentiodynamic conditions with initial and final potentials of -1.0 V to +2.0 Vsce, respectively, in low current densities (∼μA cm-2) with an absence of hysteresis, aspure Ti. The results obtained showed that this specific alloy has the potential to be used in biomedical applications.Laboratory of Biomaterials and Electrochemistry Federal University of Paraná UFPRPhysics Department Laboratory of Surface Mechanical Properties Federal University of Paraná UFPRUNESP School of Engineering Materials and Technology Department Guaratinguetá CampusDepartment of Mechanical Engineering Laboratory of Biomaterials and Electrochemistry Federal University of Paraná UFPRUNESP School of Engineering Materials and Technology Department Guaratinguetá CampusUniversidade Federal do Paraná (UFPR)Universidade Estadual Paulista (Unesp)Reyes, K. M.Kuromoto, N. K.Alves Claro, A. P.R. [UNESP]Marino, C. E.B.2018-12-11T17:13:54Z2018-12-11T17:13:54Z2017-07-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://dx.doi.org/10.1088/2053-1591/aa6ee4Materials Research Express, v. 4, n. 7, 2017.2053-1591http://hdl.handle.net/11449/17502810.1088/2053-1591/aa6ee42-s2.0-850271305152-s2.0-85027130515.pdfScopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengMaterials Research Express1,429info:eu-repo/semantics/openAccess2024-07-02T15:03:30Zoai:repositorio.unesp.br:11449/175028Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T14:12:15.290735Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Electrochemical stability of binary TiNb for biomedical applications
title Electrochemical stability of binary TiNb for biomedical applications
spellingShingle Electrochemical stability of binary TiNb for biomedical applications
Reyes, K. M.
Corrosion resistance
Electrochemical stability
Ti-Nb alloys
title_short Electrochemical stability of binary TiNb for biomedical applications
title_full Electrochemical stability of binary TiNb for biomedical applications
title_fullStr Electrochemical stability of binary TiNb for biomedical applications
title_full_unstemmed Electrochemical stability of binary TiNb for biomedical applications
title_sort Electrochemical stability of binary TiNb for biomedical applications
author Reyes, K. M.
author_facet Reyes, K. M.
Kuromoto, N. K.
Alves Claro, A. P.R. [UNESP]
Marino, C. E.B.
author_role author
author2 Kuromoto, N. K.
Alves Claro, A. P.R. [UNESP]
Marino, C. E.B.
author2_role author
author
author
dc.contributor.none.fl_str_mv Universidade Federal do Paraná (UFPR)
Universidade Estadual Paulista (Unesp)
dc.contributor.author.fl_str_mv Reyes, K. M.
Kuromoto, N. K.
Alves Claro, A. P.R. [UNESP]
Marino, C. E.B.
dc.subject.por.fl_str_mv Corrosion resistance
Electrochemical stability
Ti-Nb alloys
topic Corrosion resistance
Electrochemical stability
Ti-Nb alloys
description The Ti-Nb alloy binary system has been widely studied with regard to biomedical applications due to the high biocompatibility and excellent mechanical properties of the alloys. Regarding physicalchemical stability, Ti-Nb alloys maintain the properties of Ti metal, which is highly resistant to corrosion in aggressive media due to a spontaneous stable oxide layer (TiO2) formed on its surface. The objective of this study was to evaluate the corrosion resistance of the Ti-40Nb alloy in artificial blood. The thermodynamic stability was studied using the open circuit potential technique and the corrosion resistance was assessed by potentiodynamic measurements and electrochemical impedance spectroscopy. The electrochemical results indicated that the Ti-40Nb alloy has high corrosion resistance and good thermodynamic stability, with an OCP of around -485 mV, and the alloy remained electrochemically stable in potentiodynamic conditions with initial and final potentials of -1.0 V to +2.0 Vsce, respectively, in low current densities (∼μA cm-2) with an absence of hysteresis, aspure Ti. The results obtained showed that this specific alloy has the potential to be used in biomedical applications.
publishDate 2017
dc.date.none.fl_str_mv 2017-07-01
2018-12-11T17:13:54Z
2018-12-11T17:13:54Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1088/2053-1591/aa6ee4
Materials Research Express, v. 4, n. 7, 2017.
2053-1591
http://hdl.handle.net/11449/175028
10.1088/2053-1591/aa6ee4
2-s2.0-85027130515
2-s2.0-85027130515.pdf
url http://dx.doi.org/10.1088/2053-1591/aa6ee4
http://hdl.handle.net/11449/175028
identifier_str_mv Materials Research Express, v. 4, n. 7, 2017.
2053-1591
10.1088/2053-1591/aa6ee4
2-s2.0-85027130515
2-s2.0-85027130515.pdf
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Materials Research Express
1,429
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
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