Enhanced extraction of arsenic and cadmium from environmental samples using a natural deep eutectic solvent and determination by inductively coupled plasma mass spectrometry

Detalhes bibliográficos
Autor(a) principal: Moreira, Luana S.
Data de Publicação: 2020
Outros Autores: Santana, Ana P. R. [UNESP], Costa, Floriatan S., Vera, Josiane B. [UNESP], Gonzalez, Mario H. [UNESP], Silva, Erik G. P. da, Amaral, Clarice D. B.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1080/03067319.2020.1826460
http://hdl.handle.net/11449/209490
Resumo: A natural deep eutectic solvent (NADES) synthesised from malic acid, xylitol, and water was used as a solvent in ultrasound-assisted extraction (UAE) for the determination of As and Cd in fish and shellfish samples by inductively coupled plasma mass spectrometry. The formation of the solvent was confirmed by infrared spectroscopy analysis, which showed the presence of hydrogen bonds between the components. Evaluation was made of elemental determinations performed using standard and kinetic energy discrimination (KED) modes. Higher sensitivity was observed using KED mode, which could be attributed to charge transfer between carbon and the analytes when the NADES introduced into the plasma. The detection limits were 12.7 and 0.100 mu g kg(-1)for As and Cd, respectively, and the accuracy of the extraction procedure was assessed by comparing methods. The Cd concentrations in the fish and shellfish samples were below the limits of quantification, while the As concentrations varied between 1.88 and 12.0 mu g g(-1), exceeding the maximum values recommended by regulatory agencies.
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spelling Enhanced extraction of arsenic and cadmium from environmental samples using a natural deep eutectic solvent and determination by inductively coupled plasma mass spectrometryGreen solventsnatural deep eutectic solventultrasound-assisted extractionplasma-based techniqueA natural deep eutectic solvent (NADES) synthesised from malic acid, xylitol, and water was used as a solvent in ultrasound-assisted extraction (UAE) for the determination of As and Cd in fish and shellfish samples by inductively coupled plasma mass spectrometry. The formation of the solvent was confirmed by infrared spectroscopy analysis, which showed the presence of hydrogen bonds between the components. Evaluation was made of elemental determinations performed using standard and kinetic energy discrimination (KED) modes. Higher sensitivity was observed using KED mode, which could be attributed to charge transfer between carbon and the analytes when the NADES introduced into the plasma. The detection limits were 12.7 and 0.100 mu g kg(-1)for As and Cd, respectively, and the accuracy of the extraction procedure was assessed by comparing methods. The Cd concentrations in the fish and shellfish samples were below the limits of quantification, while the As concentrations varied between 1.88 and 12.0 mu g g(-1), exceeding the maximum values recommended by regulatory agencies.Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Univ Fed Parana, Dept Chem, Spectrometry Sensors & Biosensors Lab, Curitiba, Parana, BrazilSao Paulo State Univ, Natl Inst Alternat Technol Detect Toxicol Evalua, Dept Chem & Environm Sci, Sao Jose Do Rio Preto, SP, BrazilUniv Estadual Santa Cruz, Dept Exact & Technol Sci, Ilheus, BA, BrazilSao Paulo State Univ, Natl Inst Alternat Technol Detect Toxicol Evalua, Dept Chem & Environm Sci, Sao Jose Do Rio Preto, SP, BrazilCNPq: 465571/2014-0CNPq: 421694/2018-1CNPq: 306698/2019-6FAPESP: 2014/50945-4FAPESP: 2015/08873-9FAPESP: 2017/18531-3FAPESP: 2019/22113-8CAPES: 001CAPES: CAPES 88887136426/2017/00Taylor & Francis LtdUniv Fed ParanaUniversidade Estadual Paulista (Unesp)Univ Estadual Santa CruzMoreira, Luana S.Santana, Ana P. R. [UNESP]Costa, Floriatan S.Vera, Josiane B. [UNESP]Gonzalez, Mario H. [UNESP]Silva, Erik G. P. daAmaral, Clarice D. B.2021-06-25T12:20:14Z2021-06-25T12:20:14Z2020-09-29info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article12http://dx.doi.org/10.1080/03067319.2020.1826460International Journal Of Environmental Analytical Chemistry. Abingdon: Taylor & Francis Ltd, 12 p., 2020.0306-7319http://hdl.handle.net/11449/20949010.1080/03067319.2020.1826460WOS:000573320800001Web of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengInternational Journal Of Environmental Analytical Chemistryinfo:eu-repo/semantics/openAccess2021-10-23T19:28:14Zoai:repositorio.unesp.br:11449/209490Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462021-10-23T19:28:14Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Enhanced extraction of arsenic and cadmium from environmental samples using a natural deep eutectic solvent and determination by inductively coupled plasma mass spectrometry
title Enhanced extraction of arsenic and cadmium from environmental samples using a natural deep eutectic solvent and determination by inductively coupled plasma mass spectrometry
spellingShingle Enhanced extraction of arsenic and cadmium from environmental samples using a natural deep eutectic solvent and determination by inductively coupled plasma mass spectrometry
Moreira, Luana S.
