Metallo-stannosilicate heterogeneous catalyst for biodiesel production using edible, non-edible and waste oils as feedstock

Detalhes bibliográficos
Autor(a) principal: Silva, Danilo Antonio da [UNESP]
Data de Publicação: 2018
Outros Autores: Santisteban, Oscar A. N. [UNESP], Vasconcellos, Adriano de [UNESP], Paula, Alex Silva [UNESP], Aranda, Donato A. G., Giotto, Marcus Vinicius, Jaeger, Christian, Nery, Jose G. [UNESP]
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1016/j.jece.2018.08.047
http://hdl.handle.net/11449/164624
Resumo: This study reports the synthesis, physicochemical characterization by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and solid-state MAS NMR (H-1, Na-23, Si-29 and Sn-119 MAS NMR) of a metallo-stannosilicate and its application as a heterogeneous catalyst for biodiesel production via ethanolysis and methanolysis routes using edible, non-edible an waste oils as feedstocks. XRD characterization of the metallo-stannosilicate has revealed a typical structure of mixed octahedral-pentahedral-tetrahedral material with an orthorhombic unit cell (a = 14.522 angstrom, b = 12.469 angstrom, and c = 10.654 angstrom). Sn-119 single-pulse MAS NMR results presented two resonance lines, at delta(1)= -683.8 ppm and delta(2) = -690.9 ppm, which were assigned to the fin octahedrally coordinated in the metallo-stannosilicate structure. Heterogenous catalytic studies in the transesterification of refined edible, non-edible, and waste oils have resulted in high yields of FAMEs and FAEEs (fatty acid methyl and ethyl esters), nevertheless the highest FAMES (98.2%) and FAEEs (96.6%) yields were obtained for non-edible microalgae oil extracted from the genetically modified heterotrophic algal strain Prototheca moriformis. Catalytic studies also using non-edible macaw palm oil (Acrocomia aculeata) with a high content of free fatty acids (FFAs) demonstrated that the catalyst could simultaneously perform esterification and transesterification reactions. These findings indicate the potential application of this novel metallo-stannosilicate in the production of renewable and environmentally clean biofuels, like biodiesel, using different sources of lipids feedstocks, notably those that do not compete with food production.
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spelling Metallo-stannosilicate heterogeneous catalyst for biodiesel production using edible, non-edible and waste oils as feedstockSol-gel chemistryMetallo-stannosilicateBiofuelsBiomassEdible and non-edible lipid feedstocksThis study reports the synthesis, physicochemical characterization by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and solid-state MAS NMR (H-1, Na-23, Si-29 and Sn-119 MAS NMR) of a metallo-stannosilicate and its application as a heterogeneous catalyst for biodiesel production via ethanolysis and methanolysis routes using edible, non-edible an waste oils as feedstocks. XRD characterization of the metallo-stannosilicate has revealed a typical structure of mixed octahedral-pentahedral-tetrahedral material with an orthorhombic unit cell (a = 14.522 angstrom, b = 12.469 angstrom, and c = 10.654 angstrom). Sn-119 single-pulse MAS NMR results presented two resonance lines, at delta(1)= -683.8 ppm and delta(2) = -690.9 ppm, which were assigned to the fin octahedrally coordinated in the metallo-stannosilicate structure. Heterogenous catalytic studies in the transesterification of refined edible, non-edible, and waste oils have resulted in high yields of FAMEs and FAEEs (fatty acid methyl and ethyl esters), nevertheless the highest FAMES (98.2%) and FAEEs (96.6%) yields were obtained for non-edible microalgae oil extracted from the genetically modified heterotrophic algal strain Prototheca moriformis. Catalytic studies also using non-edible macaw palm oil (Acrocomia aculeata) with a high content of free fatty acids (FFAs) demonstrated that the catalyst could simultaneously perform esterification and transesterification reactions. These findings indicate the potential application of this novel metallo-stannosilicate in the production of renewable and environmentally clean biofuels, like biodiesel, using different sources of lipids feedstocks, notably those that do not compete with food production.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)UNESP Sao Paulo State Univ, Inst Biosci Letters & Exact Sci, Dept Phys, Campus Sao Jose do Rio Preto, BR-15054000 Sao Paulo, BrazilUniv Fed Rio de Janeiro, Sch Chem, Greentec Lab, BR-21941972 Rio De Janeiro, RJ, BrazilUniv Connecticut, Inst Mat Sci, 97 North Eagleville Rd, Storrs, CT 06269 USABAM Fed Inst Mat Res & Testing, Div 1-3,Richard Willstaetter Str 11, D-12489 Berlin, GermanyUNESP Sao Paulo State Univ, Inst Biosci Letters & Exact Sci, Dept Phys, Campus Sao Jose do Rio Preto, BR-15054000 Sao Paulo, BrazilFAPESP: 11/51851-5CNPq: 406761/2013-2CAPES: BEX 2428/15-6Elsevier B.V.Universidade Estadual Paulista (Unesp)Universidade Federal do Rio de Janeiro (UFRJ)Univ ConnecticutBAM Fed Inst Mat Res & TestingSilva, Danilo Antonio da [UNESP]Santisteban, Oscar A. N. [UNESP]Vasconcellos, Adriano de [UNESP]Paula, Alex Silva [UNESP]Aranda, Donato A. G.Giotto, Marcus ViniciusJaeger, ChristianNery, Jose G. [UNESP]2018-11-26T17:55:21Z2018-11-26T17:55:21Z2018-08-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article5488-5497application/pdfhttp://dx.doi.org/10.1016/j.jece.2018.08.047Journal Of Environmental Chemical Engineering. Oxford: Elsevier Sci Ltd, v. 6, n. 4, p. 5488-5497, 2018.2213-3437http://hdl.handle.net/11449/16462410.1016/j.jece.2018.08.047WOS:000444046700177WOS000444046700177.pdfWeb of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal Of Environmental Chemical Engineering0,924info:eu-repo/semantics/openAccess2024-01-08T06:29:59Zoai:repositorio.unesp.br:11449/164624Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T22:29:24.864175Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Metallo-stannosilicate heterogeneous catalyst for biodiesel production using edible, non-edible and waste oils as feedstock
