Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation

Detalhes bibliográficos
Autor(a) principal: Oliveira, Yuri A. [UNESP]
Data de Publicação: 2021
Outros Autores: Olean-Oliveira, André [UNESP], Teixeira, Marcos F.S. [UNESP]
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1016/j.jelechem.2020.114928
http://hdl.handle.net/11449/205614
Resumo: We have developed electrocatalytic platforms based on palladium metallopolymer-graphene for the water splitting reaction. The platforms presented a low potential for the water oxidation reaction. By cyclic voltammetry and electrochemical impedance spectroscopy (EIS), the interfacial phenomena were investigated, allowing us to obtain important results that helped to determine kinetic and mechanistic information. The studies revealed that the introduction of graphene in the metallopolymer matrix increased the turnover frequency (TOF) value. Analysis of the Tafel plots obtained from the EIS data also revealed a change in the reaction mechanism after the introduction of graphene. The new platform demonstrated its applicability in the water splitting reaction for use in fuel cells.
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spelling Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidationElectrocatalysisElectrochemical impedanceMetallopolymerWater oxidationWater splittingWe have developed electrocatalytic platforms based on palladium metallopolymer-graphene for the water splitting reaction. The platforms presented a low potential for the water oxidation reaction. By cyclic voltammetry and electrochemical impedance spectroscopy (EIS), the interfacial phenomena were investigated, allowing us to obtain important results that helped to determine kinetic and mechanistic information. The studies revealed that the introduction of graphene in the metallopolymer matrix increased the turnover frequency (TOF) value. Analysis of the Tafel plots obtained from the EIS data also revealed a change in the reaction mechanism after the introduction of graphene. The new platform demonstrated its applicability in the water splitting reaction for use in fuel cells.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Department of Chemistry and Biochemistry School of Science and Technology - Sao Paulo State University (UNESP), Rua Roberto Simonsen 305Department of Chemistry and Biochemistry School of Science and Technology - Sao Paulo State University (UNESP), Rua Roberto Simonsen 305FAPESP: 2016/09017-1CNPq: 301298/2017-3CAPES: 88882.434480/2019-01Universidade Estadual Paulista (Unesp)Oliveira, Yuri A. [UNESP]Olean-Oliveira, André [UNESP]Teixeira, Marcos F.S. [UNESP]2021-06-25T10:18:21Z2021-06-25T10:18:21Z2021-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1016/j.jelechem.2020.114928Journal of Electroanalytical Chemistry, v. 880.1572-6657http://hdl.handle.net/11449/20561410.1016/j.jelechem.2020.1149282-s2.0-85097901017Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Electroanalytical Chemistryinfo:eu-repo/semantics/openAccess2021-10-22T12:11:06Zoai:repositorio.unesp.br:11449/205614Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462021-10-22T12:11:06Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation
title Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation
spellingShingle Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation
Oliveira, Yuri A. [UNESP]
Electrocatalysis
Electrochemical impedance
Metallopolymer
Water oxidation
Water splitting
title_short Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation
title_full Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation
title_fullStr Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation
title_full_unstemmed Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation
title_sort Short communication: Molecular architecture based on palladium-salen complex/graphene for low potential water oxidation
author Oliveira, Yuri A. [UNESP]
author_facet Oliveira, Yuri A. [UNESP]
Olean-Oliveira, André [UNESP]
Teixeira, Marcos F.S. [UNESP]
author_role author
author2 Olean-Oliveira, André [UNESP]
Teixeira, Marcos F.S. [UNESP]
author2_role author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (Unesp)
dc.contributor.author.fl_str_mv Oliveira, Yuri A. [UNESP]
Olean-Oliveira, André [UNESP]
Teixeira, Marcos F.S. [UNESP]
dc.subject.por.fl_str_mv Electrocatalysis
Electrochemical impedance
Metallopolymer
Water oxidation
Water splitting
topic Electrocatalysis
Electrochemical impedance
Metallopolymer
Water oxidation
Water splitting
description We have developed electrocatalytic platforms based on palladium metallopolymer-graphene for the water splitting reaction. The platforms presented a low potential for the water oxidation reaction. By cyclic voltammetry and electrochemical impedance spectroscopy (EIS), the interfacial phenomena were investigated, allowing us to obtain important results that helped to determine kinetic and mechanistic information. The studies revealed that the introduction of graphene in the metallopolymer matrix increased the turnover frequency (TOF) value. Analysis of the Tafel plots obtained from the EIS data also revealed a change in the reaction mechanism after the introduction of graphene. The new platform demonstrated its applicability in the water splitting reaction for use in fuel cells.
publishDate 2021
dc.date.none.fl_str_mv 2021-06-25T10:18:21Z
2021-06-25T10:18:21Z
2021-01-01
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1016/j.jelechem.2020.114928
Journal of Electroanalytical Chemistry, v. 880.
1572-6657
http://hdl.handle.net/11449/205614
10.1016/j.jelechem.2020.114928
2-s2.0-85097901017
url http://dx.doi.org/10.1016/j.jelechem.2020.114928
http://hdl.handle.net/11449/205614
identifier_str_mv Journal of Electroanalytical Chemistry, v. 880.
1572-6657
10.1016/j.jelechem.2020.114928
2-s2.0-85097901017
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Journal of Electroanalytical Chemistry
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1799965575834763264

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