Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I)

Detalhes bibliográficos
Autor(a) principal: Muraoka, T. K. [UNESP]
Data de Publicação: 2007
Outros Autores: Duarte, A. P. [UNESP], Takahashi, P. M. [UNESP], Nogueira, V. M. [UNESP], Netto, A. V.G. [UNESP], Mauro, A. E. [UNESP]
Tipo de documento: Artigo
Idioma: por
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.26850/1678-4618EQJ.V32.2.2007.P7-11
http://hdl.handle.net/11449/229760
Resumo: This work describes the one pot syntheses and characterization of two new heterometallic carbonyl compounds of the type [Fe(CO)3(m-CS2)(PPh3)(CuX)], X = Cl, ClO4. Both compounds were investigated by infrared and 31P{1H} NMR spectroscopies in order to clarify the coordination mode of the carbonyl groups, as well the bridging disposition of the carbon disulfide between iron (0) and copper (I) atoms.
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spelling Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I)Reatividade do [Fe(CO)2(2-CS2)(PPh3)2] frente a compostos de Cu(I): Síntese de espécies binucleares heterometálicas contendo CS2 em ponte entre Fe(0) e Cu(I).Carbon disulfideCopper (I)Heterometallic carbonyl complexesIron (0)This work describes the one pot syntheses and characterization of two new heterometallic carbonyl compounds of the type [Fe(CO)3(m-CS2)(PPh3)(CuX)], X = Cl, ClO4. Both compounds were investigated by infrared and 31P{1H} NMR spectroscopies in order to clarify the coordination mode of the carbonyl groups, as well the bridging disposition of the carbon disulfide between iron (0) and copper (I) atoms.Departamento de Química Geral e Inorgânica Instituto de Química – UNESPCentro Universitário de Araraquara UNIARADepartamento de Química Geral e Inorgânica Instituto de Química – UNESPUniversidade Estadual Paulista (UNESP)UNIARAMuraoka, T. K. [UNESP]Duarte, A. P. [UNESP]Takahashi, P. M. [UNESP]Nogueira, V. M. [UNESP]Netto, A. V.G. [UNESP]Mauro, A. E. [UNESP]2022-04-29T08:35:39Z2022-04-29T08:35:39Z2007-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article7-11http://dx.doi.org/10.26850/1678-4618EQJ.V32.2.2007.P7-11Ecletica Quimica, v. 32, n. 2, p. 7-11, 2007.1678-46180100-4670http://hdl.handle.net/11449/22976010.26850/1678-4618EQJ.V32.2.2007.P7-112-s2.0-85117570292Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPporEcletica Quimicainfo:eu-repo/semantics/openAccess2022-04-29T08:35:39Zoai:repositorio.unesp.br:11449/229760Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T15:38:54.930901Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I)
Reatividade do [Fe(CO)2(2-CS2)(PPh3)2] frente a compostos de Cu(I): Síntese de espécies binucleares heterometálicas contendo CS2 em ponte entre Fe(0) e Cu(I).
title Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I)
spellingShingle Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I)
Muraoka, T. K. [UNESP]
Carbon disulfide
Copper (I)
Heterometallic carbonyl complexes
Iron (0)
title_short Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I)
title_full Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I)
title_fullStr Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I)
title_full_unstemmed Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I)
title_sort Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I)
author Muraoka, T. K. [UNESP]
author_facet Muraoka, T. K. [UNESP]
Duarte, A. P. [UNESP]
Takahashi, P. M. [UNESP]
Nogueira, V. M. [UNESP]
Netto, A. V.G. [UNESP]
Mauro, A. E. [UNESP]
author_role author
author2 Duarte, A. P. [UNESP]
Takahashi, P. M. [UNESP]
Nogueira, V. M. [UNESP]
Netto, A. V.G. [UNESP]
Mauro, A. E. [UNESP]
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (UNESP)
UNIARA
dc.contributor.author.fl_str_mv Muraoka, T. K. [UNESP]
Duarte, A. P. [UNESP]
Takahashi, P. M. [UNESP]
Nogueira, V. M. [UNESP]
Netto, A. V.G. [UNESP]
Mauro, A. E. [UNESP]
dc.subject.por.fl_str_mv Carbon disulfide
Copper (I)
Heterometallic carbonyl complexes
Iron (0)
topic Carbon disulfide
Copper (I)
Heterometallic carbonyl complexes
Iron (0)
description This work describes the one pot syntheses and characterization of two new heterometallic carbonyl compounds of the type [Fe(CO)3(m-CS2)(PPh3)(CuX)], X = Cl, ClO4. Both compounds were investigated by infrared and 31P{1H} NMR spectroscopies in order to clarify the coordination mode of the carbonyl groups, as well the bridging disposition of the carbon disulfide between iron (0) and copper (I) atoms.
publishDate 2007
dc.date.none.fl_str_mv 2007-01-01
2022-04-29T08:35:39Z
2022-04-29T08:35:39Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.26850/1678-4618EQJ.V32.2.2007.P7-11
Ecletica Quimica, v. 32, n. 2, p. 7-11, 2007.
1678-4618
0100-4670
http://hdl.handle.net/11449/229760
10.26850/1678-4618EQJ.V32.2.2007.P7-11
2-s2.0-85117570292
url http://dx.doi.org/10.26850/1678-4618EQJ.V32.2.2007.P7-11
http://hdl.handle.net/11449/229760
identifier_str_mv Ecletica Quimica, v. 32, n. 2, p. 7-11, 2007.
1678-4618
0100-4670
10.26850/1678-4618EQJ.V32.2.2007.P7-11
2-s2.0-85117570292
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv Ecletica Quimica
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 7-11
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1808128544142786560

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