Espectroscopia óptica de vidros fluoroindatos dopados com íons Er3+ e Yb3+
Autor(a) principal: | |
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Data de Publicação: | 1998 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Repositório Institucional da UNESP |
DOI: | 10.1590/S0100-40421998000400028 |
Texto Completo: | http://dx.doi.org/10.1590/S0100-40421998000400028 http://hdl.handle.net/11449/27561 |
Resumo: | Optical spectroscopy in the 400-1700nm wavelength range was performed on rare earth doped heavy metal fluoride (HMF) glasses. In the present work In-based fluoride glasses with a fixed 2 mol % YbF3 concentration and an ErF3 content ranging from 0 to 8 mol % were investigated. According to the experimental spectroscopic data a dependence in the absorption coefficient, the photoluminescence intensity and in the radiative lifetime could be verified as a function of the ErF3 content. In addition, at liquid nitrogen temperature, light emission corresponding to indirect transitions in the infrared energy range could be easily observed as a consequence of the low phonon frequency characteristic of this class of fluoride glasses. For all the studied compositions, strong upconversion to the green and red light was observed by pumping these Er3+- and Yb3+-doped HMF glasses with 790 and 980nm photon sources. |
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Repositório Institucional da UNESP |
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spelling |
Espectroscopia óptica de vidros fluoroindatos dopados com íons Er3+ e Yb3+Optical spectroscopy of in-based fluoride glasses doped with Er3+ and Yb3+ ionsoptical spectroscopyrare earth doped glassesupconversionOptical spectroscopy in the 400-1700nm wavelength range was performed on rare earth doped heavy metal fluoride (HMF) glasses. In the present work In-based fluoride glasses with a fixed 2 mol % YbF3 concentration and an ErF3 content ranging from 0 to 8 mol % were investigated. According to the experimental spectroscopic data a dependence in the absorption coefficient, the photoluminescence intensity and in the radiative lifetime could be verified as a function of the ErF3 content. In addition, at liquid nitrogen temperature, light emission corresponding to indirect transitions in the infrared energy range could be easily observed as a consequence of the low phonon frequency characteristic of this class of fluoride glasses. For all the studied compositions, strong upconversion to the green and red light was observed by pumping these Er3+- and Yb3+-doped HMF glasses with 790 and 980nm photon sources.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Universidade de São Paulo Instituto de Física de São CarlosUniversidade Estadual de São Paulo Instituto de QuímicaSociedade Brasileira de QuímicaUniversidade de São Paulo (USP)Universidade Estadual Paulista (Unesp)Ribeiro, C. T. M.Zanatta, A. R.Sartori, J.Nunes, L. A. O.Messaddeq, Younes [UNESP]2014-05-20T15:10:16Z2014-05-20T15:10:16Z1998-07-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article521-525application/pdfhttp://dx.doi.org/10.1590/S0100-40421998000400028Química Nova. Sociedade Brasileira de Química, v. 21, n. 4, p. 521-525, 1998.0100-4042http://hdl.handle.net/11449/2756110.1590/S0100-40421998000400028S0100-40421998000400028S0100-40421998000400028.pdf2998503841917815SciELOreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPporQuímica Nova0.6460,255info:eu-repo/semantics/openAccess2024-01-28T06:43:35Zoai:repositorio.unesp.br:11449/27561Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-06T00:06:57.686164Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Espectroscopia óptica de vidros fluoroindatos dopados com íons Er3+ e Yb3+ Optical spectroscopy of in-based fluoride glasses doped with Er3+ and Yb3+ ions |
title |
Espectroscopia óptica de vidros fluoroindatos dopados com íons Er3+ e Yb3+ |
spellingShingle |
Espectroscopia óptica de vidros fluoroindatos dopados com íons Er3+ e Yb3+ Espectroscopia óptica de vidros fluoroindatos dopados com íons Er3+ e Yb3+ Ribeiro, C. T. M. optical spectroscopy rare earth doped glasses upconversion Ribeiro, C. T. M. optical spectroscopy rare earth doped glasses upconversion |
title_short |
Espectroscopia óptica de vidros fluoroindatos dopados com íons Er3+ e Yb3+ |
title_full |
Espectroscopia óptica de vidros fluoroindatos dopados com íons Er3+ e Yb3+ |
title_fullStr |
Espectroscopia óptica de vidros fluoroindatos dopados com íons Er3+ e Yb3+ Espectroscopia óptica de vidros fluoroindatos dopados com íons Er3+ e Yb3+ |
title_full_unstemmed |
Espectroscopia óptica de vidros fluoroindatos dopados com íons Er3+ e Yb3+ Espectroscopia óptica de vidros fluoroindatos dopados com íons Er3+ e Yb3+ |
title_sort |
Espectroscopia óptica de vidros fluoroindatos dopados com íons Er3+ e Yb3+ |
author |
Ribeiro, C. T. M. |
author_facet |
Ribeiro, C. T. M. Ribeiro, C. T. M. Zanatta, A. R. Sartori, J. Nunes, L. A. O. Messaddeq, Younes [UNESP] Zanatta, A. R. Sartori, J. Nunes, L. A. O. Messaddeq, Younes [UNESP] |
author_role |
author |
author2 |
Zanatta, A. R. Sartori, J. Nunes, L. A. O. Messaddeq, Younes [UNESP] |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
Universidade de São Paulo (USP) Universidade Estadual Paulista (Unesp) |
dc.contributor.author.fl_str_mv |
Ribeiro, C. T. M. Zanatta, A. R. Sartori, J. Nunes, L. A. O. Messaddeq, Younes [UNESP] |
dc.subject.por.fl_str_mv |
optical spectroscopy rare earth doped glasses upconversion |
topic |
optical spectroscopy rare earth doped glasses upconversion |
description |
Optical spectroscopy in the 400-1700nm wavelength range was performed on rare earth doped heavy metal fluoride (HMF) glasses. In the present work In-based fluoride glasses with a fixed 2 mol % YbF3 concentration and an ErF3 content ranging from 0 to 8 mol % were investigated. According to the experimental spectroscopic data a dependence in the absorption coefficient, the photoluminescence intensity and in the radiative lifetime could be verified as a function of the ErF3 content. In addition, at liquid nitrogen temperature, light emission corresponding to indirect transitions in the infrared energy range could be easily observed as a consequence of the low phonon frequency characteristic of this class of fluoride glasses. For all the studied compositions, strong upconversion to the green and red light was observed by pumping these Er3+- and Yb3+-doped HMF glasses with 790 and 980nm photon sources. |
publishDate |
1998 |
dc.date.none.fl_str_mv |
1998-07-01 2014-05-20T15:10:16Z 2014-05-20T15:10:16Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1590/S0100-40421998000400028 Química Nova. Sociedade Brasileira de Química, v. 21, n. 4, p. 521-525, 1998. 0100-4042 http://hdl.handle.net/11449/27561 10.1590/S0100-40421998000400028 S0100-40421998000400028 S0100-40421998000400028.pdf 2998503841917815 |
url |
http://dx.doi.org/10.1590/S0100-40421998000400028 http://hdl.handle.net/11449/27561 |
identifier_str_mv |
Química Nova. Sociedade Brasileira de Química, v. 21, n. 4, p. 521-525, 1998. 0100-4042 10.1590/S0100-40421998000400028 S0100-40421998000400028 S0100-40421998000400028.pdf 2998503841917815 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
Química Nova 0.646 0,255 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
521-525 application/pdf |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
SciELO reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1822182247435862016 |
dc.identifier.doi.none.fl_str_mv |
10.1590/S0100-40421998000400028 |