Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular

Detalhes bibliográficos
Autor(a) principal: Francisco Junior, Wilmo E. [UNESP]
Data de Publicação: 2009
Outros Autores: Bevilaqua, Denise [UNESP], Garcia Júnior, Oswaldo[UNESP]
Tipo de documento: Artigo
Idioma: por
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1590/S0100-40422009000600022
http://hdl.handle.net/11449/25355
Resumo: This paper analyses the oxidation of covellite and molybdenite by Acidithiobacillus ferrooxidans strain LR using respirometric experiments. The results showed that both sulfides were oxidized by A. ferrooxidans, however, the covellite oxidation was much higher than molybdenite. Regarding the kinetic oxidation, the findings revealed that just molybdenite oxidation followed the classical Michaelis-Menten kinetic. It is probably associated with the pathway which these sulfides react to chemistry-bacterial attack, what is influenced by its electronic structures. Besides, experiments conducted in the presence of Fe3+ did not indicate alterations in molybdenite oxidation. Thus, ferric ions seem not to be essential to the sulfide oxidations.
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spelling Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celularOxidation study of the synthetic sulfides molybdenite (MoS2) and covellite (CuS) by Acidithiobacillus ferrooxidans using respirometric experimentssulfide oxidationA. ferrooxidansrespirometric experimentsThis paper analyses the oxidation of covellite and molybdenite by Acidithiobacillus ferrooxidans strain LR using respirometric experiments. The results showed that both sulfides were oxidized by A. ferrooxidans, however, the covellite oxidation was much higher than molybdenite. Regarding the kinetic oxidation, the findings revealed that just molybdenite oxidation followed the classical Michaelis-Menten kinetic. It is probably associated with the pathway which these sulfides react to chemistry-bacterial attack, what is influenced by its electronic structures. Besides, experiments conducted in the presence of Fe3+ did not indicate alterations in molybdenite oxidation. Thus, ferric ions seem not to be essential to the sulfide oxidations.Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Universidade Federal de Rondônia Departamento de QuímicaUniversidade Estadual Paulista Instituto de Química Departamento de Bioquímica e Tecnologia QuímicaUniversidade Estadual Paulista Instituto de Química Departamento de Bioquímica e Tecnologia QuímicaSociedade Brasileira de QuímicaUniversidade Federal de Rondônia (UNIR)Universidade Estadual Paulista (Unesp)Francisco Junior, Wilmo E. [UNESP]Bevilaqua, Denise [UNESP]Garcia Júnior, Oswaldo[UNESP]2014-05-20T14:17:53Z2014-05-20T14:17:53Z2009-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article1477-1481application/pdfhttp://dx.doi.org/10.1590/S0100-40422009000600022Química Nova. Sociedade Brasileira de Química, v. 32, n. 6, p. 1477-1481, 2009.0100-4042http://hdl.handle.net/11449/2535510.1590/S0100-40422009000600022S0100-40422009000600022WOS:000270128800022S0100-40422009000600022.pdfSciELOreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPporQuímica Nova0.6460,255info:eu-repo/semantics/openAccess2023-11-12T06:11:40Zoai:repositorio.unesp.br:11449/25355Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T17:28:01.449005Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular
Oxidation study of the synthetic sulfides molybdenite (MoS2) and covellite (CuS) by Acidithiobacillus ferrooxidans using respirometric experiments
title Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular
spellingShingle Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular
Francisco Junior, Wilmo E. [UNESP]
sulfide oxidation
A. ferrooxidans
respirometric experiments
title_short Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular
title_full Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular
title_fullStr Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular
title_full_unstemmed Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular
title_sort Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular
author Francisco Junior, Wilmo E. [UNESP]
author_facet Francisco Junior, Wilmo E. [UNESP]
Bevilaqua, Denise [UNESP]
Garcia Júnior, Oswaldo[UNESP]
author_role author
author2 Bevilaqua, Denise [UNESP]
Garcia Júnior, Oswaldo[UNESP]
author2_role author
author
dc.contributor.none.fl_str_mv Universidade Federal de Rondônia (UNIR)
Universidade Estadual Paulista (Unesp)
dc.contributor.author.fl_str_mv Francisco Junior, Wilmo E. [UNESP]
Bevilaqua, Denise [UNESP]
Garcia Júnior, Oswaldo[UNESP]
dc.subject.por.fl_str_mv sulfide oxidation
A. ferrooxidans
respirometric experiments
topic sulfide oxidation
A. ferrooxidans
respirometric experiments
description This paper analyses the oxidation of covellite and molybdenite by Acidithiobacillus ferrooxidans strain LR using respirometric experiments. The results showed that both sulfides were oxidized by A. ferrooxidans, however, the covellite oxidation was much higher than molybdenite. Regarding the kinetic oxidation, the findings revealed that just molybdenite oxidation followed the classical Michaelis-Menten kinetic. It is probably associated with the pathway which these sulfides react to chemistry-bacterial attack, what is influenced by its electronic structures. Besides, experiments conducted in the presence of Fe3+ did not indicate alterations in molybdenite oxidation. Thus, ferric ions seem not to be essential to the sulfide oxidations.
publishDate 2009
dc.date.none.fl_str_mv 2009-01-01
2014-05-20T14:17:53Z
2014-05-20T14:17:53Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1590/S0100-40422009000600022
Química Nova. Sociedade Brasileira de Química, v. 32, n. 6, p. 1477-1481, 2009.
0100-4042
http://hdl.handle.net/11449/25355
10.1590/S0100-40422009000600022
S0100-40422009000600022
WOS:000270128800022
S0100-40422009000600022.pdf
url http://dx.doi.org/10.1590/S0100-40422009000600022
http://hdl.handle.net/11449/25355
identifier_str_mv Química Nova. Sociedade Brasileira de Química, v. 32, n. 6, p. 1477-1481, 2009.
0100-4042
10.1590/S0100-40422009000600022
S0100-40422009000600022
WOS:000270128800022
S0100-40422009000600022.pdf
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv Química Nova
0.646
0,255
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 1477-1481
application/pdf
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv SciELO
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
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