3D-printing pen from valorization of pine cone residues as reinforcement in acrylonitrile butadiene styrene (ABS): Microstructure and thermal properties
Autor(a) principal: | |
---|---|
Data de Publicação: | 2021 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1177/08927057211012735 http://hdl.handle.net/11449/207709 |
Resumo: | This study presents an alternative to reducing solid waste, improving the concept of green composites. So, the use of fibers from pine cone as reinforcement in acrylonitrile butadiene styrene (ABS) composites filaments as a potential for 3D pen was evaluated. The effect of the treatment chemical (alkaline and bleaching) was studied. A thermokinetic mixer processed the ABS/pine cone fibers (2 and 5% wt.) composites. After, the filaments were prepared by mini extruder and printing 3D pen. Filaments were characterized by Scanning Electron Microscopy (SEM), Thermogravimetry (TGA), and Infrared Spectroscopy (FTIR). Filaments revealed homogeneous diameters. The addition of 2 and 5% wt. fiber not significantly influenced the filament’s diameter and density. On the other hand, thermal stability and morphological analysis influenced the type of fiber (raw, treated, and bleached). The addition of bleached fibers to ABS increased composites’ thermal stability compared to other fibers (treated and raw). Also, inserting bleached fibers was perceptible a uniformly distributed and embedded throughout the wire cross-section compared to treated and raw fiber added to ABS due to good interfacial bonding. Results indicated that fibers were hydrogen-bonded to ABS chains and increased the filament’s density. So, it is possible to affirm that the addition of fibers from pine cone to ABS thermally improved and can be a low-cost feedstock for printing 3D pen applications. Despite the low concentration of natural fiber on the composites investigated in this work, the successful obtainment of ABS reinforced with biodegradable natural fiber, compromising neither its thermal properties nor its processability and printability, opens the possibility for future work investigation into a composite with larger fiber content. |
id |
UNSP_612562076315722630d75794136ce0ef |
---|---|
oai_identifier_str |
oai:repositorio.unesp.br:11449/207709 |
network_acronym_str |
UNSP |
network_name_str |
Repositório Institucional da UNESP |
repository_id_str |
2946 |
spelling |
3D-printing pen from valorization of pine cone residues as reinforcement in acrylonitrile butadiene styrene (ABS): Microstructure and thermal properties3D printingAcetosolv/bleachingcomposites filamentsmicrostructural analysispine conethermal propertiesThis study presents an alternative to reducing solid waste, improving the concept of green composites. So, the use of fibers from pine cone as reinforcement in acrylonitrile butadiene styrene (ABS) composites filaments as a potential for 3D pen was evaluated. The effect of the treatment chemical (alkaline and bleaching) was studied. A thermokinetic mixer processed the ABS/pine cone fibers (2 and 5% wt.) composites. After, the filaments were prepared by mini extruder and printing 3D pen. Filaments were characterized by Scanning Electron Microscopy (SEM), Thermogravimetry (TGA), and Infrared Spectroscopy (FTIR). Filaments revealed homogeneous diameters. The addition of 2 and 5% wt. fiber not significantly influenced the filament’s diameter and density. On the other hand, thermal stability and morphological analysis influenced the type of fiber (raw, treated, and bleached). The addition of bleached fibers to ABS increased composites’ thermal stability compared to other fibers (treated and raw). Also, inserting bleached fibers was perceptible a uniformly distributed and embedded throughout the wire cross-section compared to treated and raw fiber added to ABS due to good interfacial bonding. Results indicated that fibers were hydrogen-bonded to ABS chains and increased the filament’s density. So, it is possible to affirm that the addition of fibers from pine cone to ABS thermally improved and can be a low-cost feedstock for printing 3D pen applications. Despite the low concentration of natural fiber on the composites investigated in this work, the successful obtainment of ABS reinforced with biodegradable natural fiber, compromising neither its thermal properties nor its processability and printability, opens the possibility for future work investigation into a composite with larger fiber content.Material Science and Engineering Department University of California DavisDepartment of Materials and Technology School of Engineering Sao Paulo State University (UNESP), GuaratinguetáResearch Center on Biotechnology Araraquara University, AraraquaraTereza Dávila University Center, LorenaDepartment of Mechanic and Energy State University of Rio de Janeiro (UERJ)Department of Materials and Technology School of Engineering Sao Paulo State University (UNESP), GuaratinguetáUniversity of California DavisUniversidade Estadual Paulista (Unesp)Araraquara UniversityTereza Dávila University CenterUniversidade do Estado do Rio de Janeiro (UERJ)Costa, Isabella LMPereira, Paulo HF [UNESP]Claro, Amanda MariaAmaral, Nayara Cavichiolli doBarud, Hernane da SilvaRibeiro, Rosinei BatistaMulinari, Daniella Regina2021-06-25T10:59:40Z2021-06-25T10:59:40Z2021-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1177/08927057211012735Journal of Thermoplastic Composite Materials.1530-79800892-7057http://hdl.handle.net/11449/20770910.1177/089270572110127352-s2.0-85105482357Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Thermoplastic Composite Materialsinfo:eu-repo/semantics/openAccess2021-10-23T17:45:56Zoai:repositorio.unesp.br:11449/207709Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462021-10-23T17:45:56Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
