Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I)
Autor(a) principal: | |
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Data de Publicação: | 2007 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.26850/1678-4618EQJ.V32.2.2007.P7-11 http://hdl.handle.net/11449/229760 |
Resumo: | This work describes the one pot syntheses and characterization of two new heterometallic carbonyl compounds of the type [Fe(CO)3(m-CS2)(PPh3)(CuX)], X = Cl, ClO4. Both compounds were investigated by infrared and 31P{1H} NMR spectroscopies in order to clarify the coordination mode of the carbonyl groups, as well the bridging disposition of the carbon disulfide between iron (0) and copper (I) atoms. |
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Repositório Institucional da UNESP |
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2946 |
spelling |
Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I)Reatividade do [Fe(CO)2(2-CS2)(PPh3)2] frente a compostos de Cu(I): Síntese de espécies binucleares heterometálicas contendo CS2 em ponte entre Fe(0) e Cu(I).Carbon disulfideCopper (I)Heterometallic carbonyl complexesIron (0)This work describes the one pot syntheses and characterization of two new heterometallic carbonyl compounds of the type [Fe(CO)3(m-CS2)(PPh3)(CuX)], X = Cl, ClO4. Both compounds were investigated by infrared and 31P{1H} NMR spectroscopies in order to clarify the coordination mode of the carbonyl groups, as well the bridging disposition of the carbon disulfide between iron (0) and copper (I) atoms.Departamento de Química Geral e Inorgânica Instituto de Química – UNESPCentro Universitário de Araraquara UNIARADepartamento de Química Geral e Inorgânica Instituto de Química – UNESPUniversidade Estadual Paulista (UNESP)UNIARAMuraoka, T. K. [UNESP]Duarte, A. P. [UNESP]Takahashi, P. M. [UNESP]Nogueira, V. M. [UNESP]Netto, A. V.G. [UNESP]Mauro, A. E. [UNESP]2022-04-29T08:35:39Z2022-04-29T08:35:39Z2007-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article7-11http://dx.doi.org/10.26850/1678-4618EQJ.V32.2.2007.P7-11Ecletica Quimica, v. 32, n. 2, p. 7-11, 2007.1678-46180100-4670http://hdl.handle.net/11449/22976010.26850/1678-4618EQJ.V32.2.2007.P7-112-s2.0-85117570292Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPporEcletica Quimicainfo:eu-repo/semantics/openAccess2022-04-29T08:35:39Zoai:repositorio.unesp.br:11449/229760Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T15:38:54.930901Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I) Reatividade do [Fe(CO)2(2-CS2)(PPh3)2] frente a compostos de Cu(I): Síntese de espécies binucleares heterometálicas contendo CS2 em ponte entre Fe(0) e Cu(I). |
title |
Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I) |
spellingShingle |
Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I) Muraoka, T. K. [UNESP] Carbon disulfide Copper (I) Heterometallic carbonyl complexes Iron (0) |
title_short |
Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I) |
title_full |
Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I) |
title_fullStr |
Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I) |
title_full_unstemmed |
Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I) |
title_sort |
Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I) |
author |
Muraoka, T. K. [UNESP] |
author_facet |
Muraoka, T. K. [UNESP] Duarte, A. P. [UNESP] Takahashi, P. M. [UNESP] Nogueira, V. M. [UNESP] Netto, A. V.G. [UNESP] Mauro, A. E. [UNESP] |
author_role |
author |
author2 |
Duarte, A. P. [UNESP] Takahashi, P. M. [UNESP] Nogueira, V. M. [UNESP] Netto, A. V.G. [UNESP] Mauro, A. E. [UNESP] |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Universidade Estadual Paulista (UNESP) UNIARA |
dc.contributor.author.fl_str_mv |
Muraoka, T. K. [UNESP] Duarte, A. P. [UNESP] Takahashi, P. M. [UNESP] Nogueira, V. M. [UNESP] Netto, A. V.G. [UNESP] Mauro, A. E. [UNESP] |
dc.subject.por.fl_str_mv |
Carbon disulfide Copper (I) Heterometallic carbonyl complexes Iron (0) |
topic |
Carbon disulfide Copper (I) Heterometallic carbonyl complexes Iron (0) |
description |
This work describes the one pot syntheses and characterization of two new heterometallic carbonyl compounds of the type [Fe(CO)3(m-CS2)(PPh3)(CuX)], X = Cl, ClO4. Both compounds were investigated by infrared and 31P{1H} NMR spectroscopies in order to clarify the coordination mode of the carbonyl groups, as well the bridging disposition of the carbon disulfide between iron (0) and copper (I) atoms. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007-01-01 2022-04-29T08:35:39Z 2022-04-29T08:35:39Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.26850/1678-4618EQJ.V32.2.2007.P7-11 Ecletica Quimica, v. 32, n. 2, p. 7-11, 2007. 1678-4618 0100-4670 http://hdl.handle.net/11449/229760 10.26850/1678-4618EQJ.V32.2.2007.P7-11 2-s2.0-85117570292 |
url |
http://dx.doi.org/10.26850/1678-4618EQJ.V32.2.2007.P7-11 http://hdl.handle.net/11449/229760 |
identifier_str_mv |
Ecletica Quimica, v. 32, n. 2, p. 7-11, 2007. 1678-4618 0100-4670 10.26850/1678-4618EQJ.V32.2.2007.P7-11 2-s2.0-85117570292 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
Ecletica Quimica |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
7-11 |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808128544142786560 |