Effect of microstructure on the nanotube growth by anodic oxidation on Ti-10Nb alloy
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1088/2053-1591/aa7d25 http://hdl.handle.net/11449/163058 |
Resumo: | Several papers have reported the grown self-organized nanotube arrays on pure Ti and its alloys to improve the surface of these materials for biomedical applications. The growth of nanotubes can be influenced by microstructure of material; however, few papers concerning this topic have been published. The aim of this work was to investigate the morphology, the cross-section view and the oxides in nanotube arrays in relationship to the microstructure of the Ti-10Nb alloy. The growth of nanotubes on the Ti-10Nb alloy obtained by anodic oxidation (AO). The Ti-10Nb alloy is composed by alfa and beta phases that were investigated by metallographic analysis, patterns of x-ray diffraction and EDS analysis. SEM images and EDS analysis revealed the morphology was composed by self-organized nanotube arrays on the alpha phase and walls with transversal holes on beta phase. X-ray patterns show crystalline oxides formation. Raman spectrum confirms the presence of anatase and Nb2O5 oxides. A significant contribution of the Nb2O5 was observed by bi-dimensional (x, y) Raman mapping, which also showed that the all oxide film was homogeneous oxide distributed on Ti-10Nb alloy. The nanostructured films have higher thickness in the beta than in the alpha phase, and have a small different in structure and oxide composition; as observed by SEM and Raman mapping. The results indicate that the microstructure of the Ti-10Nb affects the nanotubes morphology and the cross-section view, but the oxide formation was similar for all regions analyzed. |
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Effect of microstructure on the nanotube growth by anodic oxidation on Ti-10Nb alloyTi-10Nb alloymicrostructurenanotubesnanostructured wallsRaman mappingSeveral papers have reported the grown self-organized nanotube arrays on pure Ti and its alloys to improve the surface of these materials for biomedical applications. The growth of nanotubes can be influenced by microstructure of material; however, few papers concerning this topic have been published. The aim of this work was to investigate the morphology, the cross-section view and the oxides in nanotube arrays in relationship to the microstructure of the Ti-10Nb alloy. The growth of nanotubes on the Ti-10Nb alloy obtained by anodic oxidation (AO). The Ti-10Nb alloy is composed by alfa and beta phases that were investigated by metallographic analysis, patterns of x-ray diffraction and EDS analysis. SEM images and EDS analysis revealed the morphology was composed by self-organized nanotube arrays on the alpha phase and walls with transversal holes on beta phase. X-ray patterns show crystalline oxides formation. Raman spectrum confirms the presence of anatase and Nb2O5 oxides. A significant contribution of the Nb2O5 was observed by bi-dimensional (x, y) Raman mapping, which also showed that the all oxide film was homogeneous oxide distributed on Ti-10Nb alloy. The nanostructured films have higher thickness in the beta than in the alpha phase, and have a small different in structure and oxide composition; as observed by SEM and Raman mapping. The results indicate that the microstructure of the Ti-10Nb affects the nanotubes morphology and the cross-section view, but the oxide formation was similar for all regions analyzed.Electron Microscopy Center of UFPRX-ray Optics Laboratory of the Department of Physics UFPRAraucaria FoundationCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Univ Fed Parana, Programa Posgrad Engn & Ciencia Mat PIPE, BR-81531990 Curitiba, Parana, BrazilUniv Fed Parana, Dept Engn Mecan, BR-81531990 Curitiba, Parana, BrazilUniv Estadual Paulista, Dept Fis, Campus Bauru, BR-17033360 Bauru, SP, BrazilUniv Fed Parana, Dept Fis, BR-81531990 Curitiba, Parana, BrazilUniv Estadual Paulista, Dept Fis, Campus Bauru, BR-17033360 Bauru, SP, BrazilIop Publishing LtdUniv Fed ParanaUniversidade Estadual Paulista (Unesp)Luz, A. R.Lepienski, C. M.Henke, S. L.Grandini, C. R. [UNESP]Kuromoto, N. K.2018-11-26T17:39:55Z2018-11-26T17:39:55Z2017-07-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10application/pdfhttp://dx.doi.org/10.1088/2053-1591/aa7d25Materials Research Express. Bristol: Iop Publishing Ltd, v. 4, n. 7, 10 p., 2017.2053-1591http://hdl.handle.net/11449/16305810.1088/2053-1591/aa7d25WOS:000406419100001WOS000406419100001.pdfWeb of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengMaterials Research Express1,429info:eu-repo/semantics/openAccess2024-04-25T17:40:09Zoai:repositorio.unesp.br:11449/163058Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-04-25T17:40:09Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Effect of microstructure on the nanotube growth by anodic oxidation on Ti-10Nb alloy |
