Supercapacitor Based on Nanostructured Multilayer Films Consisting of Polyelectrolyte/Graphene Oxide-MnO2-ZnO for Energy Storage Applications
Autor(a) principal: | |
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Data de Publicação: | 2022 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1002/pssa.202100871 http://hdl.handle.net/11449/239881 |
Resumo: | The development of new technologies has increased the demand for energy storage devices with high performance. In this sense, supercapacitors appear as a prominent alternative due to their high power density, fast charge–discharge time, environment friendly, and long-term cycle stability. Carbon materials and transition metal oxides have been reported as attractive materials to achieve supercapacitors with enhanced properties. This study investigates nanostructured films, using the layer-by-layer (LbL) method, consisting of MnO2-ZnO nanostructures embedded into reduced graphene oxide (rGO) and combined with polyallylamine hydrochloride (PAH) polyelectrolyte for supercapacitor applications. The film morphology and the incorporation of MnO2-ZnO nanostructures in rGO layers are analyzed by scanning electron microscopy images. The electrochemical properties are evaluated by cyclic voltammetry and galvanostatic charge–discharge measurements. A high capacitance is reached for a 20-bilayer PAH/rGO-MnO2-ZnO LbL film at a 1 mV s−1 and 1.15 A g−1 with values of 1650 F g−1 and 26 mF cm−2. Furthermore, the film exhibits high energy and power densities of 112.3 Wh kg−1 and 404.4 W kg−1, respectively, as well as high capacitive retention and cycle stability. These findings indicate the potential application of PAH/rGO-MnO2-ZnO LbL films as supercapacitor electrodes and envisage further studies of LbL nanostructured systems for energy storage applications. |
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Supercapacitor Based on Nanostructured Multilayer Films Consisting of Polyelectrolyte/Graphene Oxide-MnO2-ZnO for Energy Storage Applicationsenergy storage deviceslayer-by-layer filmsMnO2-ZnO nanostructuresreduced graphene oxidesupercapacitorsThe development of new technologies has increased the demand for energy storage devices with high performance. In this sense, supercapacitors appear as a prominent alternative due to their high power density, fast charge–discharge time, environment friendly, and long-term cycle stability. Carbon materials and transition metal oxides have been reported as attractive materials to achieve supercapacitors with enhanced properties. This study investigates nanostructured films, using the layer-by-layer (LbL) method, consisting of MnO2-ZnO nanostructures embedded into reduced graphene oxide (rGO) and combined with polyallylamine hydrochloride (PAH) polyelectrolyte for supercapacitor applications. The film morphology and the incorporation of MnO2-ZnO nanostructures in rGO layers are analyzed by scanning electron microscopy images. The electrochemical properties are evaluated by cyclic voltammetry and galvanostatic charge–discharge measurements. A high capacitance is reached for a 20-bilayer PAH/rGO-MnO2-ZnO LbL film at a 1 mV s−1 and 1.15 A g−1 with values of 1650 F g−1 and 26 mF cm−2. Furthermore, the film exhibits high energy and power densities of 112.3 Wh kg−1 and 404.4 W kg−1, respectively, as well as high capacitive retention and cycle stability. These findings indicate the potential application of PAH/rGO-MnO2-ZnO LbL films as supercapacitor electrodes and envisage further studies of LbL nanostructured systems for energy storage applications.Laboratory of Applied Nanomaterials and Nanostructures (LANNA) Institute of Exact Sciences Natural and Education Federal University of Triângulo Mineiro (UFTM), MGDepartment of Physical-Chemistry São Paulo State University (UNESP), SPDepartment of Physical-Chemistry São Paulo State University (UNESP), SPFederal University of Triângulo Mineiro (UFTM)Universidade Estadual Paulista (UNESP)Oliveira, Danilo A.Silva, Ranilson A. da[UNESP]Orlandi, Marcelo O. [UNESP]Siqueira, José R.2023-03-01T19:51:35Z2023-03-01T19:51:35Z2022-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1002/pssa.202100871Physica Status Solidi (A) Applications and Materials Science.1862-63191862-6300http://hdl.handle.net/11449/23988110.1002/pssa.2021008712-s2.0-85128202031Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengPhysica Status Solidi (A) Applications and Materials Scienceinfo:eu-repo/semantics/openAccess2023-03-01T19:51:35Zoai:repositorio.unesp.br:11449/239881Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462023-03-01T19:51:35Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Supercapacitor Based on Nanostructured Multilayer Films Consisting of Polyelectrolyte/Graphene Oxide-MnO2-ZnO for Energy Storage Applications |
