Electrospray ionization mass spectrometry screening of piperidine alkaloids from Senna spectabilis (Fabaceae) extracts: Fast identification of new constituents and co-metabolites

Detalhes bibliográficos
Autor(a) principal: Pivatto, Marcos [UNESP]
Data de Publicação: 2005
Outros Autores: Crotti, Antônio E. M., Lopes, Norberto P., Castro-Gamboa, Ian [UNESP], De Rezende, Amanda [UNESP], Viegas Jr., Cláudio [UNESP], Young, Maria Claudia M., Furlan, Maysa [UNESP], Bolzani, Vanderlan da Silva [UNESP]
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1590/S0103-50532005000800023
http://hdl.handle.net/11449/68471
Resumo: The fragmentation pattern of a homologous series of piperidine alkaloids isolated from S. spectabilis was investigated using electrospray ionization tandem mass spectrometry (ESI-MS/MS). The ESI-MS and ESI-MS/MS analyses of EtOH extracts and fractions from flowers and fruits of S. spectabilis allowed to elucidate the structures of four new compounds. The identification of these co-metabolites, based on the fragmentation patterns of previously isolated compounds, and further confirmed by accurate mass spectrometry defines this technique as a powerful tool to determine the metabolomic profile of species which has pharmacological importance. ©2005 Sociedade Brasileira de Química.
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spelling Electrospray ionization mass spectrometry screening of piperidine alkaloids from Senna spectabilis (Fabaceae) extracts: Fast identification of new constituents and co-metabolitesElectrosprayMetabolomic profilePiperidine alkaloidsSenna spectabilisTandem mass spectrometryThe fragmentation pattern of a homologous series of piperidine alkaloids isolated from S. spectabilis was investigated using electrospray ionization tandem mass spectrometry (ESI-MS/MS). The ESI-MS and ESI-MS/MS analyses of EtOH extracts and fractions from flowers and fruits of S. spectabilis allowed to elucidate the structures of four new compounds. The identification of these co-metabolites, based on the fragmentation patterns of previously isolated compounds, and further confirmed by accurate mass spectrometry defines this technique as a powerful tool to determine the metabolomic profile of species which has pharmacological importance. ©2005 Sociedade Brasileira de Química.Instituto de Química Universidade Estadual Paulista, CP 355, 14801-970 Araraquara - SPNúcleo de Pesquisas em Ciências Exatas e Tecnológicas Universidade de Franca, Av. Dr. A. Salles de Oliveira 201, 14404-600 Franca - SPDepartamento de Física e Química Faculdade de Ciências Farmacêuticas Universidade de São Paulo, Via do Café s/n, 14040-903 Ribeirão Preto - SPSeção de Fisiologia e Bioquímica de Plantas Instituto de Botânica, CP 4005, 01061-970 São Paulo - SPInstituto de Química Universidade Estadual Paulista, CP 355, 14801-970 Araraquara - SPUniversidade Estadual Paulista (Unesp)Universidade de FrancaUniversidade de São Paulo (USP)Instituto de BotânicaPivatto, Marcos [UNESP]Crotti, Antônio E. M.Lopes, Norberto P.Castro-Gamboa, Ian [UNESP]De Rezende, Amanda [UNESP]Viegas Jr., Cláudio [UNESP]Young, Maria Claudia M.Furlan, Maysa [UNESP]Bolzani, Vanderlan da Silva [UNESP]2014-05-27T11:21:40Z2014-05-27T11:21:40Z2005-11-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article1431-1438application/pdfhttp://dx.doi.org/10.1590/S0103-50532005000800023Journal of the Brazilian Chemical Society, v. 16, n. 6 B, p. 1431-1438, 2005.0103-5053http://hdl.handle.net/11449/6847110.1590/S0103-50532005000800023S0103-50532005000800023WOS:0002340787000232-s2.0-308444534022-s2.0-30844453402.pdf13080427947868724484083685251673Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of the Brazilian Chemical Society1.4440,357info:eu-repo/semantics/openAccess2023-11-03T06:08:43Zoai:repositorio.unesp.br:11449/68471Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T16:47:42.224150Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Electrospray ionization mass spectrometry screening of piperidine alkaloids from Senna spectabilis (Fabaceae) extracts: Fast identification of new constituents and co-metabolites
title Electrospray ionization mass spectrometry screening of piperidine alkaloids from Senna spectabilis (Fabaceae) extracts: Fast identification of new constituents and co-metabolites
spellingShingle Electrospray ionization mass spectrometry screening of piperidine alkaloids from Senna spectabilis (Fabaceae) extracts: Fast identification of new constituents and co-metabolites
Pivatto, Marcos [UNESP]
Electrospray
Metabolomic profile
Piperidine alkaloids
Senna spectabilis
Tandem mass spectrometry
title_short Electrospray ionization mass spectrometry screening of piperidine alkaloids from Senna spectabilis (Fabaceae) extracts: Fast identification of new constituents and co-metabolites
title_full Electrospray ionization mass spectrometry screening of piperidine alkaloids from Senna spectabilis (Fabaceae) extracts: Fast identification of new constituents and co-metabolites
title_fullStr Electrospray ionization mass spectrometry screening of piperidine alkaloids from Senna spectabilis (Fabaceae) extracts: Fast identification of new constituents and co-metabolites
title_full_unstemmed Electrospray ionization mass spectrometry screening of piperidine alkaloids from Senna spectabilis (Fabaceae) extracts: Fast identification of new constituents and co-metabolites
title_sort Electrospray ionization mass spectrometry screening of piperidine alkaloids from Senna spectabilis (Fabaceae) extracts: Fast identification of new constituents and co-metabolites
author Pivatto, Marcos [UNESP]
author_facet Pivatto, Marcos [UNESP]
Crotti, Antônio E. M.