title |
Effect of microstructure on the nanotube growth by anodic oxidation on Ti-10Nb alloy |
spellingShingle |
Effect of microstructure on the nanotube growth by anodic oxidation on Ti-10Nb alloy Luz, A. R. Ti-10Nb alloy microstructure nanotubes nanostructured walls Raman mapping |
title_short |
Effect of microstructure on the nanotube growth by anodic oxidation on Ti-10Nb alloy |
title_full |
Effect of microstructure on the nanotube growth by anodic oxidation on Ti-10Nb alloy |
title_fullStr |
Effect of microstructure on the nanotube growth by anodic oxidation on Ti-10Nb alloy |
title_full_unstemmed |
Effect of microstructure on the nanotube growth by anodic oxidation on Ti-10Nb alloy |
title_sort |
Effect of microstructure on the nanotube growth by anodic oxidation on Ti-10Nb alloy |
author |
Luz, A. R. |
author_facet |
Luz, A. R. Lepienski, C. M. Henke, S. L. Grandini, C. R. [UNESP] Kuromoto, N. K. |
author_role |
author |
author2 |
Lepienski, C. M. Henke, S. L. Grandini, C. R. [UNESP] Kuromoto, N. K. |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
Univ Fed Parana Universidade Estadual Paulista (Unesp) |
dc.contributor.author.fl_str_mv |
Luz, A. R. Lepienski, C. M. Henke, S. L. Grandini, C. R. [UNESP] Kuromoto, N. K. |
dc.subject.por.fl_str_mv |
Ti-10Nb alloy microstructure nanotubes nanostructured walls Raman mapping |
topic |
Ti-10Nb alloy microstructure nanotubes nanostructured walls Raman mapping |
description |
Several papers have reported the grown self-organized nanotube arrays on pure Ti and its alloys to improve the surface of these materials for biomedical applications. The growth of nanotubes can be influenced by microstructure of material; however, few papers concerning this topic have been published. The aim of this work was to investigate the morphology, the cross-section view and the oxides in nanotube arrays in relationship to the microstructure of the Ti-10Nb alloy. The growth of nanotubes on the Ti-10Nb alloy obtained by anodic oxidation (AO). The Ti-10Nb alloy is composed by alfa and beta phases that were investigated by metallographic analysis, patterns of x-ray diffraction and EDS analysis. SEM images and EDS analysis revealed the morphology was composed by self-organized nanotube arrays on the alpha phase and walls with transversal holes on beta phase. X-ray patterns show crystalline oxides formation. Raman spectrum confirms the presence of anatase and Nb2O5 oxides. A significant contribution of the Nb2O5 was observed by bi-dimensional (x, y) Raman mapping, which also showed that the all oxide film was homogeneous oxide distributed on Ti-10Nb alloy. The nanostructured films have higher thickness in the beta than in the alpha phase, and have a small different in structure and oxide composition; as observed by SEM and Raman mapping. The results indicate that the microstructure of the Ti-10Nb affects the nanotubes morphology and the cross-section view, but the oxide formation was similar for all regions analyzed. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-07-01 2018-11-26T17:39:55Z 2018-11-26T17:39:55Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1088/2053-1591/aa7d25 Materials Research Express. Bristol: Iop Publishing Ltd, v. 4, n. 7, 10 p., 2017. 2053-1591 http://hdl.handle.net/11449/163058 10.1088/2053-1591/aa7d25 WOS:000406419100001 WOS000406419100001.pdf |
url |
http://dx.doi.org/10.1088/2053-1591/aa7d25 http://hdl.handle.net/11449/163058 |
identifier_str_mv |
Materials Research Express. Bristol: Iop Publishing Ltd, v. 4, n. 7, 10 p., 2017. 2053-1591 10.1088/2053-1591/aa7d25 WOS:000406419100001 WOS000406419100001.pdf |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Materials Research Express 1,429 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
10 application/pdf |
dc.publisher.none.fl_str_mv |
Iop Publishing Ltd |
publisher.none.fl_str_mv |
Iop Publishing Ltd |
dc.source.none.fl_str_mv |
Web of Science reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
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1799965325958053888 |