Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular
Autor(a) principal: | |
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Data de Publicação: | 2009 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1590/S0100-40422009000600022 http://hdl.handle.net/11449/25355 |
Resumo: | This paper analyses the oxidation of covellite and molybdenite by Acidithiobacillus ferrooxidans strain LR using respirometric experiments. The results showed that both sulfides were oxidized by A. ferrooxidans, however, the covellite oxidation was much higher than molybdenite. Regarding the kinetic oxidation, the findings revealed that just molybdenite oxidation followed the classical Michaelis-Menten kinetic. It is probably associated with the pathway which these sulfides react to chemistry-bacterial attack, what is influenced by its electronic structures. Besides, experiments conducted in the presence of Fe3+ did not indicate alterations in molybdenite oxidation. Thus, ferric ions seem not to be essential to the sulfide oxidations. |
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Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celularOxidation study of the synthetic sulfides molybdenite (MoS2) and covellite (CuS) by Acidithiobacillus ferrooxidans using respirometric experimentssulfide oxidationA. ferrooxidansrespirometric experimentsThis paper analyses the oxidation of covellite and molybdenite by Acidithiobacillus ferrooxidans strain LR using respirometric experiments. The results showed that both sulfides were oxidized by A. ferrooxidans, however, the covellite oxidation was much higher than molybdenite. Regarding the kinetic oxidation, the findings revealed that just molybdenite oxidation followed the classical Michaelis-Menten kinetic. It is probably associated with the pathway which these sulfides react to chemistry-bacterial attack, what is influenced by its electronic structures. Besides, experiments conducted in the presence of Fe3+ did not indicate alterations in molybdenite oxidation. Thus, ferric ions seem not to be essential to the sulfide oxidations.Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Universidade Federal de Rondônia Departamento de QuímicaUniversidade Estadual Paulista Instituto de Química Departamento de Bioquímica e Tecnologia QuímicaUniversidade Estadual Paulista Instituto de Química Departamento de Bioquímica e Tecnologia QuímicaSociedade Brasileira de QuímicaUniversidade Federal de Rondônia (UNIR)Universidade Estadual Paulista (Unesp)Francisco Junior, Wilmo E. [UNESP]Bevilaqua, Denise [UNESP]Garcia Júnior, Oswaldo[UNESP]2014-05-20T14:17:53Z2014-05-20T14:17:53Z2009-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article1477-1481application/pdfhttp://dx.doi.org/10.1590/S0100-40422009000600022Química Nova. Sociedade Brasileira de Química, v. 32, n. 6, p. 1477-1481, 2009.0100-4042http://hdl.handle.net/11449/2535510.1590/S0100-40422009000600022S0100-40422009000600022WOS:000270128800022S0100-40422009000600022.pdfSciELOreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPporQuímica Nova0.6460,255info:eu-repo/semantics/openAccess2023-11-12T06:11:40Zoai:repositorio.unesp.br:11449/25355Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T17:28:01.449005Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular Oxidation study of the synthetic sulfides molybdenite (MoS2) and covellite (CuS) by Acidithiobacillus ferrooxidans using respirometric experiments |
title |
Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular |
spellingShingle |
Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular Francisco Junior, Wilmo E. [UNESP] sulfide oxidation A. ferrooxidans respirometric experiments |
title_short |
Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular |
title_full |
Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular |
title_fullStr |
Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular |
title_full_unstemmed |
Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular |
title_sort |
Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular |
author |
Francisco Junior, Wilmo E. [UNESP] |
author_facet |
Francisco Junior, Wilmo E. [UNESP] Bevilaqua, Denise [UNESP] Garcia Júnior, Oswaldo[UNESP] |
author_role |
author |
author2 |
Bevilaqua, Denise [UNESP] Garcia Júnior, Oswaldo[UNESP] |
author2_role |
author author |
dc.contributor.none.fl_str_mv |
Universidade Federal de Rondônia (UNIR) Universidade Estadual Paulista (Unesp) |
dc.contributor.author.fl_str_mv |
Francisco Junior, Wilmo E. [UNESP] Bevilaqua, Denise [UNESP] Garcia Júnior, Oswaldo[UNESP] |
dc.subject.por.fl_str_mv |
sulfide oxidation A. ferrooxidans respirometric experiments |
topic |
sulfide oxidation A. ferrooxidans respirometric experiments |
description |
This paper analyses the oxidation of covellite and molybdenite by Acidithiobacillus ferrooxidans strain LR using respirometric experiments. The results showed that both sulfides were oxidized by A. ferrooxidans, however, the covellite oxidation was much higher than molybdenite. Regarding the kinetic oxidation, the findings revealed that just molybdenite oxidation followed the classical Michaelis-Menten kinetic. It is probably associated with the pathway which these sulfides react to chemistry-bacterial attack, what is influenced by its electronic structures. Besides, experiments conducted in the presence of Fe3+ did not indicate alterations in molybdenite oxidation. Thus, ferric ions seem not to be essential to the sulfide oxidations. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-01-01 2014-05-20T14:17:53Z 2014-05-20T14:17:53Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1590/S0100-40422009000600022 Química Nova. Sociedade Brasileira de Química, v. 32, n. 6, p. 1477-1481, 2009. 0100-4042 http://hdl.handle.net/11449/25355 10.1590/S0100-40422009000600022 S0100-40422009000600022 WOS:000270128800022 S0100-40422009000600022.pdf |
url |
http://dx.doi.org/10.1590/S0100-40422009000600022 http://hdl.handle.net/11449/25355 |
identifier_str_mv |
Química Nova. Sociedade Brasileira de Química, v. 32, n. 6, p. 1477-1481, 2009. 0100-4042 10.1590/S0100-40422009000600022 S0100-40422009000600022 WOS:000270128800022 S0100-40422009000600022.pdf |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
Química Nova 0.646 0,255 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
1477-1481 application/pdf |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
SciELO reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808128815304540160 |