title Metallo-stannosilicate heterogeneous catalyst for biodiesel production using edible, non-edible and waste oils as feedstock
spellingShingle Metallo-stannosilicate heterogeneous catalyst for biodiesel production using edible, non-edible and waste oils as feedstock
Silva, Danilo Antonio da [UNESP]
Sol-gel chemistry
Metallo-stannosilicate
Biofuels
Biomass
Edible and non-edible lipid feedstocks
title_short Metallo-stannosilicate heterogeneous catalyst for biodiesel production using edible, non-edible and waste oils as feedstock
title_full Metallo-stannosilicate heterogeneous catalyst for biodiesel production using edible, non-edible and waste oils as feedstock
title_fullStr Metallo-stannosilicate heterogeneous catalyst for biodiesel production using edible, non-edible and waste oils as feedstock
title_full_unstemmed Metallo-stannosilicate heterogeneous catalyst for biodiesel production using edible, non-edible and waste oils as feedstock
title_sort Metallo-stannosilicate heterogeneous catalyst for biodiesel production using edible, non-edible and waste oils as feedstock
author Silva, Danilo Antonio da [UNESP]
author_facet Silva, Danilo Antonio da [UNESP]
Santisteban, Oscar A. N. [UNESP]
Vasconcellos, Adriano de [UNESP]
Paula, Alex Silva [UNESP]
Aranda, Donato A. G.
Giotto, Marcus Vinicius
Jaeger, Christian
Nery, Jose G. [UNESP]
author_role author
author2 Santisteban, Oscar A. N. [UNESP]
Vasconcellos, Adriano de [UNESP]
Paula, Alex Silva [UNESP]
Aranda, Donato A. G.
Giotto, Marcus Vinicius
Jaeger, Christian
Nery, Jose G. [UNESP]
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (Unesp)
Universidade Federal do Rio de Janeiro (UFRJ)
Univ Connecticut
BAM Fed Inst Mat Res & Testing
dc.contributor.author.fl_str_mv Silva, Danilo Antonio da [UNESP]
Santisteban, Oscar A. N. [UNESP]
Vasconcellos, Adriano de [UNESP]
Paula, Alex Silva [UNESP]
Aranda, Donato A. G.
Giotto, Marcus Vinicius
Jaeger, Christian
Nery, Jose G. [UNESP]
dc.subject.por.fl_str_mv Sol-gel chemistry
Metallo-stannosilicate
Biofuels
Biomass
Edible and non-edible lipid feedstocks
topic Sol-gel chemistry
Metallo-stannosilicate
Biofuels
Biomass
Edible and non-edible lipid feedstocks
description This study reports the synthesis, physicochemical characterization by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and solid-state MAS NMR (H-1, Na-23, Si-29 and Sn-119 MAS NMR) of a metallo-stannosilicate and its application as a heterogeneous catalyst for biodiesel production via ethanolysis and methanolysis routes using edible, non-edible an waste oils as feedstocks. XRD characterization of the metallo-stannosilicate has revealed a typical structure of mixed octahedral-pentahedral-tetrahedral material with an orthorhombic unit cell (a = 14.522 angstrom, b = 12.469 angstrom, and c = 10.654 angstrom). Sn-119 single-pulse MAS NMR results presented two resonance lines, at delta(1)= -683.8 ppm and delta(2) = -690.9 ppm, which were assigned to the fin octahedrally coordinated in the metallo-stannosilicate structure. Heterogenous catalytic studies in the transesterification of refined edible, non-edible, and waste oils have resulted in high yields of FAMEs and FAEEs (fatty acid methyl and ethyl esters), nevertheless the highest FAMES (98.2%) and FAEEs (96.6%) yields were obtained for non-edible microalgae oil extracted from the genetically modified heterotrophic algal strain Prototheca moriformis. Catalytic studies also using non-edible macaw palm oil (Acrocomia aculeata) with a high content of free fatty acids (FFAs) demonstrated that the catalyst could simultaneously perform esterification and transesterification reactions. These findings indicate the potential application of this novel metallo-stannosilicate in the production of renewable and environmentally clean biofuels, like biodiesel, using different sources of lipids feedstocks, notably those that do not compete with food production.
publishDate 2018
dc.date.none.fl_str_mv 2018-11-26T17:55:21Z
2018-11-26T17:55:21Z
2018-08-01
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1016/j.jece.2018.08.047
Journal Of Environmental Chemical Engineering. Oxford: Elsevier Sci Ltd, v. 6, n. 4, p. 5488-5497, 2018.
2213-3437
http://hdl.handle.net/11449/164624
10.1016/j.jece.2018.08.047
WOS:000444046700177
WOS000444046700177.pdf
url http://dx.doi.org/10.1016/j.jece.2018.08.047
http://hdl.handle.net/11449/164624
identifier_str_mv Journal Of Environmental Chemical Engineering. Oxford: Elsevier Sci Ltd, v. 6, n. 4, p. 5488-5497, 2018.
2213-3437
10.1016/j.jece.2018.08.047
WOS:000444046700177
WOS000444046700177.pdf
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Journal Of Environmental Chemical Engineering
0,924
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 5488-5497
application/pdf
dc.publisher.none.fl_str_mv Elsevier B.V.
publisher.none.fl_str_mv Elsevier B.V.
dc.source.none.fl_str_mv Web of Science
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
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