title |
Supercapacitor Based on Nanostructured Multilayer Films Consisting of Polyelectrolyte/Graphene Oxide-MnO2-ZnO for Energy Storage Applications |
spellingShingle |
Supercapacitor Based on Nanostructured Multilayer Films Consisting of Polyelectrolyte/Graphene Oxide-MnO2-ZnO for Energy Storage Applications Oliveira, Danilo A. energy storage devices layer-by-layer films MnO2-ZnO nanostructures reduced graphene oxide supercapacitors |
title_short |
Supercapacitor Based on Nanostructured Multilayer Films Consisting of Polyelectrolyte/Graphene Oxide-MnO2-ZnO for Energy Storage Applications |
title_full |
Supercapacitor Based on Nanostructured Multilayer Films Consisting of Polyelectrolyte/Graphene Oxide-MnO2-ZnO for Energy Storage Applications |
title_fullStr |
Supercapacitor Based on Nanostructured Multilayer Films Consisting of Polyelectrolyte/Graphene Oxide-MnO2-ZnO for Energy Storage Applications |
title_full_unstemmed |
Supercapacitor Based on Nanostructured Multilayer Films Consisting of Polyelectrolyte/Graphene Oxide-MnO2-ZnO for Energy Storage Applications |
title_sort |
Supercapacitor Based on Nanostructured Multilayer Films Consisting of Polyelectrolyte/Graphene Oxide-MnO2-ZnO for Energy Storage Applications |
author |
Oliveira, Danilo A. |
author_facet |
Oliveira, Danilo A. Silva, Ranilson A. da[UNESP] Orlandi, Marcelo O. [UNESP] Siqueira, José R. |
author_role |
author |
author2 |
Silva, Ranilson A. da[UNESP] Orlandi, Marcelo O. [UNESP] Siqueira, José R. |
author2_role |
author author author |
dc.contributor.none.fl_str_mv |
Federal University of Triângulo Mineiro (UFTM) Universidade Estadual Paulista (UNESP) |
dc.contributor.author.fl_str_mv |
Oliveira, Danilo A. Silva, Ranilson A. da[UNESP] Orlandi, Marcelo O. [UNESP] Siqueira, José R. |
dc.subject.por.fl_str_mv |
energy storage devices layer-by-layer films MnO2-ZnO nanostructures reduced graphene oxide supercapacitors |
topic |
energy storage devices layer-by-layer films MnO2-ZnO nanostructures reduced graphene oxide supercapacitors |
description |
The development of new technologies has increased the demand for energy storage devices with high performance. In this sense, supercapacitors appear as a prominent alternative due to their high power density, fast charge–discharge time, environment friendly, and long-term cycle stability. Carbon materials and transition metal oxides have been reported as attractive materials to achieve supercapacitors with enhanced properties. This study investigates nanostructured films, using the layer-by-layer (LbL) method, consisting of MnO2-ZnO nanostructures embedded into reduced graphene oxide (rGO) and combined with polyallylamine hydrochloride (PAH) polyelectrolyte for supercapacitor applications. The film morphology and the incorporation of MnO2-ZnO nanostructures in rGO layers are analyzed by scanning electron microscopy images. The electrochemical properties are evaluated by cyclic voltammetry and galvanostatic charge–discharge measurements. A high capacitance is reached for a 20-bilayer PAH/rGO-MnO2-ZnO LbL film at a 1 mV s−1 and 1.15 A g−1 with values of 1650 F g−1 and 26 mF cm−2. Furthermore, the film exhibits high energy and power densities of 112.3 Wh kg−1 and 404.4 W kg−1, respectively, as well as high capacitive retention and cycle stability. These findings indicate the potential application of PAH/rGO-MnO2-ZnO LbL films as supercapacitor electrodes and envisage further studies of LbL nanostructured systems for energy storage applications. |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022-01-01 2023-03-01T19:51:35Z 2023-03-01T19:51:35Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1002/pssa.202100871 Physica Status Solidi (A) Applications and Materials Science. 1862-6319 1862-6300 http://hdl.handle.net/11449/239881 10.1002/pssa.202100871 2-s2.0-85128202031 |
url |
http://dx.doi.org/10.1002/pssa.202100871 http://hdl.handle.net/11449/239881 |
identifier_str_mv |
Physica Status Solidi (A) Applications and Materials Science. 1862-6319 1862-6300 10.1002/pssa.202100871 2-s2.0-85128202031 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Physica Status Solidi (A) Applications and Materials Science |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1799965356765216768 |