Lopes, Norberto P.
Castro-Gamboa, Ian [UNESP]
De Rezende, Amanda [UNESP]
Viegas Jr., Cláudio [UNESP]
Young, Maria Claudia M.
Furlan, Maysa [UNESP]
Bolzani, Vanderlan da Silva [UNESP]
author_role author
author2 Crotti, Antônio E. M.
Lopes, Norberto P.
Castro-Gamboa, Ian [UNESP]
De Rezende, Amanda [UNESP]
Viegas Jr., Cláudio [UNESP]
Young, Maria Claudia M.
Furlan, Maysa [UNESP]
Bolzani, Vanderlan da Silva [UNESP]
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (Unesp)
Universidade de Franca
Universidade de São Paulo (USP)
Instituto de Botânica
dc.contributor.author.fl_str_mv Pivatto, Marcos [UNESP]
Crotti, Antônio E. M.
Lopes, Norberto P.
Castro-Gamboa, Ian [UNESP]
De Rezende, Amanda [UNESP]
Viegas Jr., Cláudio [UNESP]
Young, Maria Claudia M.
Furlan, Maysa [UNESP]
Bolzani, Vanderlan da Silva [UNESP]
dc.subject.por.fl_str_mv Electrospray
Metabolomic profile
Piperidine alkaloids
Senna spectabilis
Tandem mass spectrometry
topic Electrospray
Metabolomic profile
Piperidine alkaloids
Senna spectabilis
Tandem mass spectrometry
description The fragmentation pattern of a homologous series of piperidine alkaloids isolated from S. spectabilis was investigated using electrospray ionization tandem mass spectrometry (ESI-MS/MS). The ESI-MS and ESI-MS/MS analyses of EtOH extracts and fractions from flowers and fruits of S. spectabilis allowed to elucidate the structures of four new compounds. The identification of these co-metabolites, based on the fragmentation patterns of previously isolated compounds, and further confirmed by accurate mass spectrometry defines this technique as a powerful tool to determine the metabolomic profile of species which has pharmacological importance. ©2005 Sociedade Brasileira de Química.
publishDate 2005
dc.date.none.fl_str_mv 2005-11-01
2014-05-27T11:21:40Z
2014-05-27T11:21:40Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1590/S0103-50532005000800023
Journal of the Brazilian Chemical Society, v. 16, n. 6 B, p. 1431-1438, 2005.
0103-5053
http://hdl.handle.net/11449/68471
10.1590/S0103-50532005000800023
S0103-50532005000800023
WOS:000234078700023
2-s2.0-30844453402
2-s2.0-30844453402.pdf
1308042794786872
4484083685251673
url http://dx.doi.org/10.1590/S0103-50532005000800023
http://hdl.handle.net/11449/68471
identifier_str_mv Journal of the Brazilian Chemical Society, v. 16, n. 6 B, p. 1431-1438, 2005.
0103-5053
10.1590/S0103-50532005000800023
S0103-50532005000800023
WOS:000234078700023
2-s2.0-30844453402
2-s2.0-30844453402.pdf
1308042794786872
4484083685251673
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Journal of the Brazilian Chemical Society
1.444
0,357
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 1431-1438
application/pdf
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1808128703049236480

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