Green solvents
natural deep eutectic solvent
ultrasound-assisted extraction
plasma-based technique
title_short Enhanced extraction of arsenic and cadmium from environmental samples using a natural deep eutectic solvent and determination by inductively coupled plasma mass spectrometry
title_full Enhanced extraction of arsenic and cadmium from environmental samples using a natural deep eutectic solvent and determination by inductively coupled plasma mass spectrometry
title_fullStr Enhanced extraction of arsenic and cadmium from environmental samples using a natural deep eutectic solvent and determination by inductively coupled plasma mass spectrometry
title_full_unstemmed Enhanced extraction of arsenic and cadmium from environmental samples using a natural deep eutectic solvent and determination by inductively coupled plasma mass spectrometry
title_sort Enhanced extraction of arsenic and cadmium from environmental samples using a natural deep eutectic solvent and determination by inductively coupled plasma mass spectrometry
author Moreira, Luana S.
author_facet Moreira, Luana S.
Santana, Ana P. R. [UNESP]
Costa, Floriatan S.
Vera, Josiane B. [UNESP]
Gonzalez, Mario H. [UNESP]
Silva, Erik G. P. da
Amaral, Clarice D. B.
author_role author
author2 Santana, Ana P. R. [UNESP]
Costa, Floriatan S.
Vera, Josiane B. [UNESP]
Gonzalez, Mario H. [UNESP]
Silva, Erik G. P. da
Amaral, Clarice D. B.
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Univ Fed Parana
Universidade Estadual Paulista (Unesp)
Univ Estadual Santa Cruz
dc.contributor.author.fl_str_mv Moreira, Luana S.
Santana, Ana P. R. [UNESP]
Costa, Floriatan S.
Vera, Josiane B. [UNESP]
Gonzalez, Mario H. [UNESP]
Silva, Erik G. P. da
Amaral, Clarice D. B.
dc.subject.por.fl_str_mv Green solvents
natural deep eutectic solvent
ultrasound-assisted extraction
plasma-based technique
topic Green solvents
natural deep eutectic solvent
ultrasound-assisted extraction
plasma-based technique
description A natural deep eutectic solvent (NADES) synthesised from malic acid, xylitol, and water was used as a solvent in ultrasound-assisted extraction (UAE) for the determination of As and Cd in fish and shellfish samples by inductively coupled plasma mass spectrometry. The formation of the solvent was confirmed by infrared spectroscopy analysis, which showed the presence of hydrogen bonds between the components. Evaluation was made of elemental determinations performed using standard and kinetic energy discrimination (KED) modes. Higher sensitivity was observed using KED mode, which could be attributed to charge transfer between carbon and the analytes when the NADES introduced into the plasma. The detection limits were 12.7 and 0.100 mu g kg(-1)for As and Cd, respectively, and the accuracy of the extraction procedure was assessed by comparing methods. The Cd concentrations in the fish and shellfish samples were below the limits of quantification, while the As concentrations varied between 1.88 and 12.0 mu g g(-1), exceeding the maximum values recommended by regulatory agencies.
publishDate 2020
dc.date.none.fl_str_mv 2020-09-29
2021-06-25T12:20:14Z
2021-06-25T12:20:14Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1080/03067319.2020.1826460
International Journal Of Environmental Analytical Chemistry. Abingdon: Taylor & Francis Ltd, 12 p., 2020.
0306-7319
http://hdl.handle.net/11449/209490
10.1080/03067319.2020.1826460
WOS:000573320800001
url http://dx.doi.org/10.1080/03067319.2020.1826460
http://hdl.handle.net/11449/209490
identifier_str_mv International Journal Of Environmental Analytical Chemistry. Abingdon: Taylor & Francis Ltd, 12 p., 2020.
0306-7319
10.1080/03067319.2020.1826460
WOS:000573320800001
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv International Journal Of Environmental Analytical Chemistry
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 12
dc.publisher.none.fl_str_mv Taylor & Francis Ltd
publisher.none.fl_str_mv Taylor & Francis Ltd
dc.source.none.fl_str_mv Web of Science
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
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