Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1016/j.jelechem.2020.114928 http://hdl.handle.net/11449/205614 |
Resumo: | We have developed electrocatalytic platforms based on palladium metallopolymer-graphene for the water splitting reaction. The platforms presented a low potential for the water oxidation reaction. By cyclic voltammetry and electrochemical impedance spectroscopy (EIS), the interfacial phenomena were investigated, allowing us to obtain important results that helped to determine kinetic and mechanistic information. The studies revealed that the introduction of graphene in the metallopolymer matrix increased the turnover frequency (TOF) value. Analysis of the Tafel plots obtained from the EIS data also revealed a change in the reaction mechanism after the introduction of graphene. The new platform demonstrated its applicability in the water splitting reaction for use in fuel cells. |
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Repositório Institucional da UNESP |
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2946 |
spelling |
Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidationElectrocatalysisElectrochemical impedanceMetallopolymerWater oxidationWater splittingWe have developed electrocatalytic platforms based on palladium metallopolymer-graphene for the water splitting reaction. The platforms presented a low potential for the water oxidation reaction. By cyclic voltammetry and electrochemical impedance spectroscopy (EIS), the interfacial phenomena were investigated, allowing us to obtain important results that helped to determine kinetic and mechanistic information. The studies revealed that the introduction of graphene in the metallopolymer matrix increased the turnover frequency (TOF) value. Analysis of the Tafel plots obtained from the EIS data also revealed a change in the reaction mechanism after the introduction of graphene. The new platform demonstrated its applicability in the water splitting reaction for use in fuel cells.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Department of Chemistry and Biochemistry School of Science and Technology - Sao Paulo State University (UNESP), Rua Roberto Simonsen 305Department of Chemistry and Biochemistry School of Science and Technology - Sao Paulo State University (UNESP), Rua Roberto Simonsen 305FAPESP: 2016/09017-1CNPq: 301298/2017-3CAPES: 88882.434480/2019-01Universidade Estadual Paulista (Unesp)Oliveira, Yuri A. [UNESP]Olean-Oliveira, André [UNESP]Teixeira, Marcos F.S. [UNESP]2021-06-25T10:18:21Z2021-06-25T10:18:21Z2021-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1016/j.jelechem.2020.114928Journal of Electroanalytical Chemistry, v. 880.1572-6657http://hdl.handle.net/11449/20561410.1016/j.jelechem.2020.1149282-s2.0-85097901017Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Electroanalytical Chemistryinfo:eu-repo/semantics/openAccess2021-10-22T12:11:06Zoai:repositorio.unesp.br:11449/205614Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T22:36:33.527209Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation |
title |
Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation |
spellingShingle |
Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation Oliveira, Yuri A. [UNESP] Electrocatalysis Electrochemical impedance Metallopolymer Water oxidation Water splitting |
title_short |
Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation |
title_full |
Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation |
title_fullStr |
Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation |
title_full_unstemmed |
Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation |
title_sort |
Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation |
author |
Oliveira, Yuri A. [UNESP] |
author_facet |
Oliveira, Yuri A. [UNESP] Olean-Oliveira, André [UNESP] Teixeira, Marcos F.S. [UNESP] |
author_role |
author |
author2 |
Olean-Oliveira, André [UNESP] Teixeira, Marcos F.S. [UNESP] |
author2_role |
author author |
dc.contributor.none.fl_str_mv |
Universidade Estadual Paulista (Unesp) |
dc.contributor.author.fl_str_mv |
Oliveira, Yuri A. [UNESP] Olean-Oliveira, André [UNESP] Teixeira, Marcos F.S. [UNESP] |
dc.subject.por.fl_str_mv |
Electrocatalysis Electrochemical impedance Metallopolymer Water oxidation Water splitting |
topic |
Electrocatalysis Electrochemical impedance Metallopolymer Water oxidation Water splitting |
description |
We have developed electrocatalytic platforms based on palladium metallopolymer-graphene for the water splitting reaction. The platforms presented a low potential for the water oxidation reaction. By cyclic voltammetry and electrochemical impedance spectroscopy (EIS), the interfacial phenomena were investigated, allowing us to obtain important results that helped to determine kinetic and mechanistic information. The studies revealed that the introduction of graphene in the metallopolymer matrix increased the turnover frequency (TOF) value. Analysis of the Tafel plots obtained from the EIS data also revealed a change in the reaction mechanism after the introduction of graphene. The new platform demonstrated its applicability in the water splitting reaction for use in fuel cells. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-06-25T10:18:21Z 2021-06-25T10:18:21Z 2021-01-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1016/j.jelechem.2020.114928 Journal of Electroanalytical Chemistry, v. 880. 1572-6657 http://hdl.handle.net/11449/205614 10.1016/j.jelechem.2020.114928 2-s2.0-85097901017 |
url |
http://dx.doi.org/10.1016/j.jelechem.2020.114928 http://hdl.handle.net/11449/205614 |
identifier_str_mv |
Journal of Electroanalytical Chemistry, v. 880. 1572-6657 10.1016/j.jelechem.2020.114928 2-s2.0-85097901017 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Journal of Electroanalytical Chemistry |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808129442552217600 |