Effect of the pH pre-adjustment on the formation of In(2)W(3)O(12 )and In6WO12 powders: Cluster coordination and optical band gap

• Autor(a) principal: Paiva, Rafael Texeira de
• Data de Publicação: 2020
• Outros Autores: Nogueira, Icamira Costa, Sczancoski, Julio Cesar, Lemos, Pablo Santana, Elias Matos, Jose Milton, Santos, Reginaldo Silva, Longo, Elson [UNESP], Cavalcante, Laecio Santos
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Institucional da UNESP
• Texto Completo: http://dx.doi.org/10.1016/j.bsecv.2019.02.001; http://hdl.handle.net/11449/196869
• topic: In2W3O12; In6WO12; Rietveld refinement; Clusters; Optical band gap

In this communication, diindium tristungstate (In2W3O12) and hexaindium tungstate (In6WO12) powders were synthesized by the co-precipitation method at different pH values and heat treatment at 1073 K for 2 h. X-ray diffraction patterns and Rietveld refinements were employed to analyze the long-range structural ordering as well as quantify the presence crystallographic phases, respectively. All powders obtained in pH ranging from 2 to 3.5 exhibited a mixture of In2W3O12 and gamma-tungsten oxide (gamma-WO3) phases. When prepared at pH close to 4, the powders presented both In2W3O12 and In6WO12 phases. All these crystalline structures were simulated in a three-dimensional visualization program by adopting the Rietveld refinements analysis as input data. The ultraviolet-visible spectra were employed to estimate the optical band gap energy of all powders for the first time. (C) 2019 Published by Elsevier Espana, S.L.U. on behalf of SECV.