Electrochemical stability of binary TiNb for biomedical applications
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1088/2053-1591/aa6ee4 http://hdl.handle.net/11449/175028 |
Resumo: | The Ti-Nb alloy binary system has been widely studied with regard to biomedical applications due to the high biocompatibility and excellent mechanical properties of the alloys. Regarding physicalchemical stability, Ti-Nb alloys maintain the properties of Ti metal, which is highly resistant to corrosion in aggressive media due to a spontaneous stable oxide layer (TiO2) formed on its surface. The objective of this study was to evaluate the corrosion resistance of the Ti-40Nb alloy in artificial blood. The thermodynamic stability was studied using the open circuit potential technique and the corrosion resistance was assessed by potentiodynamic measurements and electrochemical impedance spectroscopy. The electrochemical results indicated that the Ti-40Nb alloy has high corrosion resistance and good thermodynamic stability, with an OCP of around -485 mV, and the alloy remained electrochemically stable in potentiodynamic conditions with initial and final potentials of -1.0 V to +2.0 Vsce, respectively, in low current densities (∼μA cm-2) with an absence of hysteresis, aspure Ti. The results obtained showed that this specific alloy has the potential to be used in biomedical applications. |
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Electrochemical stability of binary TiNb for biomedical applicationsCorrosion resistanceElectrochemical stabilityTi-Nb alloysThe Ti-Nb alloy binary system has been widely studied with regard to biomedical applications due to the high biocompatibility and excellent mechanical properties of the alloys. Regarding physicalchemical stability, Ti-Nb alloys maintain the properties of Ti metal, which is highly resistant to corrosion in aggressive media due to a spontaneous stable oxide layer (TiO2) formed on its surface. The objective of this study was to evaluate the corrosion resistance of the Ti-40Nb alloy in artificial blood. The thermodynamic stability was studied using the open circuit potential technique and the corrosion resistance was assessed by potentiodynamic measurements and electrochemical impedance spectroscopy. The electrochemical results indicated that the Ti-40Nb alloy has high corrosion resistance and good thermodynamic stability, with an OCP of around -485 mV, and the alloy remained electrochemically stable in potentiodynamic conditions with initial and final potentials of -1.0 V to +2.0 Vsce, respectively, in low current densities (∼μA cm-2) with an absence of hysteresis, aspure Ti. The results obtained showed that this specific alloy has the potential to be used in biomedical applications.Laboratory of Biomaterials and Electrochemistry Federal University of Paraná UFPRPhysics Department Laboratory of Surface Mechanical Properties Federal University of Paraná UFPRUNESP School of Engineering Materials and Technology Department Guaratinguetá CampusDepartment of Mechanical Engineering Laboratory of Biomaterials and Electrochemistry Federal University of Paraná UFPRUNESP School of Engineering Materials and Technology Department Guaratinguetá CampusUniversidade Federal do Paraná (UFPR)Universidade Estadual Paulista (Unesp)Reyes, K. M.Kuromoto, N. K.Alves Claro, A. P.R. [UNESP]Marino, C. E.B.2018-12-11T17:13:54Z2018-12-11T17:13:54Z2017-07-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://dx.doi.org/10.1088/2053-1591/aa6ee4Materials Research Express, v. 4, n. 7, 2017.2053-1591http://hdl.handle.net/11449/17502810.1088/2053-1591/aa6ee42-s2.0-850271305152-s2.0-85027130515.pdfScopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengMaterials Research Express1,429info:eu-repo/semantics/openAccess2024-07-02T15:03:30Zoai:repositorio.unesp.br:11449/175028Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T14:12:15.290735Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Electrochemical stability of binary TiNb for biomedical applications |
title |
Electrochemical stability of binary TiNb for biomedical applications |
spellingShingle |
Electrochemical stability of binary TiNb for biomedical applications Reyes, K. M. Corrosion resistance Electrochemical stability Ti-Nb alloys |
title_short |
Electrochemical stability of binary TiNb for biomedical applications |
title_full |
Electrochemical stability of binary TiNb for biomedical applications |
title_fullStr |
Electrochemical stability of binary TiNb for biomedical applications |
title_full_unstemmed |
Electrochemical stability of binary TiNb for biomedical applications |
title_sort |
Electrochemical stability of binary TiNb for biomedical applications |
author |
Reyes, K. M. |
author_facet |
Reyes, K. M. Kuromoto, N. K. Alves Claro, A. P.R. [UNESP] Marino, C. E.B. |
author_role |
author |
author2 |
Kuromoto, N. K. Alves Claro, A. P.R. [UNESP] Marino, C. E.B. |
author2_role |
author author author |
dc.contributor.none.fl_str_mv |
Universidade Federal do Paraná (UFPR) Universidade Estadual Paulista (Unesp) |
dc.contributor.author.fl_str_mv |
Reyes, K. M. Kuromoto, N. K. Alves Claro, A. P.R. [UNESP] Marino, C. E.B. |
dc.subject.por.fl_str_mv |
Corrosion resistance Electrochemical stability Ti-Nb alloys |
topic |
Corrosion resistance Electrochemical stability Ti-Nb alloys |
description |
The Ti-Nb alloy binary system has been widely studied with regard to biomedical applications due to the high biocompatibility and excellent mechanical properties of the alloys. Regarding physicalchemical stability, Ti-Nb alloys maintain the properties of Ti metal, which is highly resistant to corrosion in aggressive media due to a spontaneous stable oxide layer (TiO2) formed on its surface. The objective of this study was to evaluate the corrosion resistance of the Ti-40Nb alloy in artificial blood. The thermodynamic stability was studied using the open circuit potential technique and the corrosion resistance was assessed by potentiodynamic measurements and electrochemical impedance spectroscopy. The electrochemical results indicated that the Ti-40Nb alloy has high corrosion resistance and good thermodynamic stability, with an OCP of around -485 mV, and the alloy remained electrochemically stable in potentiodynamic conditions with initial and final potentials of -1.0 V to +2.0 Vsce, respectively, in low current densities (∼μA cm-2) with an absence of hysteresis, aspure Ti. The results obtained showed that this specific alloy has the potential to be used in biomedical applications. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-07-01 2018-12-11T17:13:54Z 2018-12-11T17:13:54Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1088/2053-1591/aa6ee4 Materials Research Express, v. 4, n. 7, 2017. 2053-1591 http://hdl.handle.net/11449/175028 10.1088/2053-1591/aa6ee4 2-s2.0-85027130515 2-s2.0-85027130515.pdf |
url |
http://dx.doi.org/10.1088/2053-1591/aa6ee4 http://hdl.handle.net/11449/175028 |
identifier_str_mv |
Materials Research Express, v. 4, n. 7, 2017. 2053-1591 10.1088/2053-1591/aa6ee4 2-s2.0-85027130515 2-s2.0-85027130515.pdf |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Materials Research Express 1,429 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
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1808128332024250368 |