3D-printing pen from valorization of pine cone residues as reinforcement in acrylonitrile butadiene styrene (ABS): Microstructure and thermal properties |
title |
3D-printing pen from valorization of pine cone residues as reinforcement in acrylonitrile butadiene styrene (ABS): Microstructure and thermal properties |
spellingShingle |
3D-printing pen from valorization of pine cone residues as reinforcement in acrylonitrile butadiene styrene (ABS): Microstructure and thermal properties Costa, Isabella LM 3D printing Acetosolv/bleaching composites filaments microstructural analysis pine cone thermal properties |
title_short |
3D-printing pen from valorization of pine cone residues as reinforcement in acrylonitrile butadiene styrene (ABS): Microstructure and thermal properties |
title_full |
3D-printing pen from valorization of pine cone residues as reinforcement in acrylonitrile butadiene styrene (ABS): Microstructure and thermal properties |
title_fullStr |
3D-printing pen from valorization of pine cone residues as reinforcement in acrylonitrile butadiene styrene (ABS): Microstructure and thermal properties |
title_full_unstemmed |
3D-printing pen from valorization of pine cone residues as reinforcement in acrylonitrile butadiene styrene (ABS): Microstructure and thermal properties |
title_sort |
3D-printing pen from valorization of pine cone residues as reinforcement in acrylonitrile butadiene styrene (ABS): Microstructure and thermal properties |
author |
Costa, Isabella LM |
author_facet |
Costa, Isabella LM Pereira, Paulo HF [UNESP] Claro, Amanda Maria Amaral, Nayara Cavichiolli do Barud, Hernane da Silva Ribeiro, Rosinei Batista Mulinari, Daniella Regina |
author_role |
author |
author2 |
Pereira, Paulo HF [UNESP] Claro, Amanda Maria Amaral, Nayara Cavichiolli do Barud, Hernane da Silva Ribeiro, Rosinei Batista Mulinari, Daniella Regina |
author2_role |
author author author author author author |
dc.contributor.none.fl_str_mv |
University of California Davis Universidade Estadual Paulista (Unesp) Araraquara University Tereza Dávila University Center Universidade do Estado do Rio de Janeiro (UERJ) |
dc.contributor.author.fl_str_mv |
Costa, Isabella LM Pereira, Paulo HF [UNESP] Claro, Amanda Maria Amaral, Nayara Cavichiolli do Barud, Hernane da Silva Ribeiro, Rosinei Batista Mulinari, Daniella Regina |
dc.subject.por.fl_str_mv |
3D printing Acetosolv/bleaching composites filaments microstructural analysis pine cone thermal properties |
topic |
3D printing Acetosolv/bleaching composites filaments microstructural analysis pine cone thermal properties |
description |
This study presents an alternative to reducing solid waste, improving the concept of green composites. So, the use of fibers from pine cone as reinforcement in acrylonitrile butadiene styrene (ABS) composites filaments as a potential for 3D pen was evaluated. The effect of the treatment chemical (alkaline and bleaching) was studied. A thermokinetic mixer processed the ABS/pine cone fibers (2 and 5% wt.) composites. After, the filaments were prepared by mini extruder and printing 3D pen. Filaments were characterized by Scanning Electron Microscopy (SEM), Thermogravimetry (TGA), and Infrared Spectroscopy (FTIR). Filaments revealed homogeneous diameters. The addition of 2 and 5% wt. fiber not significantly influenced the filament’s diameter and density. On the other hand, thermal stability and morphological analysis influenced the type of fiber (raw, treated, and bleached). The addition of bleached fibers to ABS increased composites’ thermal stability compared to other fibers (treated and raw). Also, inserting bleached fibers was perceptible a uniformly distributed and embedded throughout the wire cross-section compared to treated and raw fiber added to ABS due to good interfacial bonding. Results indicated that fibers were hydrogen-bonded to ABS chains and increased the filament’s density. So, it is possible to affirm that the addition of fibers from pine cone to ABS thermally improved and can be a low-cost feedstock for printing 3D pen applications. Despite the low concentration of natural fiber on the composites investigated in this work, the successful obtainment of ABS reinforced with biodegradable natural fiber, compromising neither its thermal properties nor its processability and printability, opens the possibility for future work investigation into a composite with larger fiber content. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-06-25T10:59:40Z 2021-06-25T10:59:40Z 2021-01-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1177/08927057211012735 Journal of Thermoplastic Composite Materials. 1530-7980 0892-7057 http://hdl.handle.net/11449/207709 10.1177/08927057211012735 2-s2.0-85105482357 |
url |
http://dx.doi.org/10.1177/08927057211012735 http://hdl.handle.net/11449/207709 |
identifier_str_mv |
Journal of Thermoplastic Composite Materials. 1530-7980 0892-7057 10.1177/08927057211012735 2-s2.0-85105482357 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Journal of Thermoplastic Composite Materials |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1799965371436892160 |