Biodegradation of additive PHBV/PP-co-PE films buried in soil

Detalhes bibliográficos
Autor(a) principal: Rani-Borges, Barbara [UNESP]
Data de Publicação: 2016
Outros Autores: Faria, Adriano Uemura [UNESP], De Campos, Adriana, Gonçalves, Suely Patricia Costa [UNESP], Martins-Franchetti, Sandra Mara [UNESP]
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1590/0104-1428.2127
http://hdl.handle.net/11449/173220
Resumo: There is considerable concern about the impact plastic materials have on the environment due to their durability and resistance to degradation. The use of pro-oxidant additives in the polymer films could be a viable way to decrease the harmful effects of these discarded materials. In this study, films of PHBV/PP-co-PE (80/20 w/w) and PHBV/PP-co-PE/add (80/19/1 w/w/w) (with pro-oxidant additive) were employed to verify the influence of the additive on the biodegradation of these films in the soil. These films were obtained by melting the pellets in a press at 180 °C which were buried in soil columns for 3 and 6 months. Some samples were also heated before being buried in soil. The biodegradation is higher for the additive blend buried for 3 months than for the pre-heated blend. After 6 months the blend buried and heated/buried was completely degraded in soil. The effect of the additive, on chain oxidation, is more time-dependant than heat-dependant.
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spelling Biodegradation of additive PHBV/PP-co-PE films buried in soilAdditiveBiodegradationBlendPHBV/PP-co-PESoilThere is considerable concern about the impact plastic materials have on the environment due to their durability and resistance to degradation. The use of pro-oxidant additives in the polymer films could be a viable way to decrease the harmful effects of these discarded materials. In this study, films of PHBV/PP-co-PE (80/20 w/w) and PHBV/PP-co-PE/add (80/19/1 w/w/w) (with pro-oxidant additive) were employed to verify the influence of the additive on the biodegradation of these films in the soil. These films were obtained by melting the pellets in a press at 180 °C which were buried in soil columns for 3 and 6 months. Some samples were also heated before being buried in soil. The biodegradation is higher for the additive blend buried for 3 months than for the pre-heated blend. After 6 months the blend buried and heated/buried was completely degraded in soil. The effect of the additive, on chain oxidation, is more time-dependant than heat-dependant.Polymer Treatment Laboratory-LTP Biochemistry and Microbiology Department Universidade Estadual Paulista - UNESPNational Nanotechnology Laboratory for Agriculture - LNNA Embrapa Instrumentação - EMBRAPAPolymer Treatment Laboratory-LTP Biochemistry and Microbiology Department Universidade Estadual Paulista - UNESPUniversidade Estadual Paulista (Unesp)Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA)Rani-Borges, Barbara [UNESP]Faria, Adriano Uemura [UNESP]De Campos, AdrianaGonçalves, Suely Patricia Costa [UNESP]Martins-Franchetti, Sandra Mara [UNESP]2018-12-11T17:04:11Z2018-12-11T17:04:11Z2016-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article161-167application/pdfhttp://dx.doi.org/10.1590/0104-1428.2127Polimeros, v. 26, n. 2, p. 161-167, 2016.0104-1428http://hdl.handle.net/11449/17322010.1590/0104-1428.2127S0104-142820160002001612-s2.0-84978424171S0104-14282016000200161.pdfScopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengPolimeros0,244info:eu-repo/semantics/openAccess2023-10-09T06:09:51Zoai:repositorio.unesp.br:11449/173220Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T14:29:40.027933Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Biodegradation of additive PHBV/PP-co-PE films buried in soil
title Biodegradation of additive PHBV/PP-co-PE films buried in soil
spellingShingle Biodegradation of additive PHBV/PP-co-PE films buried in soil
Rani-Borges, Barbara [UNESP]
Additive
Biodegradation
Blend
PHBV/PP-co-PE
Soil
title_short Biodegradation of additive PHBV/PP-co-PE films buried in soil
title_full Biodegradation of additive PHBV/PP-co-PE films buried in soil
title_fullStr Biodegradation of additive PHBV/PP-co-PE films buried in soil
title_full_unstemmed Biodegradation of additive PHBV/PP-co-PE films buried in soil
title_sort Biodegradation of additive PHBV/PP-co-PE films buried in soil
author Rani-Borges, Barbara [UNESP]
author_facet Rani-Borges, Barbara [UNESP]
Faria, Adriano Uemura [UNESP]
De Campos, Adriana
Gonçalves, Suely Patricia Costa [UNESP]
Martins-Franchetti, Sandra Mara [UNESP]
author_role author
author2 Faria, Adriano Uemura [UNESP]
De Campos, Adriana
Gonçalves, Suely Patricia Costa [UNESP]
Martins-Franchetti, Sandra Mara [UNESP]
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (Unesp)
Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA)
dc.contributor.author.fl_str_mv Rani-Borges, Barbara [UNESP]
Faria, Adriano Uemura [UNESP]
De Campos, Adriana
Gonçalves, Suely Patricia Costa [UNESP]
Martins-Franchetti, Sandra Mara [UNESP]
dc.subject.por.fl_str_mv Additive
Biodegradation
Blend
PHBV/PP-co-PE
Soil
topic Additive
Biodegradation
Blend
PHBV/PP-co-PE
Soil
description There is considerable concern about the impact plastic materials have on the environment due to their durability and resistance to degradation. The use of pro-oxidant additives in the polymer films could be a viable way to decrease the harmful effects of these discarded materials. In this study, films of PHBV/PP-co-PE (80/20 w/w) and PHBV/PP-co-PE/add (80/19/1 w/w/w) (with pro-oxidant additive) were employed to verify the influence of the additive on the biodegradation of these films in the soil. These films were obtained by melting the pellets in a press at 180 °C which were buried in soil columns for 3 and 6 months. Some samples were also heated before being buried in soil. The biodegradation is higher for the additive blend buried for 3 months than for the pre-heated blend. After 6 months the blend buried and heated/buried was completely degraded in soil. The effect of the additive, on chain oxidation, is more time-dependant than heat-dependant.
publishDate 2016
dc.date.none.fl_str_mv 2016-01-01
2018-12-11T17:04:11Z
2018-12-11T17:04:11Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1590/0104-1428.2127
Polimeros, v. 26, n. 2, p. 161-167, 2016.
0104-1428
http://hdl.handle.net/11449/173220
10.1590/0104-1428.2127
S0104-14282016000200161
2-s2.0-84978424171
S0104-14282016000200161.pdf
url http://dx.doi.org/10.1590/0104-1428.2127
http://hdl.handle.net/11449/173220
identifier_str_mv Polimeros, v. 26, n. 2, p. 161-167, 2016.
0104-1428
10.1590/0104-1428.2127
S0104-14282016000200161
2-s2.0-84978424171
S0104-14282016000200161.pdf
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Polimeros
0,244
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 161-167
application/pdf
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1808128367770206208